Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing wastewater treatment. However, little is currently known about the changes of treatment efficiency with time going. This research investigated the long-term performance of the catalyzed Fe-Cu process to reduce nitrobenzene (NB) in alkaline wastewater. In addition, the changes of the metal surfaces morphologies and matters before and after the reaction were analyzed by scanning electron microscopy (SEM) in conjunction with energy-dispersion spectroscopy (EDS) and X-ray diffraction spectroscopy (XRD). The results showed that the surface properties of copper almost remained unchanged after weeks of operation, which spelled its strong chemical stability and resistance to poisoning. Moreover, the results indicated that there were two reasons for the treatment efficiency decreasing with time. One was the gradual iron element consumption due to corrosion. The other was iron reactivity weakened due to the precipitates accumulation on the surfaces that were mainly Fe₃O₄ and FeCO. __________ Translated from Environmental Pollution & Control, 2006, 28(10): 783–785 [译自: 环境污染与防治]     

中国经济增长最大的风险是资源不足

中国经济增长最大的风险是资源不足，按照已经探明的自然资源总量估计的资源价值，中国是5万亿美元，远远比不上俄罗斯的300万亿美元。按照人均资源中国就更是少得可怜。寄希望于科技进步，如氢燃料，转基因、海水淡化，由于成本限制在15年内应用价值不大。把污染环境，消耗资源最大的重化工业，如钢铁、造纸、化工等向海外迁移，是一个重要的大战略，但国内生产速度要下降，外国能够接纳多少也未可知。如果是投资带移民，对中国利益最大，但必然要受到外国的强烈反对。     

半导体生产排放的废气和废水中砷、磷、硫的分析方法研究

研究了一种快速、灵敏、可靠的高温氢还原-气相色谱分析方法[1-2]，并自行设计了高温还原系统(还原炉、六通阀等)，测定半导体生产排放废气和废水中的砷、磷、硫及其化合物，样品不需预处理，使气相色谱仪能直接测定固、液、气相样品中砷、磷、硫及其化合物的含量。砷、磷、硫的检测限分别为0．01mg／L、0．003mg／L、0．02mg／L；相对标准偏差分别为6．2％、8．6％和0．3％，与经典方法进行对比，结果基本一致。从分析方法的误差统计角度，也说明该方法准确、可靠。     

Effects of acid,acid-ZVI/PMS,Fe(Ⅱ)/PMS and ZVI/PMS conditioning on the wastewater activated sludge(WAS)dewaterability and extracellular polymeric substances(EPS)

The effects of four conditioning approaches:Acid,Acid-zero-valent iron(ZVI)/peroxydisulfate(PMS),Fe(Ⅱ)/PMS and ZVI/PMS,on wastewater activated sludge(WAS) dewatering and organics distribution in supernatant and extracellular polymeric substances(EPS) layers were investigated.The highest reduction in bound water and the most WAS destruction was achieved by Acid-ZVI/PMS,and the optimum conditions were pH 3,ZVI dosage 0.15 g/g dry solid(DS),oxone dosage 0.07 g/g DS and reaction time 10.6 min with the reductions in capillary suction time(CST) and water content(Wc) as 19.67% and 8.49%,respectively.Four conditioning approaches could result in TOC increase in EPS layers and supernatant,and protein(PN) content in tightly bound EPS(TB-EPS).After conditioning,organics in EPS layers could migrate to supernatant.Polysaccharide(PS) was easier to migrate to supernatant than PN.In addition,Acid,Acid-ZVI/PMS or Fe(Ⅱ)/PMS conditioning promoted the release of some polysaccharides containing ring vibrations v P=O,v C-O-C,v C-O-P functional groups from TB-EPS.ESR spectra proved that both radicals of SO_4~-· and·OH contributed to dewatering and organics transformation and migration.CST value of WAS positively correlated with the ratios of PN/PS in LB-EPS and total EPS,while it negatively correlated with TOC,PN content and PS content in TB-EPS,as well as PS content in supernatant and LB-EPS.BWC negatively correlated to zeta potential and TOC value,PN content,and HA content in supernatant.     

Determination and discussion hydraulic retention time in membrane bioreactor system

Based on the microorganism kinetic model, the formula for computing hydraulic retention time in a membrane bioreactor system (MBR) is derived. With considering HRT as an evaluation index a combinational approach was used to discuss factors which have an effect on MBR. As a result, the influencing factors were listed in order from strength to weakness as: maximum specific removal rate K, saturation constant Ks, maintenance coefficient m, maximum specific growth rate ,ua and observed yield coefficient Yobs. Moreover, the formula was simplified, whose parameters were experimentally determined in petrochemical wastewater treatment. The simplified formula is θ= 1.1( 1/β -1)(Kｓ S)/KXo , for oetroehemical wastewater treatment K and Ko eaualed 0.185 and 154.2, resoectively.     

人的安全性评价研究

随着人们对人在整个安全系统中的重要性认识的不断提高 ,如何对人的安全性进行科学的评价也就越来越显得重要。笔者在综合论述了目前我国对机车乘务人员、起重机械作业人员、驾驶员以及电力运行人员的安全性研究以及国外相关研究的基础上 ,提出了有关人的安全性评价的定义 ,并提出如何建立人的安全性评价体系以及对人的安全性评价的通用指标 ,探讨了在实际工作中如何运用上述指标去评价人的安全性。为人的安全性评价提供了一种有效的方法和新的研究思路     

武钢金山店铁矿某通风系统项目评估

介绍了金山店铁矿通风系统多级站和机站设计；阐述了该项目的施工，检测及通风效果评估情况；对安全生产提出了全面，系统的建议。     

地面除尘在酒钢3#焦炉的应用

论述酒钢3#焦炉推焦过程中产生烟尘的治理方法-地面除尘技术,针对其存在的问题,提出改进方法.     

火灾中均布荷载作用下钢筋混凝土方板的极限分析

本文利用有限差分法确定了火灾时钢筋混凝土板的温度分布，并基于塑性铰线理论确定了火灾时钢筋混凝土方板的破坏机制，根据高温下混凝土和钢筋的力学性能对火灾过程中塑性铰截面的弯矩及板的极限荷载进行了分析，可为建筑结构的耐火设计提供依据。     

浅论环境教育的实施原则

本文对环境教育的涵义与基本特征作了简要的分析，重点论述了实施环境教育应遵循的七条基本原则。