氢化物发生原子荧光光谱法测定饮用水中的铅

通过改变仪器条件及试剂配比进行优选实验,利用原子荧光光谱法测定饮用水中的铅可知:铅的检出限是0.020μg/L,能够满足GB 5749-2006《生活饮用水卫生标准》的要求;同时原子荧光光谱仪分析样品灵敏度高、重现性好、干扰少、操作简便、分析快捷,测定样品的准确度和精密度均能达到质量控制要求。     

基于协调度与熵权法的绩效评价新方法

自人们意识到绩效评价的重要性以来,越来越多的研究集中于绩效评价的方法。以往的绩效评价侧重用数字表象进行评价,而忽略了政府、企业系统及其与社会经济发展之间的特性。基于此,根据既有的信息熵理论研究成果,提出了协调度与熵权法复合评价模型,并运用该模型对2009年度河北省区域创新绩效进行了实证分析,既科学、全面地衡量绩效情况,又便于政府、企业及其与社会经济发展之间的系统分析,是一种绩效评价方法的创新,具有一定的普适性和通用性。     

整体合建倒置A^2O氧化沟中试试验及参数优化

以处理20m^3／d城镇生活污水的深沟型气升推流立体循环倒置A^2O整体合建氧化沟中试装置为研究平台,通过对影响该工艺运行的有机物的去除效果、硝化反应与反硝化反应效果及除磷效果等因素进行探索及最佳工况的正交试验设计,实验结果表明该工艺对BOD,、COD、SS、NH4^-N、TN、TP的平均去除率分别为94．25％、90...     

秀丽线虫适应响应的形成与调控机理

除了环境暴露评价,在环境毒理学研究中模式动物秀丽线虫也已经被应用于适应响应形成及其调控机理研究.在综述中,系统介绍了秀丽线虫中存在的几种形式毒物诱发的适应响应,即同一因素适应响应、交叉适应响应与特殊形式的适应响应;讨论了目前已经揭示出的6种影响适应响应形成因素;分析了适应响应形成可能机制,即抗氧化应激体系、热激蛋白、金...     

Assessment of heavy metals in sediments from a typical catchment of the Yangtze River, China

An intensive investigation was conducted to study the accumulation, speciation, and distribution of various heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in sediments from the Yangtze River catchment of Wuhan, China. The potential ecological risks posed by these heavy metals also were estimated. The median concentrations of most heavy metals (As, Cd, Cr, Cu, Ni, Pb, and Zn) were higher than the background values of soils in Wuhan and were beyond the threshold effect level (TEL), implying heavy metal contamination of the sediments. Carbonate-bound Cd and exchangeable Cd, both of which had high bioavailability, were 40.2% and 30.5% of the total for Cd, respectively, demonstrating that Cd poses a high ecological risk in the sediments. The coefficients of the relationship among Pb, Hg, and Cu were greater than 0.797 using correlation analysis, indicating the highly positive correlation among these three elements. Besides, total organic carbon content played an important role in determining the behaviors of heavy metals in sediments. Principal component analysis was used to study the distribution and potential origin of heavy metals. The result suggested three principal components controlling their variability in sediments, which accounted for 36.72% (factor 1: Hg, Cu, and Pb), 28.69% (factor 2: Cr, Zn, and Ni), and 19.45% (factor 3: As and Cd) of the total variance. Overall, 75% of the studied sediment samples afforded relatively low potential ecological risk despite the fact that generally higher concentrations of heavy metals relative to TEL were detected in the sediments.     

A dynamic Bayesian networks modeling of human factors on offshore blowouts

An application of dynamic Bayesian networks for quantitative risk assessment of human factors on offshore blowouts is presented. Human error is described using human factor barrier failure (HFBF), which consists of three categories of factors, including individual factor barrier failure (IFBF), organizational factor barrier failure (OFBF) and group factor barrier failure (GFBF). The structure of human factors is illustrated using pseudo-fault tree, which is defined by incorporating the intermediate options into fault tree in order to eliminate the binary restriction. A methodology of translating pseudo-fault tree into Bayesian networks and dynamic Bayesian networks taking repair into consideration is proposed and the propagation is performed. The results show that the human factor barrier failure probability only increases within the first two weeks and rapidly reaches a stable level when the repair is considered, whereas it increases continuously when the repair action is not considered. The results of mutual information show that the important degree sequences for the three categories of human factors on HFBF are: GFBF, OFBF and IFBF. In addition, each individual human factor contributes different to the HFBF, those which contribute much should given more attention in order to improve the human reliability and prevent the potential accident occurring.     

A comparative study of the effect of clay binders on iron oxide sorbent in the high-temperature removal of hydrogen sulfide

The purpose of this study is to investigate the effect of clay binder, an important additive, on the performance of iron oxide sorbent in high temperature coal gas desulfurization. The four clay binders chosen for the study were kaolinite, diatomite, bentonite and brick clay. The sulfidation–regeneration cycles were conducted in a fixed-bed reactor. XRD, DTA and FTIR, together with texture characterizing techniques, such as mercury porosimetry and nitrogen adsorption, were adopted to characterize the sorbents and raw materials. The results obtained show that sorbents prepared from various clay binders exhibit different breakthrough behaviors. In addition, a correlation between pore volume and sulfur capacity reveals that sorbents with a greater number of pores larger than 200 nm (diameter), exhibit higher sulfur capacity. The reason for this is that a greater number of large pores can improve diffusion and provide a larger space for relieving heat impact. However, too many large pores may result in weak strength and very low bulk density, thus a balance between large pores and the density must be achieved. This study also reveals that clay binder can contribute to the modification of a sorbent's texture as gas is released when the mineral structure changes during calcination. In addition, a clay mineral with an active interlayer has been shown to be beneficial in improving the dispersion of active components in the sorbent, because of the existence of an interaction between the mineral and red mud.     

全面罩空气自携式潜水装具的研制

为解决目前国内自携式潜水装具性能相对落后的问题,研制了全面罩空气自携式潜水装具。本文介绍了装具的组成、工作原理和性能实验。结果表明全面罩空气自携式潜水装具在使用性能、舒适性及功能性等方面有了较大的提高,能满足国内潜水员的使用要求。     

Evaluating coal bed methane investment in China based on a real options model

In this paper, a real options based binominal lattices model for the investment of coal bed methane (CBM) is conducted. CBM prices and market demand are incorporated into the model as the predominant uncertain factors and it is solved by using the bidimensional binominal lattices approach. Then the model is employed to evaluate the investment in CBM projects in China, and the effect of related policies is analyzed. The empirical results demonstrate that the model can be used to offer a better explanation of why the CBM industry has developed slowly in China from an investment perspective. It is found that the current policy environment is not positive enough to attract investment in the CBM industry. Among various factors, CBM prices yield the most significant effect on stimulating investment in CBM development. Increasing the price subsidy is also an effective policy to stimulate investment and promote the development of the CBM industry in China.     

秦皇岛雷暴天气的时空尺度分布与雷电灾害分析

利用2003-2012年3～10月秦皇岛地区5个气象站雷暴监测和雷电灾害资料,采用数理统计、天气综合分析方法,得出秦皇岛地区雷暴天气的时空尺度分布特征为：全区年雷暴发生频次总体上呈递减趋势,其中,2005年35次,2008年33次,2012年20次;6月份为全年雷暴发生的峰值时段,7月、8月次之,且与秦皇岛本地主汛期相吻合;在海岸带地区由于受海洋条件影响,个别年份雷暴最早出现在2月份,最晚出现在11月中旬;雷暴天气的日时段主要出现在下午至傍晚,占70%,夜间占20%,其他时段为10%;北部山区的雷电频次大于沿海地区,对应电力、化工等行业雷电灾害呈下降趋势,但是通讯、计算机、家电等弱电系统雷击事件呈递增趋势。