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861.
Bioabsorbable soy protein plastic composites: Effect of polyphosphate fillers on water absorption and mechanical properties 总被引:7,自引:0,他引:7
The use of synthetic and natural bioabsorbable plastics has been severely limited due to their low stiffness and strength
properties as well as their strong tendency to absorb moisture. This research focused on the development of bioabsorbable
polyphosphate filler/soy protein plastic composites with enhanced stiffness, strength, and water resistance. Bioabsorbable
polyphosphate fillers, biodegradable soy protein isolate, plasticizer, and adhesion promoter were homogenized and compression-molded.
Physical, mechanical, and water absorption testing was performed on the molded specimens. Results showed improvements in stiffness,
strength, and water resistance with increasing polyphosphate filler content up to 20% by weight. Application of a coupling
agent produced further mechanical property enhancements and a dramatic improvement in water resistance, interpreted by an
interfacial chemical bonding model. Examination of the fracture surfaces of the materials revealed that the addition of the
polyphosphate fillers changed the failure mode from brittle to pseudo-ductile. These results suggest that these materials
are suitable for many load-bearing applications in both humid and dry environments where current soy protein plastics are
not usable. 相似文献
862.
ABSTRACT: Past historical evidence indicates that droughts have had great impacts on human life. Drought (or scarcity of water) is assessed based on two key factors, namely, the estimated water demand, and the expected water supply. The formulation of these key factors for a region largely depends on the agro-climatic and economic conditions. Consideration of one such key factor is the relationship between the crop yield and water deficit in the assessment and prediction of agricultural droughts. The varying nature of this relationship from crop to crop adds to the complexity of agricultural drought analysis. To overcome this difficulty in analyzing agricultural droughts of a region, it is adequate to consider and place emphasis on a single crop (i.e., an index crop) grown homogeneously over the major area of the region. From one year to another year, the pattern of water requirement during the growing season of an index crop is rather stationary, and the water supply in arid and semi-arid area is mainly from seasonal random precipitation. In a region, grain yield of the index crop and, in turn, assessment of the severity of drought can reasonably be predicted as a function of the time of crop sowing and the distribution of rainfall, provided that temporal and spatial effects of other contributing factors (crop variety, soil fertility status, crop disease, pest control, cultivation practices etc.) on grain yield are considered to be uniformly distributed (i.e., stable). A predictive method of assessing agricultural droughts in an arid area of western India is presented. The major crop (Pearl Millet) of this region is grown from. July through September. The formulation of the proposed predictive method inherently implies that the grain yield of the main crop is a reliable indicator of agricultural drought. In the development of this predictive relationship (i.e., a regression type model) a number of potential yet simple variables affecting the grain yield in the region were investigated. The soil moisture index, although generally considered significant compared to the simple variables, has been found to account for insignificant variation in the grain yield. Results of our investigations suggest that it would be advisable to exclude the soil moisture index variable from the model. The proposed regression model can be used in the prediction of grain yield of the main crop several months ahead of crop harvesting operations and, in turn, the assessment of agricultural drought severity as mild, moderate, or severe. Such an assessment is expected to be helpful to planners for arranging appropriate measures to effectively combat agricultural drought situations. 相似文献
863.
864.
865.
866.
867.
868.
The Influence of Atmospheric N Deposition on Nitrous Oxide and Nitric Oxide Fluxes and Soil Ammonium and Nitrate Concentrations 总被引:2,自引:0,他引:2
U. Skiba C. Pitcairn L. Sheppard V. Kennedy D. Fowler 《Water, Air, & Soil Pollution: Focus》2004,4(6):37-43
The deposition of atmospheric N to soils provides sources of available N to the nitrifying and denitrifying microbial community and subsequently influences the rate of NO and N2O emissions from soil. We have investigated the influence of three different sources of enhanced N deposition on NO and N2O emissions 1) elevated NH3 deposition to woodlands downwind of poultry and pig farms, 2) increased wet cloud and occult N deposition to upland forest and moorland and 3) enhanced N deposition to trees as NO
3
–
and NH
4
+
aerosol. Flux measurements of NO and N2O were made using static chambers in the field or intact and repacked soil cores in the laboratory and determination of N2O by gas chromatography and of NO by chemiluminescence analysis. Rates of N deposition to our study sites were derived from modelled estimates of N deposition, NH3 concentrations measured by passive diffusion and inference from measurements of the 210Pb inventory of soils under tree canopies compared with open grassland. NO and N2O emissions and KCl-extractable soil NH
4
+
and NO
3
–
concentrations all increased with increasing N deposition rate. The extent of increase did not appear to be influenced by the chemical form of the N deposited. Systems dominated by dry-deposited NH3 downwind of intensive livestock farms or wet-deposited NH
4
+
and NO
3
–
in the upland regions of Britain resulted in approximately the same linear response. Emissions of NO and N2O from these soils increased with both N deposition and KCl extractable NH
4
+
, but the relationship between NH
4
+
and N deposition (ln NH
4
+
= 0.62 ln Ndeposition + 0.21, r
2 = 0.33, n = 43) was more robust than the relationship between N deposition and soil NO and N2O fluxes. 相似文献
869.
Measuring Aerosol and Heavy Metal Deposition on Urban Woodland and Grass Using Inventories of 210Pb and Metal Concentrations in Soil 总被引:1,自引:0,他引:1
D. Fowler U. Skiba E. Nemitz F. Choubedar D. Branford R. Donovan P. Rowland 《Water, Air, & Soil Pollution: Focus》2004,4(2-3):483-499
The deposition of aerosols to trees has proved very difficult to quantify, especially in complex landscapes. However, trees are widely quoted to be efficient scavengers of particles from the atmosphere, and a growing proportion of the pollutant burden in the atmosphere is present in the aerosol phase. In this study, the deposition of aerosols onto woodland and grass was quantified at a range of locations throughout the West Midlands of England. The sites included mature deciduous woodland in Edgbaston, and Moseley, and mixed woodland at sites within Sutton Park, a large area of semi-natural vegetation. Aerosol deposition to areas of grassland close to the woodland at each site was also measured. Detailed inventories of 210Pb in soils within the woodland and in grassland soils, together with concentrations in the atmosphere and precipitation, provided the necessary data to calculate the long-term (about 40 years) annual deposition of sub-micron aerosols onto grassland and woodland. The soil inventories of 210Pb under woodland exceeded those under grass, by between 22% and 60%, with dry deposition contributing 24% of the total input flux for grass and 47% for woodland. The aerosol dry deposition velocity to grassland averaged 3.3 mm s-1 and 9 mm s-1 for woodland. The large deposition rates of aerosols onto woodland relative to grass or other short vegetation (× 3), and accumulation of heavy metals within the surface horizons of organic soils, leads to large concentrations in soils of urban woodland. Concentrations in the top 10 cm of these woodland soils averaged 252 mg kg-1 for Pb with peaks to 400 mg kg-1. Concentrations of Cd averaged 1.4 mg kg-1, Cu, 126 mg kg-1, Ni 23 mg kg-1 and Zn 173 mg kg-1. The accumulated Pb in urban woodland soils is shown to be large relative to UK emissions. 相似文献
870.
T. Grewer H. Klusacek U. Lffler R. L. Rogers J. Steinbach 《Journal of Loss Prevention in the Process Industries》1989,2(4):215-223
Experience gained in the chemical industry in testing and assessing the thermal safety of chemical processes is published in this paper. Isothermal and adiabatic tests, which are the most important methods for both small and large quantities, are described and discussed. Methods for testing the thermal hazards of primary or desired reactions are also included, e.g. reaction calorimetry, adiabatic methods, investigations using a sampling method. More important are the criteria for assessing the test results. On the basis of energies produced by primary and secondary reactions and the temperature ranges within which they take place, thermal hazards can be predicted. If the rules for the safe design of batch and semi-batch reactions are observed, it is possible to control the thermal behaviour of reactions. 相似文献