Facile, effective, and environment-friendly degradation of sulfamonomethoxine in aqueous solution with the aid of a UV/Oxone oxidative process

The degradation of sulfamonomethoxine (SMM) in the aqueous environment by the combination of UV illumination and Oxone has been studied. Experimental results indicated that the UV illumination can effectively activate Oxone to produce sulfate-free radicals (SO₄ ^??). When 10 mmol L^?1 Oxone was added, 96.78 % removal of SMM (5 mg L^?1) was achieved within 90 min. Mineralization of SMM was investigated by measuring the total organic carbon, which decreased by 89.01 % after 90 min reaction. Six intermediate compounds generated during the SMM degradation were identified with the aid of liquid chromatography and mass spectroscopy, combined with proton nuclear magnetic resonance spectroscopy. A general reaction pathway for the degradation of SMM was proposed, where the presence of SO₄ ^?? remained crucial during the degradation process.     

基于AERMOD模式的固定源对不同楼层大气污染预测研究

环境影响评价中,大气污染预测通常考虑地面的浓度影响,对高层住宅楼不同楼层影响的考虑较少.通过案例设计,模拟4种不同的污染排放情景,采用预测推荐模式AERMOD分别计算各情景下5个代表高度共20种组合情况的预测受体结果,并基于三维可视仪软件VOXLER直观显示各情景污染物浓度的空间连续分布情况,对小时最大浓度的分布规律利用分析工具CANOCO进行了分析.结果表明:(1)污染源高为15～80 m时,不同楼层间小时浓度分布差异性较大;污染源高为120～240 m时,楼层间差异性较小.(2)污染源高为15m时,小时最大浓度以50 m为分界线随楼层高度的增加先增后降;污染源高为80～240 m时,小时最大浓度随楼层高度的增加而增加.     

混凝辅助电化学法处理橙黄G染料废水

以石墨板为阳极,研究了电化学氧化法对橙黄G染料废水的降解效果。比较了在NaCl、Na2 SO4以及NaCl与FeSO4·7H2O组合的支持电解质体系中的处理效果,同时考察了电压、初始pH、电解质浓度、电极间距和电解时间等因素对废水中橙黄G脱色率及COD去除率的影响。研究结果表明,橙黄G的脱色主要是活性氯的氧化作用,橙黄G分子的矿化可能主要是电解过程中产生的·OH的作用,FeSO4·7H2O的加入增加了混凝作用,使得处理效果进一步提高。最佳脱色条件下橙黄G脱色率和COD的去除率分别为97．6％和56．3％,B／C（BOD／COD）由0．09提高至0．41,可生化性有较大改善,并且随着降解时间的增加,COD去除率逐渐升高。此结果表明,橙黄G废水COD的去除相对于脱色存在滞后性。     

四环素高效降解酵母菌Trichosporon mycotoxinivorans XPY-10降解特性

Trichosporon mycotoxinivorans XPY-10是一株分离自抗生素制药厂的高效四环素降解酵母菌。为了建立该菌株降解四环素的适宜条件,分别研究了碳源、有机氮源、金属离子等营养物质及初始底物浓度、接种量、pH、温度、装液量、摇床转速等理化因素对菌体生长及四环素降解效率的影响。结果表明,菌株XPY-10生长的最适碳源和氮源分别为蔗糖和蛋白胨。在含有0．05％FeSO4的培养基中,菌株XPY—10降解四环素的适宜条件为：接种量2％,pH8,温度3422,装液量100mL（250mL三角瓶）,摇床转速180r／min。在此条件下,菌株XPY—10在7d内对初始浓度为600mg／L的四环素降解率为83．63％。本菌株对养殖废水及制药废水中四环素的污染治理有一定的应用前景。     

Sorption of the veterinary antimicrobials sulfadimethoxine and ormetoprim in soil

Currently, limited research on the fate of antimicrobials in the environment exists, once they are discharged in human and animal wastes. Sorption of two antimicrobials, sulfadimethoxine (SDM) and ormetoprim (OMP), was investigated in two soils and sand using a series of batch experiments. Because OMP and SDM are often administered in combination, their sorption was also investigated in combination as co-solutes. The rate of SDM and OMP sorption was rapid over the first few hours of the experiments, which then slowed considerably after 16 to 68 h. OMP sorption was enhanced at high concentrations when in combination with SDM, with linear sorption coefficients ranging from 1.3 to 58.3 L.kg(-1) in the single solute experiments and 4.96 to 89.7 L.kg(-1) in the co-solute experiments. Sorption of OMP as a single solute seems to provide a better fit with the Freundlich equation, which became more linear (n approached 1) when SDM was present. Overall, SDM sorbed less than OMP in the two soils and sand. SDM linear sorption coefficients ranged from 0.4 to 25.8 L.kg(-1) as a single solute and 2.5 to 22.1 L.kg(-1) as a co-solute. Sorption of SDM becomes more nonlinear (n < 1) when SDM is present in combination with OMP. Overall, sorption of both antimicrobials increased in the selected soils and sand as the organic matter, clay content, and cation exchange capacity increased. These experiments indicate relatively low sorption of SDM and OMP in natural soils, making them a potential threat to surface and ground water.     

城市滨水景观评价研究初探——以南京市莫愁湖滨水区为例

城市滨水区一直被认为是一个城市最具活力和生态价值的区域,但伴随着城市职能的转型以及水运地位的下降,世界上大部分的滨水区都经历了从繁荣到衰败的过程。然而目前,随着城市人群的生态需求与审美需求的进一步提高,城市滨水区又面临着复兴之势,这也对城市滨水号观设计以及作为其基础而存在的滨水景观评价提出了新的要求。因此。本文将以成分代用模式评价方法为指导,以南京市莫愁湖滨水区为案例对其进行景观评价,并基于此获取影响滨水区景观质量的重要因素,以期对以后的滨水区规划设计起到一定的指导作用。     

考虑人因差错影响的结构可靠度计算方法

通过对单个或任意多个人因差错影响下构件截面失效概率计算方法的分析讨论,推导出在理想已知条件下的数学解析求解公式;在考虑人因差错对结构参数影响程度的空间离散化后,得出了相应的简化计算方法;并以一个单筋梁的正截面为例进行了失效概率计算和人因差错影响程度分析.在目前人因差错的发生及其影响规律的研究不完善、缺乏必要的数学模型的现实条件下,该方法对人因差错影响下构件截面失效概率的分析计算有一定的实用价值.     

劳动防护服号型设置的研究

本文对劳动防护服的号型设置进行了分析与研究。《劳动防护服号型》是各类劳动防护服制作中广泛使用的基础性国家标准,依据当前劳动者人体尺寸的统计分析和企业劳动防护服生产供应实际情况,科学合理设置服装号型,以符合国家标准的科学性、实用性以及增强劳动防护服的舒适性功能。     

PHA-Pro软件指导HAZOP分析的工程应用

应用PHA-Pro软件指导HAZOP分析,在传统HAZOP分析的基础上增加了风险等级的概念,使安全评价更加深度、完备、高效和规范.本文简要介绍了应用PHA-Pro7 软件进行HAZOP分析的要点和步骤,并对壳牌(Shell)煤气化工艺(SCGP)中的关键设备气化炉进行了分析.结果表明,氧煤比和水氧比的稳定是保障气化炉安全生产的最重要因素.     

我区城市污水处理程度探讨

建立城市污水处理厂处理污水,是城市发展的必然趋势,而处理级别及处理后水的去向及用途是关系到环境保护和资源得到充分利用的关键,针对我区干旱缺水,灌溉农业特征及天然水域的特点,就污水处理级别排水的用途提出一些看法。