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401.
Molka?Feki-TounsiEmail author Pablo?Olmedo Fernando?Gil Rim?Khlifi Mohamed-Nabil?Mhiri Ahmed?Rebai Amel?Hamza-Chaffai 《Environmental science and pollution research international》2013,20(6):3923-3931
Although exposure to high levels of arsenic is associated with excess bladder cancer risk, lower exposures generally are not. This study represents the first biomonitoring of arsenic exposure in Tunisia and focuses on a possible association with bladder cancer risk. In this context, 124 male bladder cancer cases and 220 controls were recruited and blood samples were analyzed to determine the concentration of As. The study subjects were stratified into median groups based on concentrations of arsenic in their blood. Blood arsenic (B-As) was significantly two to threefold higher in bladder cancer cases than in controls (p?<?0.05). The arsenic concentrations were significantly higher among both smokers and workers in construction. However, neither drinking water nor seafood was found to be incriminated as exposure sources. The adjusted risk ratios for B-As concentration categories 0.1–0.67 and ≥0.67 μg/L were 0.18 (95% CI?=?0.014–2.95) and 2.44 (95% CI?=?1.11–5.35), respectively. Arsenic levels were not found to be associated with tumor grade or stage. The considerable risk in the category of highest cumulative exposure argues for an association between bladder cancer risk and low-level arsenic exposure. Future investigations with larger samples and using techniques that allow the distinction of the different arsenic species should better elucidate this association. Furthermore, the modulation of arsenic level according to the histological grade may be of potential to be used as a diagnostic marker of the disease process and its possible relationship etiologically. 相似文献
402.
Bruno Spinosa DeMartinis Fernando Mauro Lanças 《Journal of environmental science and health. Part. B》2013,48(5):539-547
Abstract Supercritical fluid extraction (SFE) is a rapid and convenient method for the isolation of organic compounds from environmental samples. This paper describes a supercritical carbon dioxide (CO2) extraction system that uses a newly designed extraction cell to recover organic compounds from an aqueous matrix. Analysis of the extracts by gas chromatography‐electron capture detector (GC‐ECD) indicated that the herbicide trifluralin (2,6‐dinitro‐N,N‐dipropyl‐4‐trifluoromethylaniline) could be quantitatively extracted by using the SFE system proposed with small amounts of sample. The percentage of recovery obtained with the SFE system described was twice as high as the result obtained using a conventional solid‐phase extraction technique. Extraction by SFE was completed in a short period of time using a simple and low‐cost home‐made system that did not require the use of organic solvents. 相似文献
403.
Levels and distribution of organophosphorus flame retardants and plasticizers in fishes from Manila Bay, the Philippines 总被引:2,自引:0,他引:2
Kim JW Isobe T Chang KH Amano A Maneja RH Zamora PB Siringan FP Tanabe S 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3653-3659
Organophosphorus compounds (OPCs) and stable isotope ratios (δ13C and δ15N) were determined in 58 fishes belonging to 20 species collected from Manila Bay, the Philippines. OPCs were detected in most of the samples and found up to μg/g lw (lipid weight) level, suggesting their ubiquitous presence in the coastal marine environment of the Philippines. Higher levels (>1000 ng/g lw) of total OPCs were determined in yellowstriped goatfish, silver sillago, tripletail wrasse and bumpnose trevally indicates either their active uptake from ambient water or lower metabolic capacity of these species. Levels of triphenyl phosphate (TPhP) in demersal species showed a positive correlation with δ15N, indicating that TPhP was adsorbed onto the particle, settled down to the bottom sediment and accumulated through the benthic food web rather than the pelagic. Estimated dietary intake of OPCs in Manila Bay fishes were four to five orders of magnitude lower than the proposed reference dose (RfD). 相似文献
404.
N. E. Korte J. L. Zutman R. M. Schlosser L. Liang B. Gu Q. Fernando 《Waste management (New York, N.Y.)》2000,20(8)
Palladized iron (Pd/Fe) has been tested under field conditions for the dechlorination of trichloroethene (TCE) in groundwater. Contaminated water was pumped from aquifers in Ohio (0.7– 1.5 mg/l TCE) and Missouri (2–9 mg/l TCE and 1,2-dichloroethene) and passed through columns of Pd/Fe. The experiments demonstrated that the dechlorination reaction occurs efficiently until the surface of the Pd/Fe becomes fouled. Regeneration of the surface with dilute (1M) hydrochloric acid is easily accomplished under laboratory conditions, but initially was unsuccessful in the field. Further experiments indicated, that reduced sulfur species, although not naturally present in the groundwater being treated, were permanently poisoning the palladium. Apparently, sulfur-reducing bacteria utilize the hydrogen produced by the Pd/Fe process and reduce the sulfate that is present. An anion exchange column was used to remove sulfate (20 mg/l) from groundwater at the Kansas City Plant in order to test this theory. Under these conditions, a column of Pd/Fe was repetitively regenerated for a 4-week period. A second column, not protected by sulfate removal, could not be regenerated. The results demonstrated that Pd/Fe could be used in a long-term field process if a material with more resistance to Fe and Pd losses is developed. 相似文献
405.
Jader Galba Busato Caroline Moreira de Carvalho Daniel Basilio Zandonadi Fernando Fabriz Sodré Alan Ribeiro Mol Aline Lima de Oliveira Rodrigo Diana Navarro 《Environmental science and pollution research international》2018,25(36):35811-35820
Waste from the beneficiation of fish was composted with crushed grass aiming to characterize their chemical composition and investigate the possibility of the use of the final compost as source of humic acids (HA) able to stimulate the growth of lettuce. Compost presented pH value, C/N ratio, and electrical conductivity that allow its use as an organic fertilizer. The element content was present in the following order of abundance in the compost: P?>?Ca?>?N?>?Mg?>?K?>?Fe?>?Zn?>?Mn?>?Mo?>?Cu, and the humus composition was similar to that observed in others kind of organic residues composted. The high content of oxygen pointed out a high level of oxidation of HA, in line with the predominance of phenolic acidity in the functional groups. The 13C-NMR spectra showed marked resonances due to the presence of lipids and other materials resistant to degradation as methoxy substituent and N-alkyl groups. A concentration of 20 mg L?1 HA increased significantly both dry and wet root matter in lettuce but the CO2 assimilation, stomatal conductance, and number of lateral roots of the plants were not affected. However, increases of 64% in the water-use efficiency was observed due to the HA addition, probably related to the root morphology alteration which resulted in 1.6-fold increase of lateral root average length and due to the higher H+ extrusion activity. Reuse of residues from the fish beneficiation activity by composting may represent a safe tool to increase the value of recycled organic residues and generate HA with potential use as plant growth stimulants. 相似文献
406.
Castilhos Stefani de Souza Fernando Manzotti Colpini Leda Maria Saragiotto de Mattos Jorge Luiz Mario dos Santos Onélia Aparecida Andreo 《Environmental science and pollution research international》2020,27(18):22155-22168
Environmental Science and Pollution Research - The presence of endocrine disrupting compounds in water receptor bodies, such as drugs, currently has in scientific field a great focus of studies... 相似文献
407.
Adeyemi Joseph A. Gallimberti Matheus Olise Christian C. Rocha Bruno Alves Adedire Chrs O. Barbosa Jr Fernando 《Environmental science and pollution research international》2020,27(30):37645-37649
Environmental Science and Pollution Research - Bisphenol A (BPA) is a high production volume chemical that has wide industrial applications, especially as a color developer in thermal papers. The... 相似文献
408.
409.
Mymrin Vsevolod Alekseev Kirill Klitzke Walderson de Evaniki Daniela Pedroso Cleber L. Passig Fernando H. Carvalho Karina Q. Haminiuk Charles W. I. Catai Rodrigo E. 《Journal of Material Cycles and Waste Management》2023,25(3):1549-1559
Journal of Material Cycles and Waste Management - This paper reports the development and characterization of new ceramics from hazardous bauxite red mud (50... 相似文献
410.
Peña-García A de Oña Lopez R Espín Estrella A Aznar Dols F Calvo Poyo FJ Molero Mesa E de Oña López J 《Journal of Safety Research》2010,41(5):385-389