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131.
Cachada A Pereira ME Ferreira da Silva E Duarte AC 《Environmental monitoring and assessment》2012,184(1):15-32
Urban and industrial development has caused a major impact on environmental soil quality. This work assesses the extent and
severity of contamination in a small urban area subjected to an industrial impact and identifies the major anthropogenic inputs.
Twenty-six soil samples were collected from agricultural and urban sites, and concentrations of potentially toxic elements
(As, Cd, Cu, Cr, Fe, Mn, Ni, Pb and Zn), PAHs and PCBs, were determined. In spite of the low median concentrations observed,
some sites represent a potential hazard for human health and ecosystems. Concentrations of contaminants were higher than those
found in a nearby city, indicating that the study area is affected by the surrounding industry. The use of multivariate statistical
analyses allowed for the identification of the main factors controlling the variability of potentially toxic elements and
organic pollutants in the soils. The presence of Cr, Fe, Mn and Ni was associated with geogenic inputs, and Cu, Pb, Zn, As,
PAHs and PCBs were associated with anthropogenic inputs. Industry and traffic were the most important anthropogenic sources.
Soil characteristics were identified as important factors controlling the spatial variability of elements, both from recognised
natural and anthropogenic origin. Differences between land uses were observed, which may be attributed to both management
practices and proximity to sources. 相似文献
132.
Major inputs and mobility of potentially toxic elements contamination in urban areas 总被引:1,自引:0,他引:1
A. Cachada A. C. Dias P. Pato C. Mieiro T. Rocha-Santos M. E. Pereira E. Ferreira da Silva A. C. Duarte 《Environmental monitoring and assessment》2013,185(1):279-294
Soil quality in urban areas is affected by anthropogenic activities, posing a risk to human health and ecosystems. Since the pseudo-total concentrations of potentially toxic elements may not reflect their potential risks, the study of element mobility is very important on a risk assessment basis. This study aims at characterising the distribution and major sources of 34 elements in two Portuguese urban areas (Lisbon and Viseu), with different geological characteristics, industrial and urban development processes. Furthermore, the potential availability of As, Co, Cr, Cu, Ni, Pb and Zn was assessed, by measuring the fraction easily mobilised. Lisbon is enriched in elements of geogenic and anthropogenic origin, whereas in the smaller city, the high levels observed are mainly related to a geogenic origin. Background values can be more relevant than the dimension of the city, even when anthropogenic components may be present, and this parameter should be considered when comparing results from different cities. Regarding the potential available fraction, a high variability of results was observed for elements and for sampling sites with an influence of the soil’s general characteristics. Elements showing very high concentrations due to geological reasons presented, in general, a low mobility and it was not dependent on the degree of contamination. For elements with major anthropogenic origin, only Zn was dependent on the pseudo-total content. Yet, the highest available fractions of some elements, both with major geogenic and anthropogenic origin, were observed in specific contaminated samples. Therefore, a site-specific evaluation in urban soils is important due to the high spatial variability and heterogeneity. 相似文献
133.
Nádia Hortense Torres Mario Mamede Aguiar Luiz Fernando Romanholo Ferreira Juliana Heloisa Pinê Américo Ângela Maria Machado Eliane Bezerra Cavalcanti Valdemar Luiz Tornisielo 《Environmental monitoring and assessment》2015,187(6):379
The growing use of pharmaceutical drug is mainly due to several diseases in human and in animal husbandry. As these drugs are discharged into waterways via wastewater, they cause a major impact on the environment. Many of these drugs are hormones; in which even at low concentrations can alter metabolic and physiological functions in many organisms. Hormones were found in surface water, groundwater, soil, and sediment at concentrations from nanograms to milligrams per liter of volume—quantities known to cause changes in the endocrine system of aquatic organisms. This study aimed to develop a methodology for hormone detection (estriol, estrone, 17β-estradiol, 17α-ethinylestradiol, progesterone, and testosterone) on surface and treated water samples. Sample toxicity was assessed by ecotoxicology tests using Daphnia magna. A liquid chromatograph coupled to a mass spectrometer with an electrospray ionization source (LC-ESI-MS/MS) was used for the analysis. The results showed that samples were contaminated by the hormones estriol, estrone, progesterone, 17β-estradiol, and 17α-ethinylestradiol during the sampling period, and the highest concentrations measured were 90, 28, 26, 137, and 194 ng·L?1, respectively. This indicates the inflow of sewage containing these hormones at some points in the Piracicaba River in the State of Sao Paulo—Brazil. Results indicated little toxicity of the hormone estriol in D. magna, indicating that chronic studies with this microcrustacean are necessary. 相似文献
134.
Evaluation of stream ecological integrity using litter decomposition and benthic invertebrates 总被引:1,自引:0,他引:1
Biomonitoring programs to access the ecological integrity of freshwaters tend to rely exclusively on structural parameters. Here we evaluated stream ecological integrity using (a) benthic macroinvertebrate derived metrics and a biotic index as measures of structural integrity and (b) oak litter decomposition and associated fungal sporulation rates as measures of functional integrity. The study was done at four sites (S1, S2, S3 and S4) along a downstream increasing phosphorus and habitat degradation gradient in a small stream. The biotic index, invertebrate metrics, invertebrate and fungal communities' structure and sporulation rates discriminated upstream and downstream sites. Decomposition rates classified sites S4 and S2 as having a compromised ecosystem functioning. Although both functional and structural approaches gave the same results for the most impacted site (S4), they were complementary for moderately impacted sites (S2 and S3), and we therefore support the need for incorporating functional measures in evaluations of stream ecological integrity. 相似文献
135.
P. Coelho S. Costa C. Costa S. Silva A. Walter J. Ranville M. R. Pastorinho C. Harrington A. Taylor V. Dall’Armi R. Zoffoli C. Candeias E. Ferreira da Silva S. Bonassi B. Laffon J. P. Teixeira 《Environmental geochemistry and health》2014,36(2):255-269
In the Panasqueira mine area of central Portugal, some environmental media show higher metal(loid) concentrations when compared with the local geochemical background and the values proposed in the literature for these environmental media. In order to evaluate the effect of the external contamination on selected indexes of internal dose, As, Cd, Cu, Cr, Fe, Hg, Mg, Mn, Mo, Ni, Pb, S, Se, Si, and Zn were quantified by inductively coupled plasma mass spectrometry and inductively coupled plasma optical emission spectrometry in blood, urine, hair and nail samples from individuals environmentally (N = 41) and occupationally exposed (N = 41). A matched control group (N = 40) was also studied, and data from the three groups were compared. Results obtained agreed with those reported by environmental studies performed in this area, pointing to populations living nearby and working in the mine being exposed to metal(loid)s originated from mining activities. Arsenic was the element with the highest increase in exposed populations. The concentration of other elements such as Cr, Mg, Mn, Mo, Ni, Pb, S, Se, and Zn was also increased, although at a lesser extent, specifically in the individuals environmentally exposed and in females. These findings confirm the need for competent authorities to act as soon as possible in this area and implement strategies aimed to protect exposed populations and the entire ecosystem. 相似文献
136.
Samuel Niza Daniela Ferreira Joana Mourão Patrícia Bento d’Almeida Teresa Marat-Mendes 《Regional Environmental Change》2016,16(6):1725-1737
The consumption and production of food products in the municipality of Lisbon in the 1890–1900 decade is assessed with the support of historical cartography and statistical resources. For the first time, food production in a municipality in the turn to the twentieth century is accounted and simultaneously subject of a visual analysis of the land used for agriculture and of the water infrastructures that supported such uses. Agriculture occupied at least 40 % of the territory of the city, while the built environment occupied no more than 16 % of the territory. However, local production of food was far from supplying most of the citizens’ needs, and substantial food imports were needed. In this context, the municipality behaved like a heterotrophic system, highly dependent on the external supply of resources. Moreover, comparing to other European cities at the time Lisbon was facing in the end of the nineteenth century a late and slow transition from an agrarian social metabolism to an industrial one, suggesting that Lisbon was still relatively high-solar-powered as compared to other European cities at the time that were already highly fossil-fuel-powered. 相似文献
137.
Francisco Ferreira de Campos Jacinta Enzweiler 《Environmental monitoring and assessment》2016,188(5):281
The concentrations of rare earth elements (REE), measured in water samples from Atibaia River and its tributary Anhumas Creek, Brazil, present excess of dissolved gadolinium. Such anthropogenic anomalies of Gd in water, already described in other parts of the world, result from the use of stable and soluble Gd chelates as contrast agents in magnetic resonance imaging. Atibaia River constitutes the main water supply of Campinas Metropolitan area, and its basin receives wastewater effluents. The REE concentrations in water samples were determined in 0.22-μm pore size filtered samples, without and after preconcentration by solid-phase extraction with bis-(2-ethyl-hexyl)-phosphate. This preconcentration method was unable to retain the anthropogenic Gd quantitatively. The probable reason is that the Gd chelates dissociate slowly in acidic media to produce the free ion that is retained by the phosphate ester. Strong correlations between Gd and constituents or parameters associated with effluents confirmed the source of most Gd in water samples as anthropogenic. The shale-normalized REE patterns of Atibaia River and Anhumas Creek water samples showed light and heavy REE enrichment trends, respectively. Also, positive Ce anomalies in many Atibaia River samples, as well as the strong correlations of the REE (except Gd) with terrigenous elements, imply that inorganic colloidal particles contributed to the REE measured values. 相似文献
138.
139.
Maísa Tatiane Ferreira de Souza Elizangela Ambrosio Cibele Andrade de Almeida Thábata Karoliny Formicoli de Souza Freitas Lídia Brizola Santos Vitor de Cinque Almeida Juliana Carla Garcia 《Environmental monitoring and assessment》2014,186(8):5261-5271
The goal of this study was to investigate the activity of the coagulant extracted from the cactus Opuntia ficus-indica (OFI) in the process of coagulation/flocculation of textile effluents. Preliminary tests of a kaolinite suspension achieved maximum turbidity removal of 95 % using an NaCl extraction solution. Optimization assays were conducted with actual effluents using the response surface methodology (RSM) based on the Box–Behnken experimental design. The responses of the variables FeCl3, dosage, cactus dosage, and pH in the removal of COD and turbidity from both effluents were investigated. The optimum conditions determined for jeans washing laundry effluent were the following: FeCl3 160 mg L?1, cactus dosage 2.60 mg L?1, and pH 5.0. For the fabric dyeing effluent, the optimum conditions were the following: FeCl3 640 mg L?1, cactus dosage 160 mg L?1, and pH 6.0. Investigation of the effects of the storage time and temperature of the cactus O. ficus-indica showed that coagulation efficiency was not significantly affected for storage at room temperature for up to 4 days. 相似文献
140.
Hilda Granda Suzana Gispert Gisela Martinez Manuel Gomez Raul Ferreira Teresa Collazo Carlos Magariño Luis Heredero 《黑龙江环境通报》1994,14(8):659-662
A nationwide programme for the prevention of sickle cell (SS and SC) disorders was initiated in Cuba in 1983. Couples at risk were identified by screening pregnant women and the partners of those who carry an abnormal haemoglobin, followed by genetic counselling and the offer of prenatal diagnosis. Prenatal diagnosis was performed in one laboratory, which had carried out 1068 prenatal tests for Hb SS and SC disorders by the end of 1992. The centralization of the service has permitted rapid identification and resolution of problems. 相似文献