Legumes are ideal for revegetation of metal-mined wastelands which lack nitrogen (N). A greenhouse study was conducted to investigate the feasibility of using Sesbania rostrata and S. cannabina for the reclamation of lead/zinc (Pb/Zn) mine tailings and to evaluate the effects of organic amendment using sewage sludge (0%, 25%, 50%, and 75%, v/v). The results showed that both species could continue to grow on the highly toxic tailings substrata for at least 80 days, although their growth suffered from adverse effects. That S. rostrata with stem and root nodules had better growth (biomass, growth rates, and biomass of nodules) than S. cannabina suggested that S. rostrata is a better choice as a pioneer species for revegetation of the mine tailings. Stem nodules had less obvious adverse effects imposed by tailings than root nodules. Application of sewage sludge increased contents of total carbon (C), N, phosphorus (P), and potassium (K), and reduced total Zn, Pb, Cd, and DTPA-extractable Pb and Cd in tailings substrata. These, in turn, reduced metal (Zn, Pb, and Cd) uptake and accumulation in plant tissues, and improved plant growth performance, including biomass, growth rates, stem nodulation. Fifty percent (v/v) of sludge application rate was the best loading rate for plant growth. 相似文献
Environmental Science and Pollution Research - Metabolic syndrome (MetS) is an immense health issue that causes serious complications in aging males including BPH. Icariin (ICA) is a flavonol... 相似文献
Environmental Science and Pollution Research - Azolla is a group of aquatic floating plants that can achieve very high growth rates compared to other aquatic macrophytes, with a doubling time of... 相似文献
East Africa has enormous renewable energy potential, but only a small portion of it has been exploited, and little is known on its role in improving environmental quality. Thus, this study empirically examines the impact of renewable energy on the environment using ecological footprint (EF; positive indicator) and CO2 emissions (negative indicator) as proxy indicators for environmental quality in a panel of ten East African countries from 1990 to 2015. These indicators were chosen due to their potential impact in the environment. The work used the pooled mean group (PMG) as the main panel estimator to determine the impact while controlling non-renewable energy consumption, GDP per capita, and foreign direct investment (FDI). PMG has been used as it forces the long-run coefficients to be equal across all panel groups. The findings show that in the long run, there is a significant negative relationship between CO2 emissions and renewable energy consumption, as well as a significant positive relationship (with a low impact) between EF and renewable energy consumption, suggesting that renewable energy use enhances the area’s environmental quality. Also, results indicate that non-renewable energy use degrades environmental quality in both metrics, whereas GDP degrades environmental quality through CO2 emissions and improves environmental quality through EF. This requires East African countries to focus a higher emphasis on accessible renewable energy sources to achieve quick and sustainable economic growth and minimize environmental effects. To accomplish this, strategic policies and legislation, as well as the promotion of green technology, are required.
Waste incineration bottom ash and treated flue gas cleaning products mixed with 2.5% of cement (50 kg/m3) were tested in the laboratory in terms of compressive strength and tank leaching tests over a 64-day period. Although the material displayed lower mechanical strength than a reference concrete, the strength still was sufficient for use as a base layer for roads. The metal content in the incineration-residue-based specimens was up to 100 times higher than in the reference concrete, suggesting that the mixed waste incineration residue should be used only for dedicated purposes. The leaching of Cl and Na was increased by a factor of 20-100 from the incineration-residue-based specimens as compared to the reference, while the leaching of K, Ca and SO4 was increased by a factor of 2-10. The leaching of heavy metals was also higher from the incineration-residue-based specimens than from the reference with respect to Cu (50 times), Cd, Pb and Zn (5 times), but not with respect to Cr and Ni. The leaching curves did only allow for a closer evaluation of the leaching process in a few cases. The physical retention of the constituents seemed to be the same in the reference as in the incineration-residue-based specimens. Heavy metal leaching was limited by enhanced chemical retention in the incineration-residue-specimens as compared to the reference. Since no quality criteria in terms of leaching from a monolithic material are currently available, the leaching issue must be evaluated case by case. 相似文献
The corrosion layer on steel surfaces that formed after exposure to waste isolation pilot plant (WIPP) brines under anoxic conditions was characterized for chemical composition, thickness and phase composition. The chemical composition of the corrosion layer was determined both by X-ray photoelectron spectroscopy (XPS) and by chemical analysis of acid solutions used to remove the corrosion layer. Atomic force microscopic (AFM) images indicated that the brine-corroded surface layer shows extensive granulation along the contours of the steel surface that is characteristic of sharp polishing marks. The corrosion layer seemed to be porous and could be dissolved and detached in dilute hydrochloric acid. The corrosion layer appears to be composed of iron oxides with some ionic substitutions from the brines. The 77 K M?ssbauer spectrum recorded for iron powder leached under similar conditions indicated the corrosion layer was comprised principally of green rust. 相似文献
Numerous studies have reported a positive association between ambient fine particles and daily mortality, but little is known about the particle properties or environmental factors that may contribute to these effects. This study assessed potential modification of radon on PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm)-associated daily mortality in 108 U.S. cities using a two-stage statistical approach. First, city- and season-specific PM2.5 mortality risks were estimated using over-dispersed Poisson regression models. These PM2.5 effect estimates were then regressed against mean city-level residential radon concentrations to estimate overall PM2.5 effects and potential modification by radon. Radon exposure estimates based on measured short-term basement concentrations and modeled long-term living-area concentrations were both assessed. Exposure to PM2.5 was associated with total, cardiovascular, and respiratory mortality in both the spring and the fall. In addition, higher mean city-level radon concentrations increased PM2.5-associated mortality in the spring and fall. For example, a 10 µg/m3 increase in PM2.5 in the spring at the 10th percentile of city-averaged short-term radon concentrations (21.1 Bq/m3) was associated with a 1.92% increase in total mortality (95% CI: 1.29, 2.55), whereas the same PM2.5 exposure at the 90th radon percentile (234.2 Bq/m3) was associated with a 3.73% increase in total mortality (95% CI: 2.87, 4.59). Results were robust to adjustment for spatial confounders, including average planetary boundary height, population age, percent poverty and tobacco use. While additional research is necessary, this study suggests that radon enhances PM2.5 mortality. This is of significant regulatory importance, as effective regulation should consider the increased risk for particle mortality in cities with higher radon levels.
Implications: In this large national study, city-averaged indoor radon concentration was a significant effect modifier of PM2.5-associated total, cardiovascular, and respiratory mortality risk in the spring and fall. These results suggest that radon may enhance PM2.5-associated mortality. In addition, local radon concentrations partially explain the significant variability in PM2.5 effect estimates across U.S. cities, noted in this and previous studies. Although the concept of PM as a vector for radon progeny is feasible, additional research is needed on the noncancer health effects of radon and its potential interaction with PM. Future air quality regulations may need to consider the increased risk for particle mortality in cities with higher radon levels. 相似文献
Acid mine drainage from mine tailings at Selebi Phikwe, eastern Botswana, has been investigated using a combination of total decomposition, sequential extraction, X-ray diffraction, Mössbauer spectroscopy, and SEM analyses of solid phase samples, water analyses, isotopic analyses, and geochemical modeling. The principal ferric phases in the seepage stream sediments are jarosite and goethite, which incorporate Ni and Cu. The Mössbauer spectroscopy (MS) indicated exclusively 3+ oxidation state of iron with typical features of ferric hydroxides/sulfates. A fraction of dissolved sulfate is also sequestered in gypsum which precipitates further downstream. Significant portions of Fe, Ni, and Cu are transported in suspension. Values of pH decreased downstream due to H+ generated by the precipitation of jarosite. Values of δ2H and δ18O indicate evaporation of pore water in the mine tailings before seepage. Values of δ34S(SO4) are consistent with the oxidation of sulfides, but sample from the seepage face is affected by dissolution of gypsum. No minerals of Ni and Cu were detected and the principal attenuation processes seem to be adsorption and co-precipitation with jarosite. Higher contents of Cu are sequestered in solid phases compared to Ni, in spite of much higher dissolved Ni concentrations. Based on the speciation calculations, seepage water is undersaturated with respect to all Ni and Cu phases and adsorption and co-precipitation with jarosite seems to be the principal attenuation processes. Direct geochemical modeling was able to reproduce downstream pH trends, thus confirming the precipitation of jarosite as the principal pH-controlling process. 相似文献
This paper investigates the effects of topographic heterogeneity on the runoff response simulated by a 0.05 degree (approximately 5.5 km) spatial resolution distributed hydrological model for the Pahang, Kelantan, and Muda river basins (25,600, 11,900, and 4010 km2, respectively) in Peninsular Malaysia. Daily simulations were carried out and assessed against observed streamflow for the period 1999–2004. Topographic structure was characterized by means of subgrid terrain slope to guide the decomposition of hydrological parameters over the model grid. The results show improved simulation skill for all three basins compared to a traditional runoff production parameterization scheme that does not take into account the subgrid topographic variability. However, other factors related to morphological heterogeneity and variability in physical terrain conditions should be considered in future work in order to characterize the hydrological heterogeneity. The present methodology may be of potential for further development of large-scale, coarse resolution grid-based hydrological models without adding structural model complexity and without affecting parameter parsimony. 相似文献