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61.
The use of ion exchange technology was studied to remove chromium (III) from acidic waste solution by Amberlite IR-120 resin. Batch and column experimental tests were conducted to provide data for theoretical models and verify the system performance of the adsorption process. Results of batch equilibrium tests indicated that Langmuir isotherm describes well the adsorption process, whereas experimental data also provide evidence that, under the present experimental conditions, chromium (III) adsorption by Amberlite IR-120 resin is film-diffusion controlled; on the other hand, the theoretical model used in the present investigation was found to predict reasonably well the ion exchange breakthrough performance. 相似文献
62.
Jos L. Mateos Paloma Fern ndez Del Pino Francisco J. Guti rrez Ma ero Marí a Ruiz Palomino Juan J. Colon Jos A. Lucas Garcí a Agustí n Probanza 《Chemistry and Ecology》2000,17(2):125-152
Microbial communities (phospholipid fatty acid pattern, bacterial growing strategies, eco-physiological index (EPI) and total bacteria counts, as a number of heterotrophic cuhurable bacteria), substrate-induced respiration (SIR), and nitrogen mineralization were studied in three Mediterranean soils at three different depth levels (A, B and C). Soils were experimentally treated with a final concentration of 1000 ppm of trace metals (Cu2+, Zn2+, Al3+, Fe2+, Pb2+, Ni2+, Mn2+, Cr3+ and Cd2+). Soils were stored in 571 plastic containers for one year, and watered with 1001 during this period. Leachate was recovered through a bottom tap. Samples of the three depths were studied. Soil microbial communities showed different effects to other studies presented in the literature, but carried out on non-Mediterranean soils. Dramatic differences were found between treated soils and untreated ones, but not between soils or horizons. the treated soil displayed a decrease in CFUs, SIR N-mineralization and EPI together with a dominance of r-growing strategists. the relative moles percent of several PLFAs, especially 15:0, 16: 1ω7, cy17: 0, br18:0 and 18: 1ω7 decreased because of the pollution of soils, whereas 10Me16, 18:2ω6, cy19:0, i16:0 and br17:0 showed higher values than in untreated soils. 相似文献
63.
Reis AP Patinha C Ferreira da Silva E Sousa AJ 《Environmental geochemistry and health》2012,34(2):229-241
The Marrancos gold mineralisation has a chemical assemblage of Fe–As–Se–Bi–Au–Ag–Te–(Cu–Pb–Zn–Sn–W). The −200 mesh of 144
topsoil samples was analysed by ICP–MS to determine total contents of 53 elements that include potentially harmful elements
like Cd, As and Pb. The soil geochemistry shows that some trace elements occur in considerably high concentrations. On the
basis of data for total metal concentrations, 10 topsoil samples were selected to carry out a metal fractionation study using
a selective extraction method. A set of four leaches of increasing strength was used sequentially in the soil samples. Across
the study area, there is some evidence of past mining and exploration activity, indicating that these soils may be locally
disturbed. The shallow mineralised quartz veins were exploited for gold by the Romans. Several galleries were constructed
during the 2nd World War, probably for the exploration of quartz–cassiterite–wolframite veins. However, the main mineralised
body in depth was never explored. The results of metal fractionation show different partitions for the three elements. Total
Cd concentrations in these soils are low, with a median value of 0.1 mg/kg. In average, 12% of total Cd is adsorbed by clays
and/or co-precipitated with carbonates, and 19% is bounded to Fe–Mn oxyhydroxides. However, the low concentrations indicate
that the metal does not represent an immediate risk to human health. For Pb, metal fractionation shows that, on average, 22%
of Pb is adsorbed by amorphous Fe and Mn oxides, but the samples from the northern part of the area have the major fractions
of Pb in soluble forms. The low probability of exposure in this part of the study area decreases the risk posed by this heavy
metal. Total As concentrations in the Marrancos soils are extremely high. A large area has As concentrations above 1,000 mg/kg.
For As, metal fractions in the sulphide phase vary between 84 and 98% in the studied samples. But one sample has 20% of total
As in easily reducible forms, corresponding to a partial concentration of 1,800 mg/kg that has a high probability of being
bioavailable. The most labile As forms occur at the southern part of the area, where the probability of exposure is higher
and the risk of human health increases in the same order. From the three studied potentially harmful elements, As is certainly
the element of concern. 相似文献
64.
Gilad Heinisch Aldo Corriero Antonio Medina Francisco J. Abascal Jose-Miguel de la Serna Robert Vassallo-Agius Antonio Belmonte Ríos Antonio García Fernando de la Gándara Christian Fauvel Christopher R. Bridges Constantinos C. Mylonas Saadet F. Karakulak Isik Oray Gregorio De Metrio Hanna Rosenfeld Hillel Gordin 《Marine Biology》2008,154(4):623-630
Atlantic bluefin tuna (BFT; Thunnus thynnus) is a migrating species straddling the North Atlantic Ocean and Mediterranean Sea. It is assumed that this species is divided
into a western and an eastern stock, which spawn in the Gulf of Mexico and the Mediterranean Sea, respectively. To learn more
about the reproductive behavior of the eastern BFT stock, we tracked gonadal development in adult fish that were sampled between
April and July during three consecutive years (2003–2005). Sampling campaigns were carried out using common fishing methods
at selected locations within the Mediterranean Sea, namely Levantine Sea, Malta, and Balearic Islands. An additional sampling
point, Barbate, was situated northwest of the Straits of Gibraltar along the Atlantic coast. Morphometric parameters such
as the total body mass (M
B) and the weights of the gonads (M
G) were recorded, and the respective gonadosomatic index (GSI) values were calculated. The data collected revealed two important
trends: (1) GSI values are higher in fish caught in the eastern rather than the western locations across the Mediterranean
Sea, and (2) the GSI reaches maximum values between late May and early June in Levantine Sea (eastern Mediterranean Sea),
and only 2 and 4 weeks later in the central (Malta) and western (Balearic Islands) locations, respectively. The advanced gonadal
development in BFT correlates well with higher sea surface temperatures. Our findings also distinguish the northern Levantine
Sea BFT population (mean M
B 78.41 ± 4.13 kg), and the Barbate BFT population with the greatest M
B (all fish sampled > 100 kg). These data reflect a situation in which the eastern Mediterranean basin may function as a habitat
for young BFT, until they gain a larger M
B and are able to move to the Atlantic Ocean. However, the existence of genetically discrete BFT populations in the Mediterranean
Sea cannot be ruled out. 相似文献
65.
Santos Luciane Cavalcante da Silva Anamália Ferreira dos Santos Lins Pollyanna Vanessa da Silva Duarte José Leandro Ide Alessandra Honjo Meili Lucas 《Environmental science and pollution research international》2020,27(6):5890-5900
Environmental Science and Pollution Research - Mg-Fe layered double hydroxide intercalated with chloride (Mg-Fe-Cl LDH) was synthetized, characterized, and evaluated as adsorbent to remove nitrate... 相似文献
66.
Guimarães Barbara Maria Ribeiro Scatolino Mário Vanoli Martins Maria Alice Ferreira Saulo Rocha Mendes Lourival Marin Lima José Tarcísio Junior Mario Guimarães Tonoli Gustavo Henrique Denzin 《Environmental science and pollution research international》2022,29(6):8665-8683
Environmental Science and Pollution Research - The growing demand for products with lower environmental impact and the extensive applicability of cellulose nanofibrils (CNFs) have received... 相似文献
67.
68.
Gama Nuno Godinho B. Barros-Timmons Ana Ferreira Artur 《Journal of Polymers and the Environment》2022,30(4):1451-1461
Journal of Polymers and the Environment - Aiming at minimizing the issues associated with the disposal of polymers, in this study, elastomeric materials derived from 100% recycled feedstocks were... 相似文献
69.
Large and mesoscale meteo-oceanographic patterns in local responses of biogeochemical concentrations
de Oliveira MM Pereira GC de Oliveira JL Ebecken NF 《Environmental monitoring and assessment》2012,184(11):6935-6956
Investigations surrounding the variability of productivity in upwelling regions are necessary for a better understanding the physical-biological coupling in these regions by monitoring systems of environmental impacts according to the needs of the regional coastal management. Using a spatial and temporal database from National Centers for Environmental Prediction (NCEP) and National Center for Atmospheric (NCAR) Research reanalysis, Quick Scatterometer vector wind, and surface stations from the Southeast coast of Brazil, we investigate the meteorological influences due to the large-scale systems in the variability of the nutrient and larvae concentration, and chlorophyll a, describing statistically relationships between them in upwelling regions. In addition, we used multivariate analysis, such as PCA and clustering to verify spatial and temporal variances and describe more clear the structure and composition of the ecosystem. Correlation matrix analyses were applied for different water masses present in the study area to identify the relations between physical and biogeochemical parameters in a region, where frequently upwelling occur. Statistical approaches and seasonal variability show that the period of November to March is more sensitive to nutrients (1.20?mg/m(3) for chlorophyll a, 2.20?μmol/l for total nitrogen and 5.5?ml/l for DO) and larvae concentrations (120 org/m(3) for most of the larvae, except for cirripedia that presented values around 370 org/m(3)) relating to the influence of large and mesoescale meteorological patterns. The spatial and temporal variables analyzed with multivariate approach show meaningful seasonality variance of the physical and biological samples, characterizing the principal components responsible for this variance in spring and summer (upwelling period), emphasizing the monitoring of species as crustaceans and mussels that are present in the local economy. Then, the spring and summer season are characterized by high productivity due to the occurrence of upwelling in this period. 相似文献
70.
Assessment of Eutrophication in Estuaries: Pressure–State–Response and Nitrogen Source Apportionment 总被引:1,自引:0,他引:1
Whitall D Bricker S Ferreira J Nobre AM Simas T Silva M 《Environmental management》2007,40(4):678-690
A eutrophication assessment method was developed as part of the National Estuarine Eutrophication Assessment (NEEA) Program.
The program is designed to improve monitoring and assessment of eutrophication in the estuaries and coastal bays of the United
States with the intent to guide management plans and develop analytical and research models and tools for managers. These
tools will help guide and improve management success for estuaries and coastal resources. The assessment method, a Pressure-State-Response
approach, uses a simple model to determine Pressure and statistical criteria for indicator variables (where applicable) to
determine State. The Response determination is mostly heuristic, although research models are being developed to improve that
component. The three components are determined individually and then combined into a single rating. Application to several
systems in the European Union (E.U.), specifically in Portugal, shows that the method is transferable, and thus is useful
for development of management measures in both the Unites States and E.U. This approach identifies and quantifies the key
anthropogenic nutrient input sources to estuaries so that management measures can target inputs for maximum effect. Because
nitrogen is often the limiting nutrient in estuarine systems, examples of source identification and quantification for nitrogen
have been developed for 11 coastal watersheds on the U.S. east coast using the WATERSN model. In general, estuaries in the
Northeastern United States receive most of their nitrogen from human sewage, followed by atmospheric deposition. This is in
contrast to some watersheds in the Mid-Atlantic (Chesapeake Bay) and South Atlantic (Pamlico Sound), which receive most of
their nitrogen from agricultural runoff. Source identification is important for implementing effective management measures
that should be monitored for success using assessment methods, as described herein. For instance, these results suggest that
Northeastern estuaries would likely benefit most from improved sewage treatment, where as the Mid and South Atlantic systems
would benefit most from agricultural runoff reductions. 相似文献