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11.
Masaaki Fukushima Misao Shioya Keiji Wakai Hidetoshi Ibe 《Journal of Material Cycles and Waste Management》2009,11(1):11-18
Sapporo Plastics Recycling Co., Ltd., (SPR) started its commercial operation of waste plastics liquefaction in 2000. At first
only hydrocarbon oil was reclaimed, this being derived from the waste plastics liquefaction process under the Japanese Containers
and Packaging Recycling Law. Presently, thermal degradation residue and hydrochloric acid are being produced as by-products
in addition to the hydrocarbon oil. As a result, the SPR plastics liquefaction plant has achieved a high reclamation rate
of 96%, and 93% of the recycled products have been reused in Hokkaido, where SPR is located. The technical problems caused
by corrosion and clogging have been solved.
Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6 相似文献
12.
Haruhiro Ino Yoshihisa Matsumoto Ryo Takahashi Kazukiyo Takami Junya Nishino Masaaki Itoh 《Journal of Material Cycles and Waste Management》2008,10(2):129-133
H-ZSM-5 zeolite-supported gallium oxides were studied as aromatization catalysts for polyolefin pyrolysate. The catalysts
were prepared by a conventional physical mixing method with a gallium content of 1.0 and 4.5 wt% and were reduced in flowing
hydrogen at 585°C. To test their activity, a polyolefin sample was pyrolyzed and passed over a heated catalyst layer; the
product was analyzed by gas chromatography/mass spectrometry. A continuous-flow fixed-bed reactor was used for aromatization
of a model gas of polyolefin pyrolysate. For chlorine-free sources at 450°C, the catalyst with only 1.0 wt% gallium exhibited
activity comparable to a gallium silicate catalyst. For chlorine-contaminated sources, the catalyst with 4.5 wt% gallium sustained
catalytic activity for long periods. From the activity test results, it was found that zeolite-supported gallium catalysts
prepared by the physical mixing method are suitable for converting polyolefin into aromatic hydrocarbons. 相似文献
13.
cis-Chlordane, trans-chlordane, and heptachlor were photodegraded in ethanol, and their degradation fates and degradation products were determined by a computational chemical method. The most degradable material was heptachlor (first-order reaction constant k=0.13 min(-1)). Chlorine balances changed during UV irradiation, and the chlorine atoms in chlordane and heptachlor were eventually mineralized. cis-Chlordane, trans-chlordane and heptachlor each generated two di-dechlorinated products. Reactivities at various positions in these compounds were predicted on the basis of bond dissociation energies calculated by nonempirical molecular orbital calculation (Gaussian 98W). 相似文献
14.
Polychlorinated dibenzothiophenes (PCDTs) in sediment, soil, and fly ash samples collected in Japan were analyzed and their dioxin-like endocrine-disruption potential and photodegradability investigated. PCDTs were detected in all three types of sample, although the concentrations were lower than those of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). An Ah-immunoassay confirmed that 2,3,7,8-TeCDT, 1,2,3,7,8-PeCDT, 1,2,3,7,8,9-HxCDT, and 1,2,3,4,7,8,9-HpCDT had Ah receptor-binding activities, which means that these PCDTs have the potential to cause dioxin-like endocrine-disruption. Photodegradation of PCDTs by UV irradiation was accompanied by dechlorination. The photodegradation rates of 2,3,7,8-TeCDT and OCDT were lower than the rates for the corresponding PCDF isomers (2,3,7,8-TeCDF and OCDF), which indicates that PCDTs are more stable than PCDFs to photodegradation. 相似文献
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16.
The relationship between the content of various forms of phosphorus in lakesediments and the amount of phosphorus released under aerobic and anaerobic conditions was studied. Total phosphorus content in the sediment of Lake Kasumigaura was highest at the 0–5 cm surface layer and decreased with depth. The constant value below 15 cm was consistent with the decrease of iron-bound phosphorus conent (FeP). The amount of phosphorus released from the sediments was proportional to the decrease of FeP under both aerobic and anaerobic conditions. Under anaerobic conditions, 90% of the FeP initially held in the sediments was released in 55 days. Using dialysis apparatus, maximum growth yield of algae was shown to be linearly dependent on the amount of phosphorus released under aerobic conditions. 相似文献
17.
Sano Daisuke Watanabe Ryosuke Oishi Wakana Amarasiri Mohan Kitajima Masaaki Okabe Satoshi 《Food and environmental virology》2021,13(1):84-92
Food and Environmental Virology - This study investigated the influence of viral interference on the detection of enteric viruses using the integrated cell culture (ICC)-PCR with a BGM cell line.... 相似文献
18.
Satoshi Nakai Anri Yamamura Shou Tanaka Jianghong Shi Megumi Nishikawa Yutaka Nakashimada Masaaki Hosomi 《Environmental Chemistry Letters》2011,9(1):1-6
In recent years, natural and synthetic estrogens have been recognized as endocrine disruptors in aquatic organisms. Although
natural and synthetic estrogens are known to be degraded by microbes, only limited information about their degradation pathways
is available. Here, we studied the degradation pathways of a natural estrogen, 17β-estradiol, by the nitrifying microorganism
Nitrosomonas europaea, and we determined whether the degradation products of 17β-estradiol had estrogenic activity. To identify the degradation
products, we subjected the culture solution to solid-phase extraction, and the extract was analyzed by gas chromatography–mass
spectrometry. The potential estrogenic activity of the degradation products was investigated by means of a yeast two-hybrid
assay. 1,3,5(10),16-Estratetraen-3-ol (estratetraenol) was newly identified as a degradation intermediate produced by dehydration
of 17β-estradiol. Estratetraenol was also degraded by N. europaea, and its degradation rate was faster than that of 17β-estradiol. The two-hybrid assay confirmed that estratetraenol acted
as a ligand for the estrogen receptor; estratetraenol thus has potential estrogenic activity. N. europaea eliminated the estrogenic activity derived from 17β-estradiol. This paper is the first to report dehydration as a mechanism
of microbial estrogen degradation. 相似文献
19.
Eiji Haramoto Masaaki Kitajima Naohiro Kishida Hiroyuki Katayama Mari Asami Michihiro Akiba 《Food and environmental virology》2012,4(3):93-101
A nationwide survey of viruses, protozoa, and indicator microorganisms in drinking water sources of Japan was conducted. Among 64 surface water samples collected from 16 drinking water treatment plants, 51 (80?%) samples were positive for at least one of the 11 pathogen types tested, including noroviruses of genogroups I (positive rate, 13?%) and II (2?%), human sapoviruses (5?%), human adenoviruses of serotypes 40 and 41 (39?%), Cryptosporidium oocysts (41?%), and Giardia cysts (36?%). Total coliforms, Escherichia coli, and F-specific coliphages were detected in 63 (98?%), 33 (52?%), and 17 (27?%) samples, respectively, and E. coli was judged to be the most suitable indicator of pathogen contamination of drinking water sources. Genogroup-specific real-time PCR for F-specific coliphages revealed the presence of F-specific RNA coliphages of animal genogroup I and human genogroups II and III in 13 (41?%), 12 (39?%), and 1 (3?%), respectively, of 31 plaques isolated. 相似文献
20.
Ou-Sup Han Masaaki Yashima Toei Matsuda Hidenori Matsui Atsumi Miyake Terushige Ogawa 《Journal of Loss Prevention in the Process Industries》2000,13(6):449-457
The structure of flame propagating through lycopodium dust clouds has been investigated experimentally. Upward propagating laminar flames in a vertical duct of 1800 mm height and 150×150 mm square cross-section are observed, and the leading flame front is also visualized using by a high-speed video camera. Although the dust concentration decreases slightly along the height of duct, the leading flame edge propagates upwards at a constant velocity. The maximum upward propagating velocity is 0.50 m/s at a dust concentration of 170 g/m3. Behind the upward propagating flame, some downward propagating flames are also observed. Despite the employment of nearly equal sized particles and its good dispersability and flowability, the reaction zone in lycopodium particles cloud shows the double flame structure in which isolated individual burning particles (0.5–1.0 mm in diameter) and the ball-shaped flames (2–4 mm in diameter; the combustion time of 4–6 ms) surrounding several particles are included. The ball-shaped flame appears as a faint flame in which several luminous spots are distributed, and then it turns into a luminous flame before disappearance. In order to distinguish these ball-shaped flames from others with some exceptions for merged flames, they are defined as independent flames in this study. The flame thickness in a lycopodium dust flame is observed to be 20 mm, about several orders of magnitude higher than that of a premixed gaseous flame. From the microscopic visualization, it was found that the flame front propagating through lycopodium particles is discontinuous and not smooth. 相似文献