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饮用水中含氮消毒副产物卤代腈(氰)的生成特性与控制研究进展 总被引:1,自引:0,他引:1
卤代腈(氰)是水处理过程中产生的一类含氮的氯化消毒副产物。鉴于这种物质有极强的致畸和致突变性,其细胞毒性也远大于三卤甲烷和卤乙酸等常规消毒副产物,因此成为近年来饮用水中颇受关注的含氮消毒副产物种类之一。卤代腈(氰)在水厂出厂水中被大量检出,其质量浓度基本维持在μg/L,而采用氯胺消毒的出厂水中其浓度明显高于自由氯消毒方式。重点对卤代腈(氰)的物质种类、理化特性、遗传毒性、生产机制、检测方法及控制方法进行综述。鉴于多数卤代腈(氰)类消毒副产物均具有含量低、亲水性强等特点,若生成将难以在饮用水处理工艺中有效去除,因此如何有效控制其生成是卤代腈(氰)研究的主要发展方向。 相似文献
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Shouhai Li Chunpeng Wang Fuxiang Chu Jianling Xia Yuzhi Xu 《Journal of Polymers and the Environment》2013,21(4):1072-1082
Two dissimilar renewable resource-based thermoplastic acorn nutlet (TPAN) materials were prepared via twin-screw extrusion with the aid of glycerol or monoethanolamine as plasticizers, and then two TPAN/polycaprolactone (PCL) composites with different plasticized systems were prepared. Mechanical test showed that glycerol-based composites had excellent tensile properties, and at a PCL content of 50 wt%, their tensile strength and elongation at break reached 14.4 MPa and 1,361 %, respectively. The micro-morphologic investigation of liquid-nitrogen brittle fracture surface indicated certain interface adhesion between glycerol-based thermoplastic acorn nutlet (GTPAN) and PCL. Dynamic mechanical thermal analysis , differential scanning calorimetry and thermogravimetric analysis demonstrated that the weight ratios of TPAN in composites significantly affected the crystallinity, glass transition temperature (Tg), melting temperature (Tm) and thermal stability of composites. Soil burial degradation analysis displayed that all composites had excellent biodegradability. These results demonstrated that GTPAN/PCL composites had superior mechanical and biodegradable properties, enough to partially replace the conventional thermoplastic plastics. 相似文献
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树轮异常结构作为反映气候变化的一个重要参数,已被广大生态学家所重视并应用。树轮异常结构包括霜轮、浅轮、伪轮、畸形木材反应木、树脂道、火疤等。这些异常年轮结构与温度、降水、光照等气候因子有着复杂的相关关系。温度对年轮异常结构的影响主要表现在低温对形成层生长的抑制作用,从而形成霜轮、浅轮。生长期内干旱,形成层生长时间短,甚至使形成层生长减慢或停止,从而形成伪轮。高强度的光照会引起高温少雨,加剧旱情的发生,从而导致伪轮。另外,通过对树轮异常结构的分析,可用这些特征来重建森林干扰的历史,如火山喷发、火灾、冰灾、虫害、旱灾、地震等。这些研究在帮助人们了解和研究古气候变化对森林植被的影响,以及预测未来全球变化对陆地生态系统的影响有重要的理论和现实意义。文章综述了气候变化对树轮异常结构的影响的研究进展和应用,并概述了发展前景,希望能加快和拓宽这一领域的发展。 相似文献