全文获取类型
收费全文 | 29759篇 |
免费 | 214篇 |
国内免费 | 139篇 |
专业分类
安全科学 | 475篇 |
废物处理 | 1697篇 |
环保管理 | 3418篇 |
综合类 | 5257篇 |
基础理论 | 7682篇 |
环境理论 | 15篇 |
污染及防治 | 7073篇 |
评价与监测 | 2310篇 |
社会与环境 | 2109篇 |
灾害及防治 | 76篇 |
出版年
2023年 | 108篇 |
2022年 | 234篇 |
2021年 | 270篇 |
2020年 | 142篇 |
2019年 | 192篇 |
2018年 | 1713篇 |
2017年 | 1630篇 |
2016年 | 1618篇 |
2015年 | 529篇 |
2014年 | 629篇 |
2013年 | 1503篇 |
2012年 | 1123篇 |
2011年 | 2149篇 |
2010年 | 1340篇 |
2009年 | 1277篇 |
2008年 | 1724篇 |
2007年 | 2064篇 |
2006年 | 857篇 |
2005年 | 713篇 |
2004年 | 723篇 |
2003年 | 715篇 |
2002年 | 696篇 |
2001年 | 704篇 |
2000年 | 443篇 |
1999年 | 347篇 |
1998年 | 220篇 |
1997年 | 230篇 |
1996年 | 247篇 |
1995年 | 261篇 |
1994年 | 258篇 |
1993年 | 231篇 |
1992年 | 217篇 |
1991年 | 231篇 |
1990年 | 218篇 |
1989年 | 186篇 |
1988年 | 182篇 |
1987年 | 164篇 |
1986年 | 177篇 |
1985年 | 159篇 |
1984年 | 191篇 |
1983年 | 187篇 |
1982年 | 191篇 |
1981年 | 154篇 |
1980年 | 145篇 |
1979年 | 132篇 |
1978年 | 143篇 |
1977年 | 122篇 |
1976年 | 110篇 |
1975年 | 116篇 |
1974年 | 122篇 |
排序方式: 共有10000条查询结果,搜索用时 46 毫秒
981.
Heavy metals in untreated/treated urban effluent and sludge from a biological wastewater treatment plant 总被引:1,自引:0,他引:1
Oliveira Ada S Bocio A Trevilato TM Takayanagui AM Domingo JL Segura-Muñoz SI 《Environmental science and pollution research international》2007,14(7):483-489
Background, Aim and Scope
The presence of heavy metals in wastewater is one of the main causes of water and soil pollution. The aim of the present study was to investigate the removal of Cd, Cu, Pb, Hg, Mn, Cr and Zn in urban effluent by a biological wastewater treatment, as well as to quantify the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sn, Tl, V and Zn in dewatering sludge from the Biological Wastewater Treatment Plant to Ribeirão Preto (RP-BWTP), Brazil.Materials and Methods
Concentrations of Cd, Cr, Cu, Mn and Pb in wastewater and those of Ni in sludge were determined by atomic absorption spectrophotometry with graphite furnace atomization. Mercury concentrations in wastewater were measured by hydride generation atomic spectrophotometry, and Zn levels were determined by atomic absorption spectrophotometry using acetylene flame. In sludge, the levels of As, Be, Cd, Cr, Cu, Fe, Hg, Mn, Pb, Sn, Tl, V and Zn were determined by inductively coupled plasma-mass spectrometry.Results
The percentages of removal efficiency (RE) were the following: Hg 61.5%, Cd 60.0%, Zn 44.9%, Cu 44.2%, PB 39.7%, Cr 16,5% and Mn 10.4%. In turn, the mean concentrations (mg/kg) of metals in dewatering sludge followed this increasing order: Tl (<0.03), Hg (0.31), Be (0.43), As (1.14), Cd (1.34), V (59.2), Pb (132.1), Sn (166.1), Cr (195.0), Mn (208.1), Ni (239.4), Cu (391.7), Zn (864.4) and Fe (20537).Discussion
The relationship between metal levels in untreated wastewater, as well as the removal efficiency are in agreement with previous data from various investigators, It is important to note that metal removal efficiency is not only affected by metal ion species and concentration, but also by other conditions such as operating parameters, physical, chemical, and biological factors.Conclusions
Metal values recorded for treated wastewater and sludge were within the maximum permitted levels established by the Environmental Sanitation Company (CETESB), São Paulo, Brazil.Recommendations
There is an urgent need for the authorities who are responsible for legislation on sludge uses in agriculture of establishing safety levels for As, Be, Hg, Sn, Tl and V.Perspectives
According to the current metal levels, RP-BWTP sludge might be used for agriculture purposes. However, for an environmentally safe use of sewage sludge, further studies including systematic monitoring are recommended. Annual metal concentrations and predicted variations of those elements in the sludge should be monitored.982.
Thacker NP Nitnaware VC Das SK Devotta S 《Environmental science and pollution research international》2007,14(4):225-226
Samples of effluents, sludge, pulp, final products (paper) and soil were collected from the identified pulp and paper mills
in India. The samples were analysed for 2,3,7,8-tetrachloro-dibenzo-p-dioxin (2,3,7,8-TCDD) and other dioxin congeners and
precursors. Pulp and paper mills using chlorine for the bleaching process showed the presence of 2,3,7,8-TCDD in effluent
samples. In the effluent and pulp samples from mills where chlorine dioxide was used as a bleaching agent, the 2,3,7,8-TCDD
congener ranged from below the detection limit 0.05 to 0.12 ngL−1/ngg−1. The relative standard deviation of reproducibility and the percent recovery of 2,3,7,8-TCDD were 2.07 and 82.4% in pulp
and 2.8 and 92% in effluent, respectively. The 1,3,6,8-TCDD was the only other major dioxin congener found in the treated
and untreated effluent and sludge samples. However, dichlorobenzene, trichlorophenyl, and hexachlorobiphenyl were detected
in all samples. The formation of dioxins can be minimised by replacing chlorine with chlorine dioxide in bleaching processes
in pulp and paper mills. 相似文献
983.
984.
Oil spills due to oil pipelines is a very frequent problem in Mexico. Petroleos Mexicanos (PEMEX), very concerned with the
environmental agenda, has been developing inspection and correction plans for zones around oil pipelines pumping stations
and pipeline right-of-way. These stations are located at regular intervals of kilometres along the pipelines. In this study,
two sections of an oil pipeline and two pipeline pumping stations zones are characterized in terms of the presence of Total
Petroleum Hydrocarbons (TPHs) and Polycyclic Aromatic Hydrocarbons (PAHs). The study comprehends sampling of the areas, delimitation
of contamination in the vertical and horizontal extension, analysis of the sampled soils regarding TPHs content and, in some
cases, the 16 PAHs considered as priority by USEPA, calculation of areas and volumes contaminated (according to Mexican legislation,
specifically NOM-EM-138-ECOL-2002) and, finally, a proposal for the best remediation techniques suitable for the contamination
levels and the localization of contaminants. 相似文献
985.
986.
Relation of waste generation and composition to socio-economic factors: a case study 总被引:3,自引:0,他引:3
Bandara NJ Hettiaratchi JP Wirasinghe SC Pilapiiya S 《Environmental monitoring and assessment》2007,135(1-3):31-39
To develop an effective waste management strategy for a given region, it is important to know the amount of waste generated
and the composition of the waste stream. Past research has shown that the amount of waste generated is proportional to the
population and the average mean living standards or the average income of the people. In addition, other factors may affect
the amount and composition of waste. These are climate, living habits, level of education, religious and cultural beliefs,
and social and public attitudes. This paper presents the findings of a study carried out in a suburban municipal area in Sri
Lanka to determine the solid waste generation rate and waste composition based on field surveys and to determine the related
socio-economic factors. A database was developed that included information on the quantity and composition of waste generated
in a sample of households in the study area over a time period. The collected data was analysed to relate waste generation
and composition data to various socio-economic factors. Over 400 sample households were selected for the study using a stratified
random sampling methodology based on municipal wards and property values. A technique that considers both the number of households
in a particular income group (property value range) and the standard deviation of property values within a given income group
was used to determine the appropriate sample size for each municipal ward. Through category and regression analyses, the quantities
of waste and waste composition were related to several socio-economic factors. The paper describes the basis for the sample
selection, the methodology adopted for data collection, the socio-economic parameters used for the analysis, and the relationships
developed from the analysis. 相似文献
987.
Hue O Marcotte J Berrigan F Simoneau M Doré J Marceau P Marceau S Tremblay A Teasdale N 《Chemosphere》2007,67(7):1463-1467
It has been suggested that obese individuals, because of an increased dilution space (body fat) for lipophilic organochlorines compounds, may have greater levels of toxic pollutants than lean sedentary individuals. It is important to further examine this possibility because of the potential contribution of organochlorine pesticides in the development of Parkinson's disease and other neurological diseases. The aim of this study was to further investigate the relationship between the magnitude of obesity and the plasma concentration of organochlorines for a wide range of BMI (with participants at steady state body weight). Fifty-three individuals were selected on the basis of their body mass index (BMI): lean controls (n=16; mean BMI 22.8+/-2.2 kg/m(2); mean age 38.8+/-9.4 years), obese individuals (n=19; mean BMI 33.4+/-3.0 kg/m(2); mean age 38.6+/-7.6 years) and morbidly obese individuals (n=18; mean BMI 49.3+/-6.5 kg/m(2); mean age 44.3+/-9.2 years). Blood samples were analyzed for organochlorine compounds. The relationship between the total plasma organochlorine concentration and BMI was tested using a multiple regression analysis. Age was included in the model. There was no relationship between the total plasma organochlorine concentration and BMI. Organochlorine concentrations, however, were correlated with age (BMI-adjusted R(2)=0.46; p<0.001). At steady state body weight, toxic pollutant concentrations are not associated to obesity but strongly correlate with age. 相似文献
988.
Twenty four hours diel cycles of arsenic speciation in Acid Mine Drainage (AMD) due to photooxidation have been reported for the first time. AMD samples were taken during 48 h (31st March and 1st April, 2005) at 6 h intervals from the effluent of a massive abandoned polymetallic sulphide mine of the Iberian Pyrite Belt (Sw Spain). Samples were preserved in situ using cationic exchange prior to analysis by coupled high performance liquid chromatography, hydride generation and atomic fluorescence spectrometry (HPLC-HG-AFS) for arsenic speciation. The results indicated the presence of inorganic arsenic species with daily means of 262mugl(-1) for As(V) and 107 microg l(-1) for As(III). No marked diel trend was observed for As(V). However, a marked diel trend was observed for As(III) in the two studied days, with maximum concentrations during nighttime (141-143 microg l(-1)) and minimum concentrations at daytime (72-77 microg l(-1)). This difference in concentration during daytime and nighttime is ca. 100%. A similar diel cycle was observed for iron. An explanation for the arsenic diel cycles observed is the light induced photooxidation of As(III) and the elimination of As(V) due to its adsorption onto Fe precipitates during the daytime. Furthermore, the diel changes in arsenic speciation emphasize the importance of designing suitable sampling strategies in AMD systems. 相似文献
989.
Sediment characteristics are well known to interfere with toxicity, mainly through differences in terms of bioaccumulation. Here, with chironomids exposed to zinc in an artificial and a field sediment, we investigated the differences of zinc accumulation and of effects on the life cycle, at individual and population level. We used biology and energy-based modeling to analyze the data at all the levels of biological organization. This permits a reliable estimation of thresholds values for tissue residues. Differences in zinc tissue residues accounted for most of the differences between the results for both sediments (a factor of 11 for differences from 20 to 100 depending on the parameter which is considered). Taking into account accumulation and background variability, the differences relative to thresholds could be accounted for. However, it appeared that, once the threshold was passed, effects were much more pronounced for organisms exposed to artificial sediment compared to field sediment. We concluded that some sediment characteristics can enhance toxicity, in addition to their influence on the compound accumulation, even if the latter was the major source of differences in our study. 相似文献
990.
The marine halogenated natural product 2,3,3',4,4',5,5'-heptachloro-1'-methyl-1,2'-bipyrrole (Q1) is widely distributed in the environment. In this study, we screened samples which have previously been found to contain remarkably high residues of Q1 (blubber of marine mammals from Australia, samples from Antarctica, human milk from the Faroe Island) for the additional presence of mixed chlorinated and brominated congeners. Using GC/ECNI-MS, all samples tested were positive and many contained four out of five possible bromohexachloro congeners (BrCl6-MBPs), five out of 14 possible dibromopentachloro congeners (Br2Cl5-MBPs), five of 21 possible tribromotetrachloro-congeners (Br3Cl4-MBPs), as well as several higher brominated congeners. About 20 heptahalo congeners of Q1 are described for the first time in the scientific literature. Isomers eluted within about one minute, respectively. Hence it is possible, that the peak clusters identified may be composed of more, co-eluting congeners. Similarities in the GC/ECNI-MS mass spectra with polychlorinated biphenyls (PCBs) were addressed. We also suggest an acronym system similar to that in use for polychlorinated biphenyls that may simplify the use of this substance class in scientific papers. In the samples from Australia, BrCl6-MBPs and Br2Cl5-MBPs amounted for 7-27.5% and 0.4-4.2% of Q1, respectively whereas Br3Cl4-MBPs and higher brominated MBPs were found in the range of <1% of Q1 or less. 相似文献