全文获取类型
收费全文 | 20790篇 |
免费 | 144篇 |
国内免费 | 117篇 |
专业分类
安全科学 | 333篇 |
废物处理 | 900篇 |
环保管理 | 2549篇 |
综合类 | 4086篇 |
基础理论 | 5428篇 |
环境理论 | 6篇 |
污染及防治 | 4529篇 |
评价与监测 | 1395篇 |
社会与环境 | 1779篇 |
灾害及防治 | 46篇 |
出版年
2022年 | 109篇 |
2021年 | 122篇 |
2019年 | 101篇 |
2018年 | 732篇 |
2017年 | 690篇 |
2016年 | 712篇 |
2015年 | 283篇 |
2014年 | 363篇 |
2013年 | 1080篇 |
2012年 | 605篇 |
2011年 | 1305篇 |
2010年 | 856篇 |
2009年 | 973篇 |
2008年 | 1210篇 |
2007年 | 1456篇 |
2006年 | 601篇 |
2005年 | 572篇 |
2004年 | 555篇 |
2003年 | 612篇 |
2002年 | 606篇 |
2001年 | 629篇 |
2000年 | 400篇 |
1999年 | 296篇 |
1998年 | 204篇 |
1997年 | 203篇 |
1996年 | 221篇 |
1995年 | 230篇 |
1994年 | 230篇 |
1993年 | 216篇 |
1992年 | 195篇 |
1991年 | 205篇 |
1990年 | 196篇 |
1989年 | 169篇 |
1988年 | 168篇 |
1987年 | 154篇 |
1986年 | 153篇 |
1985年 | 148篇 |
1984年 | 180篇 |
1983年 | 170篇 |
1982年 | 172篇 |
1981年 | 144篇 |
1980年 | 132篇 |
1979年 | 123篇 |
1978年 | 134篇 |
1977年 | 115篇 |
1976年 | 103篇 |
1975年 | 107篇 |
1974年 | 118篇 |
1971年 | 98篇 |
1967年 | 101篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Alexandrova M Rozhko T Vydryakova G Kudryasheva N 《Journal of environmental radioactivity》2011,102(4):407-411
The effect of americium-241 (241Am), an alpha-emitting radionuclide of high specific activity, on luminous bacteria Photobacterium phosphoreum was studied. Traces of 241Am in nutrient media (0.16-6.67 kBq/L) suppressed the growth of bacteria, but enhanced luminescence intensity and quantum yield at room temperature. Lower temperature (4 °C) increased the time of bacterial luminescence and revealed a stage of bioluminescence inhibition after 150 h of bioluminescence registration start. The role of conditions of exposure the bacterial cells to the 241Am is discussed. The effect of 241Am on luminous bacteria was attributed to peroxide compounds generated in water solutions as secondary products of radioactive decay. Increase of peroxide concentration in 241Am solutions was demonstrated; and the similarity of 241Am and hydrogen peroxide effects on bacterial luminescence was revealed. The study provides a scientific basis for elaboration of bioluminescence-based assay to monitor radiotoxicity of alpha-emitting radionuclides in aquatic solutions. 相似文献
992.
The activity of 210Po and 210Pb was determined in mussels of the same size (3.5-4.0 cm shell length) sampled monthly over a 17-month period at the Atlantic coast of Portugal. Average radionuclide concentration values in mussels were 759 ± 277 Bq kg−1 for 210Po (range 460-1470 Bq kg−1 dry weight), and 45 ± 19 Bq kg−1 for 210Pb (range 23-96 Bq kg−1 dry weight). Environmental parameters and mussel biometric parameters were monitored during the same period. Although there was no seasonal variation of radionuclide concentrations in sea water during the study period, the concentration of radionuclide activity in mussels varied seasonally displaying peaks of high concentrations in winter and low concentrations in summer. Analysis of radionuclide data in relation to the physiological Condition Index of mussels revealed that 210Po and 210Pb activities in the mussel (average activity per individual) remained nearly constant during the investigation period, while mussel body weight fluctuated due to fat storage/expenditure in the soft tissues. Similar variation of radionuclide concentrations was observed in mussels transplanted from the sea coast into the Tejo Estuary. However, under estuarine environmental conditions and with higher food availability throughout the year, transplanted mussel Condition Index was higher than in coastal mussels and average radionuclide concentrations were 210 ± 75 Bq kg−1 (dry weight) for 210Po and 10 ± 4 Bq kg−1 (dry weight) for 210Pb, therefore lower than in coastal mussels with similar shell length. It is concluded that the apparent seasonal fluctuation and inter-site difference of radionuclide concentrations were mostly caused by mussel body weight fluctuation and not by radionuclide body burden fluctuation. This interpretation can be extended to the apparent seasonal fluctuation in concentrations of lipophilic and lipophobic contaminants in mussels, and provides an explanation for occasional high concentrations of 210Po and man-made contaminants measured in mussels far from pollution sources. 相似文献
993.
The vertical distribution of the 236U/238U isotopic ratio was investigated in soil samples from three different locations on La Palma (one of the seven Canary Islands, Spain). Additionally the 240Pu/239Pu atomic ratio, as it is a well establish tool for the source identification, was determined. The radiochemical procedure consisted of a U separation step by extraction chromatography using UTEVA® Resin (Eichrom Technologies, Inc.). Afterwards Pu was separated from Th and Np by anion exchange using Dowex 1x2 (Dow Chemical Co.). Furthermore a new chemical procedure with tandem columns to separate Pu and U from the matrix was tested. For the determination of the uranium and plutonium isotopes by alpha spectrometry thin sources were prepared by microprecipitation techniques. Additionally these fractions separated from the soil samples were measured by Accelerator Mass Spectrometry (AMS) to get information on the isotopic ratios 236U/238U, 240Pu/239Pu and 236U/239Pu, respectively. The 236U concentrations [atoms/g] in each surface layer (∼2 cm) were surprisingly high compared to deeper layers where values around two orders of magnitude smaller were found. Since the isotopic ratio 240Pu/239Pu indicated a global fallout signature we assume the same origin as the probable source for 236U. Our measured 236U/239Pu value of around 0.2 is within the expected range for this contamination source. 相似文献
994.
Tushar Yadav Alka A. Mungray Arvind K. Mungray 《Environmental science and pollution research international》2016,23(5):4063-4072
The continuous rise in production and applications of carbon nanotubes (CNTs) has grown a concern about their fate and toxicity in the environment. After use, these nanomaterials pass through sewage and accumulate in wastewater treatment plants. Since, such plants rely on biological degradation of wastes; their activity may decrease due to the presence of CNTs. This study investigated the effect of multiwalled carbon nanotubes (MWCNTs) on upflow anaerobic sludge blanket (UASB) microbial activity. The toxic effect on microbial viability, extracellular polymeric substances (EPS), volatile fatty acids (VFA), and biogas generation was determined. The reduction in a colony-forming unit (CFU) was 29 and 58 % in 1 and 100 mg/L test samples, respectively, as compared to control. The volatile fatty acids and biogas production was also found reduced. The scanning electron microscopy (SEM) and fluorescent microscopy images confirmed that the MWCNT mediated microbial cell damage. This damage caused the increase in EPS carbohydrate, protein, and DNA concentration. Fourier transform infrared (FTIR) spectroscopy results supported the alterations in sludge EPS due to MWCNT. Our observations offer a new insight to understand the nanotoxic effect of MWCNTs on UASB microflora in a complex environment system. 相似文献
995.
996.
997.
Claudia Ursprung Michelle den Hollander Darryl T. Gwynne 《Behavioral ecology and sociobiology》2009,63(6):781-788
Female seed beetles, Callosobruchus maculatus, mate multiply even though association with males and copulations carry costs, such as injury to the genital tract. Multiple
mating (polyandry) may, however, offset these costs through the acquisition of food and water, two material benefits hypothesized
to be obtained from the large ejaculates produced by males. The material benefits hypothesis can be tested by increasing female
access to nutrients and water, with the prediction that female mating frequency will decrease as copulation is no longer required
to derive these materials. Females were given water, 5% sugar–water or baker’s yeast, and were compared with females deprived
of these. We presented females with virgin males daily for 8 days and recorded female mating frequency, survivorship, and
fecundity. Females provided with water and sugar–water decreased mating frequency. Thus, water, rather than nutrients in the
ejaculate, appears to be important to females of this species. In addition, both life span and fecundity were extended for
females in the sugar–water and water treatments. Since water is scarce in the arid environment in which this species is found,
we conclude that polyandry provides material benefits to females that may offset some of the costs of associating with males. 相似文献
998.
The cardinalfish Siphamia versicolor (Perciformes: Apogonidae) forms a bioluminescent symbiosis with the marine luminous bacterium Photobacterium mandapamensis, harboring the bacteria in a ventral, disc-shaped light organ and using the bacterial light apparently for counterillumination
and attracting prey. Little definitive information has been available on the developmental and microbiological events surrounding
the initiation of symbiosis, a critical stage in the life history of the fish, in S. versicolor or any of the many other species of bacterially luminous fish. To identify the stage at which light organ formation begins,
to determine the origin of cells forming the light organ, and to characterize its bacterial colonization status during development,
early developmental stages of S. versicolor obtained and reared from wild-caught mouth-brooding males were examined with histological and microbiological methods. A
light organ primordium was not evident in embryos, post-embryos, or pre-release larvae, whereas the light organ began to form
within 1 day of release of full-term pre-flexion larvae from the mouths of male fish. Analysis of post-release larvae revealed
that the light organ arises from a proliferation and differentiation of intestinal epithelial cells, and that it quickly develops
structural complexity, including the formation of chambers and gaps contiguous with the intestinal epithelium. However, the
nascent light organ remained uncolonized by the symbiotic bacteria through several days of post-release development, even
in the presence of high numbers of the symbiotic bacteria. These results demonstrate that the inception of light organ formation
in S. versicolor occurs independently of its symbiotic bacteria and that receptivity to bacterial colonization apparently requires substantial
post-release development of the light organ. Larvae therefore most likely acquire their symbiotic bacteria from seawater,
during or shortly after the transition from the pre-flexion to the flexion developmental stage. 相似文献
999.
S. Mohapatra A. K. Ahuja M. Deepa G. K. Jagadish N. Rashmi D. Sharma 《Journal of environmental science and health. Part. B》2013,48(3):264-271
Flubendiamide is a new insecticide that has been found to give excellent control of lepidopterous pests of tomato. This study has been undertaken to develop an improved method for analysis of flubendiamide and its metabolite des-iodo flubendiamide and determine residue retention in tomato and soil. The analytical method developed involved extraction of flubendiamide and its metabolite des-iodo flubendiamide with acetonitrile, liquid-liquid partitioning into hexane-ethyl acetate mixture (6:4, v v?1) and cleanup with activated neutral alumina. Finally the residues were dissolved in gradient high pressure liquid chromatography (HPLC) grade acetonitrile for analysis by HPLC. The mobile phase, acetonitrile-water at 60:40 (v v?1) proportion and the wavelength of 235 nm gave maximum peak resolution. Using the above method and HPLC parameters described, nearly 100 % recovery of both insecticides were obtained. There was no matrix interference and the limit of quantification (LOQ) of the method was 0.01 mg kg?1. Initial residue deposits of flubendiamide on field-treated tomato from treatments @ 48 and 96 g active ingredient hectare?1 were 0.83 and 1.68 mg kg?1,respectively. The residues of flubendiamide dissipated at the half-life of 3.9 and 4.4 days from treatments @ 48 and 96 g a.i. ha?1, respectively and persisted for 15 days from both the treatments. Des-iodo flubendiamide was not detected in tomato fruits at any time during the study period. Residues of flubendiamide and des-iodo flubendiamide in soil from treatment @ 48 and 96 g a.i. ha?1 were below detectable level (BDL, < 0.01 mg kg?1) after 20 days. Flubendiamide completely dissipated from tomato within 20 days when the 480 SC formulation was applied at doses recommended for protection against lepidopterous pests. 相似文献
1000.
N. Ahmad G. Bugueno L. Guo R. Marolt 《Journal of environmental science and health. Part. B》2013,48(5):829-848
Abstract A method is described for the determination of organochlorine and organophosphate pesticide residues in fruits, vegetables and sediments. The concentrated solvent extract was sealed in a polymeric membrane tube, dialysed in cyclohexane and the solvent replaced with hexane. The organophosphates were analysed on a specific thermionic detector without further clean‐up. For the organochlorine pesticides the extract was eluted through 3 g of alumina and analysed on GC/ECD. The clean‐up for sediment extract was carried out on a10 g alumina column with 100 mL hexane containing 5% acetone and the eluate was concentrated to 5 mL. The detection limit for organophosphates on a 40 g sample and a final volume of 10 mL was on the average 0.01 mg/kg. The detection limit for organochlorine pesticides, with the final volume of 25 mL, was 0.005 mg/kg for all pesticides except for p,p'‐DDT and endosulfan sulphate, which was 0.01 mg/kg. The detection limit for oganochlorine pesticides in sediment, with the final volume of 2 mL, was less than 1 μg/kg and for organophosphate pesticides less than 10 μg/kg when the final volume was made to 0.5 mL. At the detection limits the method produced a very high coefficient of variation for both organochlorine and organophosphate pesticides. 相似文献