全文获取类型
收费全文 | 3497篇 |
免费 | 29篇 |
国内免费 | 10篇 |
专业分类
安全科学 | 64篇 |
废物处理 | 239篇 |
环保管理 | 263篇 |
综合类 | 371篇 |
基础理论 | 707篇 |
环境理论 | 6篇 |
污染及防治 | 1314篇 |
评价与监测 | 331篇 |
社会与环境 | 231篇 |
灾害及防治 | 10篇 |
出版年
2023年 | 43篇 |
2022年 | 94篇 |
2021年 | 144篇 |
2020年 | 57篇 |
2019年 | 59篇 |
2018年 | 132篇 |
2017年 | 133篇 |
2016年 | 194篇 |
2015年 | 102篇 |
2014年 | 213篇 |
2013年 | 331篇 |
2012年 | 247篇 |
2011年 | 252篇 |
2010年 | 194篇 |
2009年 | 122篇 |
2008年 | 197篇 |
2007年 | 228篇 |
2006年 | 162篇 |
2005年 | 137篇 |
2004年 | 99篇 |
2003年 | 81篇 |
2002年 | 77篇 |
2001年 | 44篇 |
2000年 | 36篇 |
1999年 | 22篇 |
1998年 | 12篇 |
1997年 | 9篇 |
1996年 | 8篇 |
1995年 | 14篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1988年 | 2篇 |
1985年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1970年 | 2篇 |
1967年 | 4篇 |
1966年 | 4篇 |
1965年 | 2篇 |
1964年 | 5篇 |
1962年 | 3篇 |
1959年 | 4篇 |
1958年 | 15篇 |
1957年 | 5篇 |
1955年 | 2篇 |
1937年 | 1篇 |
1928年 | 1篇 |
排序方式: 共有3536条查询结果,搜索用时 421 毫秒
661.
Correlation analysis between sulphate content and leaching of sulphates in recycled aggregates from construction and demolition wastes 总被引:1,自引:0,他引:1
Barbudo A Galvín AP Agrela F Ayuso J Jiménez JR 《Waste management (New York, N.Y.)》2012,32(6):1229-1235
In some recycled aggregates applications, such as component of new concrete or roads, the total content of soluble sulphates should be measured and controlled. Restrictions are usually motivated by the resistance or stability of the new structure, and in most cases, structural concerns can be remedied by the use of techniques such as sulphur-resistant cements. However, environmental risk assessment from recycling and reuse construction products is often forgotten. The purpose of this study is to analyse the content of soluble sulphate on eleven recycled aggregates and six samples prepared in laboratory by the addition of different gypsum percentages. As points of reference, two natural aggregates were tested. An analysis of the content of the leachable amount of heavy metals regulated by European regulation was included. As a result, the correlation between solubility and leachability data allow suggest a limiting gypsum amount of 4.4% on recycled aggregates. This limit satisfies EU Landfill Directive criteria, which is currently used as reference by public Spanish Government for recycled aggregates in construction works. 相似文献
662.
J M López-Gutiérrez M García-León C Schnabel M Suter H A Synal S Szidat 《Journal of environmental radioactivity》2001,55(3):269-282
Iodine-129 (T1/2 = 1.57 x 10(7) yr) concentrations have been determined by accelerator mass spectrometry in rainwater samples taken at Seville (southwestern Spain) in 1996 and 1997. This technique allows a reduction in the detection limits for this radionuclide in comparison to radiometric counting and other mass spectrometric methods such as ICP-MS. Typical 129I concentrations range from 4.7 x 10(7) 129I atoms/l (19.2%) to 4.97 x 10(9) 129I atoms/l (5.9%), while 129I depositions are normally in the order of 10(8)-10(10) atoms/m2d. These values agree well with other results obtained for recent rainwater samples collected in Europe. Apart from these, the relationship between 129I deposition and some atmospheric factors has been analyzed, showing the importance of the precipitation rate and the concentration of suspended matter in it. 相似文献
663.
Extractable atrazine and its metabolites (hydroxyatrazine, deethylatrazine and deisopropylatrazine) were evaluated in agricultural
soils from the temperate humid zone (Galicia, NW Spain) under laboratory conditions. The experiment was performed with five
soils with different properties (organic C, soil texture and atrazine application history), both unamended and treated with
atrazine at field application rate. Measurements of the atrazine compounds were made at different time intervals (1, 3, 6,
9 and 12 weeks) during a 3-month incubation period. Results showed that only hydroxyatrazine was detected in the extractable
fraction of the unamended soils, with values remaining relatively constant throughout the incubation period. Atrazine addition
notably increased the concentration of the parent compound and its degradation products; deisopropylatrazine and hydroxyatrazine
were the main metabolites detected in the extractable fraction of the treated soils, whereas deethylatrazine was not detected.
After 7 days incubation, values of total extractable residues, expressed as percentage of initially added atrazine, ranged
from 75 to 86% (25–68% of atrazine, 7–11% of hydroxyatrazine and 9–57% of deisopropylatrazine). The values decreased rapidly
during the first 3 weeks of incubation, showing values of 2–8% in soils with higher atrazine application and from 28 to 30%
in soils with lower application history. At the end of the incubation, 2–8% of total extractable residues were still detected
(0–4% of atrazine, 2–3% of hydroxyatrazine and 0–2% of deisopropylatrazine), indicating a residual effect of atrazine addition.
These variations in the extractable fraction indicated that most added atrazine was rapidly degraded, especially in soils
with higher application history. 相似文献
664.
Carlos César Martínez-Rivera H. Carl Gerhardt 《Behavioral ecology and sociobiology》2008,63(2):195-208
Senders and receivers influence dynamic characteristics of the signals used for mate attraction over different time scales.
On a moment-to-moment basis, interactions among senders competing for a mate influence dynamic characteristics, whereas the
preferences of receivers of the opposite gender exert an influence over evolutionary time. We observed and recorded the calling
patterns of the bird-voiced treefrog Hyla avivoca to assess how the dynamic characters of calls vary during interactions among groups of males in a chorus. This question was
also addressed using playback experiments with males. Playback experiments with females showed how changes in dynamic call
properties are likely to affect male mating success. Frogs calling in pairs, groups, or in response to playbacks produced
longer calls than did isolated males. During call overlap, males often increased the duration of the silent interval (gaps)
between the pulses of their calls so that the pulses of the calls of two neighbors interdigitated. This change resulted in
increased variability of pulse rate, a traditionally static acoustic property; however, males also produced high proportions
of non-overlapped calls in which variability in pulse rate was low and had species-typical values. Females preferred long
calls to short- and average-duration calls, and non-overlapped calls to overlapped calls. Given a choice between pairs of
overlapped calls, females preferred pairs in which the proportion of overlap was low and pairs in which the pulses of such
calls interdigitated completely. The observed patterns of vocal competition thus reflect the preferences of conspecific females,
which have influenced the evolution of the calling behavior of H. avivoca.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
665.
Hawkins BA Diniz-Filho JA Bini LM Araújo MB Field R Hortal J Kerr JT Rahbek C Rodríguez MA Sanders NJ 《Ecology》2007,88(8):1898-1902
666.
Health risk assessment maps for arsenic groundwater content: application of national geochemical databases 总被引:3,自引:0,他引:3
This investigation assesses the feasibility of calculating and visualizing health risk estimates from exposure to groundwater
contaminated with arsenic (As) using data from national geochemical databases. The potential health risk associated with As-contaminated
groundwater was assessed based on an elaboration of existing geochemical data in accordance with accepted methodological procedures
established for human health risk assessment (U.S. Environmental Protection Agency methodology). A screening analysis approach
was used for estimating the contribution of As to the total chronic health risk from exposure to groundwater contaminated
with potentially toxic elements, including As, Ba, Cd, Cu, Hg, Pb, Sb, Se and Zn, and the results indicate that As contributes
significantly (>50%) to this total health chronic risk in about 10% of Slovak territory. Based on the calculation of the
potential risk level by exposure modelling, increased chronic as well as carcinogenic risk levels (medium to high) were documented
in approximately 0.2 and 11% of the total Slovak area, respectively. The areas characterized by high health risk levels are
mainly those geogenically contaminated. High and very high carcinogenic risk was determined in 34 of 79 districts and in 528
of 2924 municipalities. 相似文献
667.
Analysis of perfluorooctanoate (PFOA) and other perfluorinated compounds (PFCs) in the River Po watershed in N-Italy 总被引:5,自引:0,他引:5
Loos R Locoro G Huber T Wollgast J Christoph EH de Jager A Manfred Gawlik B Hanke G Umlauf G Zaldívar JM 《Chemosphere》2008,71(2):306-313
C7-C11 perfluorinated carboxylates (PFACs) and perfluorooctansulfonate (PFOS) were analysed in selected stretches of the River Po and its major tributaries. Analyses were performed by solid-phase extraction (SPE) with Oasis HLB cartridges and methanol elution followed by LC-MS-MS detection using 13C-labelled internal standards. High concentration levels ( approximately 1.3 microg l(-1)) of perfluorooctanoate (PFOA) were detected in the Tánaro River close to the city Alessandria. After this tributary, levels between 60 and 337 ng l(-1) were measured in the Po River on several occasions. The PFOA concentration close to the river mouth in Ferrara was between 60 and 174 ng l(-1). Using the river discharge flow data in m3 s(-1) at this point (average approximately 920 m3 s(-1) for the year 2006), a mass load of approximately 0.3 kg PFOA per hour or approximately 2.6 tons per year discharged in the Adriatic Sea has been calculated. PFOS concentration levels in the Po River at Ferrara were approximately 10 ng l(-1). 相似文献
668.
This study characterized and mapped the spatial variability patterns of seven topsoil heavy metals (Cr, Ni, Pb, Cu, Zn, Hg and Cd) within the Ebro river basin (9.3 million ha) by Multivariate Factorial Kriging. The variograms and cross-variograms of heavy metal concentrations showed the presence of multiscale variation that was modeled using three variogram models with ranges of 20km (short-range), 100km (medium-range) and 225km (long-range). Our results indicate that the heavy metal concentration is influenced by bedrock composition and dynamics at all the spatial scales, while human activities have a notorious effect only at the short- and medium-range scale of variation. Sources of Cu, Pb and Zn (and secondary Cd) are associated with agricultural practices (at the short-range scale of variation), whereas Hg variation at the short- and medium-range scale of variation is related to atmospheric deposition. 相似文献
669.
Combined photo-Fenton and biological oxidation for pesticide degradation: effect of photo-treated intermediates on biodegradation kinetics 总被引:2,自引:0,他引:2
Ballesteros Martín MM Sánchez Pérez JA Acién Fernández FG Casas López JL García-Ripoll AM Arques A Oller I Malato Rodríguez S 《Chemosphere》2008,70(8):1476-1483
Biodegradability of a partially photo-oxidized pesticide mixture is demonstrated and the effect of photo-Fenton treatment time on growth and substrate consumption of the bacteria Pseudomonas putida CECT 324 is shown. Four commercial pesticides, laition, metasystox, sevnol and ultracid, usually employed in citric orchards in eastern Spain, were chosen for these experiments. The active ingredients are, respectively, dimethoate, oxydemeton-methyl, carbaryl and methidathion. Judging by biomass measurements, dissolved organic carbon measurements and biodegradation efficiency, it may be concluded that 90min相似文献
670.
Adsorption of carbon dioxide on alkaline modified X zeolites was investigated by temperature programmed desorption (TPD) analysis of these materials previously saturated with CO(2) at 50, 100 and 200 degrees C. Parent X zeolite (in its sodium form) was treated with different sodium and cesium aqueous solutions, using both carbonates and hydroxides as precursors. The resulting materials were characterised by nitrogen physisorption, XRD, and NH(3)-TPD, in order to determine their morphological, crystallographic and chemical properties. Slight desilication phenomena were observed using hydroxides as precursors, whereas the treatment with Cs salts lead to higher crystallinity losses. Several successive adsorption-desorption cycles were carried out in order to check the regenerability of the adsorbents. Cesium-treated zeolites present higher carbon dioxide retention capacities than the sodium treated and than the parent material. When working with these Cs-modified materials, the desorption takes place mainly at temperatures between 250 and 400 degrees C, results of great practical interest, since it allows the use these kinds of materials for adsorption-desorption cycles. The evolution of the retention capacity with temperature is also markedly more positive for Cs-treated zeolite, especially when carbonate is used as the precursor. These materials maintain high retention capacities at 100 degrees C (10mg g(-1)) and even at 200 degrees C (3mg g(-1)), temperatures at which the most of the adsorbents are inactive. 相似文献