Carbon dioxide separation and capture by adsorption: a review

Environmental Chemistry Letters - Rising adverse impact of climate change caused by anthropogenic activities is calling for advanced methods to reduce carbon dioxide emissions. Here, we...     

Maximum power point tracking methods for photovoltaic systems operating under partially shaded or rapidly variable insolation conditions: a review paper

To increase the efficiency of photovoltaic (PV) systems, maximum power point (MPP) tracking of the solar arrays is needed. Under partially shaded conditions (PSCs), the solar arrays power–current (P–I) characteristic has multiple MPP. This paper presents various methods and approaches of tracking the MPP from a PV generator operating under PSC. Some comparisons, advantages, drawbacks and critical analysis of each method are discussed. It was found that, indirect methods use empirical data or mathematical expressions of numerical approximations to estimate the MPP from the PV generator’s voltage, current and irradiance. Direct methods offer the advantage of obtaining the actual maximum power from the PV generator’s voltage and current. Artificial intelligence methods do not need exact mathematical models. They can perform under parameter variation, load and supply voltage disturbances. Finally, novel methods require less number of iterations to converge, independent to the initial conditions. All these algorithms can be included in some of the DC/DC converters and MPP trackers for stand-alone or grid-connected systems.     

Are renewable energy policies upsetting carbon dioxide emissions? The case of Latin America countries

Environmental Science and Pollution Research - The impact of renewable energy policies in carbon dioxide emissions was analysed for a panel of ten Latin American countries, for the period from 1991...     

The possible association between selected sediment characteristics and the occurrence of benthic macroinvertebrates in a minimally affected river in South Africa

Forty-two families of which the vast majority associated with particles >2000?µm were found. Sediment particle sizes <2000?µm had a detrimental effect on biodiversity. The highest biodiversity was recorded at sites characterised by riffle and run habitats. Although relatively high concentrations of selected metals were present in the sediment, it was largely from geological origin and most probably not bioavailable. No significant correlation was demonstrated between variation in temperature, pH, and electrical conductivity and diversity and abundance of macroinvertebrates. Therefore, it can be concluded that, under these conditions, sediment particle size and biotope availability played a decisive role on the distribution and abundance of macroinvertebrate taxa.     

Genotoxicity assessment of human peripheral Lymphocytes induced by thallium(I) and thallium(III)

Thallium is a non-essential metal with a wide range of industrial uses. However, thallium is also a potential pollutant with high potential toxicity to humans. In the present study, we analyzed and compared the cellular and genotoxic effects of thallium in two main oxidation states by applying chromosome aberration assays to human peripheral lymphocytes. We observed that thallium(I) sulfate reduced the mitotic index at all tested concentrations (0.5, 1, 5, 50 and 100 μg/mL), whereas thallium(III) chloride was toxic at concentrations ≥1 μg/mL. Thallium(I) and thallium(III) treatment significantly increased structural chromosomal aberrations, with and without gaps, and increased the percentage of aberrant cells without gaps. Furthermore, satellite associations and numerical chromosomal aberration tests showed significant differences at a few of the tested concentrations. The satellite association test is related to aneuploidy. Thallium salts increased satellite associations when hyperploid cells were observed. Our results indicated that the two oxidation states of thallium induced toxicity in vitro – i.e. cyto/genotoxic (clastogenic and aneuploidogenic) effects.     

Infiltrating citizen-driven initiatives for sustainability

To examine how citizen-driven initiatives for sustainability strive to bring about change and spread their practices, efforts to link social movement, grassroots innovation and green-consumption movements theory are built upon. Göteborg’s citizen-driven waste-prevention initiatives, such as food waste recovery, creating common reuse spaces in housing blocks, exchanging used toys and repairing abandoned bicycles, are considered with data from observations, workshops, documents, social media communications and in-depth interviews. Citizen-driven initiatives succeeded in mobilizing material resources, displaying and reframing various rationales, and creating collaborative local networks to develop their waste-prevention practices. These practices infiltrated the municipal administration, matching incipient institutional mandates to minimize waste. By so doing, they bring within mainstream institutions radical rationales that can become activated in the future, contributing to diachronic change.     

Evidence of the impacts of the national housing programme on the accessibility of the low‐income population in Rio de Janeiro

The Brazilian shift from a primarily rural to a more urban society has created major challenges that public policies must address. One of the most relevant challenges is deep social exclusion in urban areas, especially in terms of adequate housing and access to urban opportunities (e.g., jobs, housing, and services). In this context, land use and transport planning play a critical role in the sustainable development agenda. The work presented here analyses the accessibility of low‐income dwellings licenced under the Brazilian housing programme to the low‐income population. To evaluate the accessibility of the programme's target population, a case study was conducted in the city of Rio de Janeiro, where 58,000 homes licensed under the programme were analysed using GIS tools in terms of the present public transport network and the location of the homes. The amount of time it takes to access public transport on foot and the homes’ locations in relation to major urban opportunities were also analysed. Finally, the same analysis was performed for the future transport network, and the results of the two analyses were compared to identify the scope of the legacy generated by investments in preparation for the 2016 network.     

Long-term effects of lead poisoning on bone mineralization in vultures exposed to ammunition sources

Long-lived species are particularly susceptible to bioaccumulation of lead in bone tissues. In this paper we gain insights into the sublethal effects of lead contamination on Egyptian vultures (Neophron percnopterus). Our approach was done on the comparison of two populations (Canary Islands and Iberian Peninsula) differing in exposures to the ingestion of lead ammunition. Blood lead levels were higher in the island population (Canary Islands range: 5.10-1780 μg L⁻¹n = 137; Iberian Peninsula range: 5.60-217.30 μg L⁻¹n = 32) showing clear seasonal trends, peaking during the hunting season. Moreover, males were more susceptible to lead accumulation than females. Bone lead concentration increased with age, reflecting a bioaccumulation effect. The bone composition was significatively altered by this contaminant: the mineralization degree decreased as lead concentration levels increased. These results demonstrate the existence of long-term effects of lead poisoning, which may be of importance in the declines of threatened populations of long-lived species exposed to this contaminant.     

Concentrations of PCDD/Fs,PCBs and PBDEs in breast milk of women from Catalonia,Spain: A follow-up study

The concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were determined in breast milk from women living in the vicinity of a new hazardous waste incinerator (HWI) in Catalonia, Spain. The results were compared with the levels obtained in two previous surveys carried out in 1998 (baseline study) and 2002. The current concentrations of PCDD/Fs in breast milk ranged from 45 to 143 pg/g fat (2.8 to 11.2 pg WHO-TEQ/g fat), while total PCBs ranged from 114 to 617 pg/g fat (2.8 to 17.6 pg WHO-TEQ/g fat). PBDE concentrations (sum 15 congeners) ranged from 0.57 ng/g fat to 5.9 ng/g fat, with a mean value of 2.5 ng/g fat. A general decrease of the concentrations for PCDD/Fs and both planar and total PCBs was observed. Regarding to PBDE concentrations in breast milk, similar levels between the 2002 and the present study were noted. The levels of PCDD/Fs and PCBs in milk of women living in urban areas were higher than those corresponding to the industrial zones (38% and 40%, respectively). However, the current PBDE levels were slightly lower (13%) in the urban than in the industrial zone. For PCDD/Fs and PCBs, the current decreases are in accordance with the reduction in the dietary intake of these pollutants found in recent studies carried out in the same area of study.     

Determination of total and available fractions of PAHs by SPME in oily wastewaters: overcoming interference from NAPL and NOM

Background, aim, and scope  

Polycyclic aromatic hydrocarbons (PAHs) are often found in oily wastewaters. Their presence is usually the result of human activities and has a negative effect on the environment. One important step in addressing this problem is to evaluate the effectiveness of PAH removal by biological processes since these are the most cost-effective treatments known today. Many techniques are presently available for PAH determination in wastewaters. Solid phase microextracion (SPME) is known to be one of the most effective techniques for this purpose. When analyzing complex matrices with substances such as natural organic matter (NOM) and non-aqueous phase liquids (NAPL), it is important to differentiate the free dissolved PAH from matrix-bonded PAH. PAHs associated with the bonded fraction are less susceptible to biological treatment. The present study concerns the development of a simple and suitable methodology for the determination of the freely dissolved and the total fraction of PAHs present in oily wastewaters. The methodology was then applied to an oily wastewater from a fuel station retention basin.