Rüstungsaltlasten

Risk assessment of contaminated sites from abandoned ammunition plants follows a multi-stage procedure with its own specific requirements for the toxicological assessment of chemical contaminants. Thus, the 22 explosives and related compounds (STVs) were classified according to carcinogenicity, genotoxicity and evaluation numbers for their toxicological potential (ENs). These characteristics permit a specific toxicological assessment and ranking at the stage of “historical reconnaissance”, independent of an evaluation of the contaminant concentrations. With a view to “orientative site evaluation” for the assessment of explosives and related compounds in groundwater and drinking water, toxicologically related guide values based on the ENs of toxicological potential as well as TDI-based guide values for STVs in soil were derived as based on toxicologically safe body doses and lifelong exposure (TDI=Tolerable Daily Intake). For regulatory purposes, substance related precautionary values are defined for probable carcinogens and contaminants with essential lacks in the toxicological data base.     

Die Wirkung von Photooxidantien auf Sommerweizen (Triticum aestivum L. Star)

The effect of short-time fumigation with the peroxidic photooxidants ozone, peroxyacetyl nitrate (PAN), and hydrogen peroxide (H₂O₂) on the gas exchange of wheat leaves was investigated. Two types of experiments are to be distinguished:

1. Fumigation is carried out at atmospheric CO₂ partial pressure (350 μbar) and the assimilation and transpiration rates are followed simultaneously.
2. The alteration of CO₂-response curves by fumigation is determined; from this, characteristic photosynthetic parameters can be calculated.

With this method, statements about the reaction of both photosynthesis as a whole and specific reaction sites within the most important photosynthetic processes are possible. Ozone in concentrations of 260–280 ppb causes a primary perturbation of the photosynthetic apparatus, whereby the carboxylation rate is affected to nearly the same extent as the electron-transport rate.PAN (120 ppb) causes a reduction in the assimilation rate, primarily due to the closing of the stomata. H₂O₂ affects the gas exchange only in concentrations of above 1 ppm, whereby the reduction of the assimilation rate represents an almost pure stomatal effect. All three fumigants cause an increase in the respiration rate, which may point to an activation of detoxification and repair mechanisms.