New York State’s Classifications- Ambient Air Quality Objectives System

The air pollution potential of any area is directly related to its population and economic development. In New York State, this pollution potential ranges from that existing in the sparsely inhabited recreational zones to that prevailing in the densely populated and/or heavily industrialized areas. No one set of air quality standards or objectives can be developed which can reasonably be applied on a statewide basis. A classifications-air quality objectives system has been adopted by the State Air Pollution Control Board for application in New York State. In accordance with this system, specific areas can be classified in one of 16 categories. Air quality objectives, in keeping with each classification, are designed to protect health and to promote the maximum comfort and enjoyment and use of property consistent with the needs of the area concerned. The system was developed by the staff with the assistance of a council of technical advisors. Units of measurement related to the most important effect of specific contaminants are utilized. Methods of sampling and analysis are specified. The details of the classifications-objectives system, the place of the system in the state’s air resource management plan, the manner in which each segment of the state after study will be classified, and how attainment will be evaluated are described.     

Nationwide Air Pollution Control Training Efforts: Status Quo vs. Needs

This paper briefly reviews the historical development of air pollution training activities in the U. S. It describes the various types of training programs currently available, such as short courses, specialized programs, and university training at the graduate level. The level of financial support and the number of individuals enrolled in these programs are discussed. The paper concludes with an outline of future needs in terms of changes in existing training programs, extension into new areas, and the critical problem of recruitment of qualified candidates for training.     

Photochemical Reactivity of Perchloroethylene: A New Appraisal

Perchloroethylene (PCE), a solvent used in dry cleaning, has been suspected of contributing significantly to photochemical ozone/oxidant (O₃/O_x) problems in urban atmospheres. Past evidence, however, was neither complete nor consistent. To interpret more conclusively the past evidence, and further understand PCE's role in the O₃O_x problem, a smog chamber testing program was conducted. The program's objectives were: (a) to explain the mechanism of the PCE reaction in smog chamber atmospheres, and (b) to extrapolate the smog chamber findings regarding PCE reactivity to the real atmosphere. Results showed that in smog chambers, PCE reacts and forms O₃/O_x following what appears to be a Cl instigated photooxidation mechanism rather than the OH initiated mechanism accepted in current smog chemistry. The evidence, collectively, strongly supported this conclusion even though the source of Cl atoms could not be identified with confidence. It was further concluded that in the real atmosphere neither the Cl instigated nor the OH instigated photooxidations of PCE can generate substantial concentrations of O₃/O_x. In fact, PCE contributes less to the ambient O₃/O_x problem than equal concentrations of ethane.     

Why Economics Matters for Endangered Species Protection

Abstract: We offer three reasons why economics matters more to species protection than many people think and what this implies for the ongoing debate over the reauthorization of the Endangered Species Act of 1973. Economics matters because (1) human behavior generally, and economic parameters in particular, help determine the degree of risk to a species; (2) in a world of scarce resources, the opportunity cost of species protection—the costs of reduced resources for other worthwhile causes—must be taken into account in decision making; and (3) economic incentives are critical in shaping human behavior, and consequently the recovery of species. Endangered species protection that explicitly addresses these basic principles can avoid wasting valuable resources that yield no gain in species protection.     

A comparison of data quality control protocols for atmospheric mercury speciation measurements

Significant advances in the measurement of atmospheric mercury species have been made in the past 10 years yet limited protocols on quality control (QC) and assurance on this data have been published in the literature. Recently, considerable work has been done to develop quality control and assurance programs within North America. Environment Canada and the National Atmospheric Deposition Network (NADP) independently developed programs, RDMQ? and AMQC, respectively, to QC atmospheric mercury speciation data (including gaseous elemental mercury (GEM), reactive gaseous mercury (RGM) and mercury associated to particles (PHg)). These 2 programs were assessed by the criteria on which the data is QCed and comparability of the final data products. Results show that the criteria used to flag data compare well within the 4 tested sites and that the number of flags for each criterion is generally comparable. The QC programs were applied to 2 distinct data sets and the final QCed data was compared. From a mid-latitude site, the final data sets compare very well and showed there to be a 0.3, 8.6 and 15% difference in the mean GEM, RGM and PHg concentrations post QC of each program. It is recommended that either the RDMQ or the AMQC programs be employed for a typical mid-latitude site. When the QC programs were applied to highly variable data, the data do not compare as well for RGM and PHg. Results showed a 2.7, 27 and 33% difference in the mean GEM, RGM and PHg concentrations, respectively, post QC of each program. It is recommended that RDMQ be used for data that is highly variable with high RGM/PHg concentrations as it allows for more manual correction over the QCed data. This investigation of 2 QC programs produced comparable data and that either of these programs can be used as standard methods for the quality control of atmospheric mercury speciation data.     

Wet deposition of mercury in the U.S. and Canada, 1996–2005: Results and analysis of the NADP mercury deposition network (MDN)

One of the most critical measurements needed to understand the biogeochemical cycle of mercury, and to verify atmospheric models, is the rate of mercury wet-deposition. The Mercury Deposition Network (MDN) operates sites across North America to monitor total mercury in wet-deposition. MDN's primary goal is to provide both spatial and temporal continental-scale observations of mercury wet-deposition fluxes to support researchers, modelers, policy-makers and the public interest. MDN represents the only continental-scale mercury deposition database with a >10-year record of continuous values. This study provides analysis and interpretation of MDN observations at 10 years (1996–2005) with an emphasis on investigating whether rigorous, statistically-significant temporal trends and spatial patterns were present and where they occurred. Wet deposition of mercury ranges from more than 25 μg m^?2 yr in south Florida to less than 3 μg m^?2 yr in northern California. Volume-weighted total mercury concentrations are statistically different between defined regions overall (Southeast ≈ Midwest > Ohio River > Northeast), with the highest in Florida, Minnesota, and several Southwest locations (10–16 ng L^?1). Total mercury wet-deposition is significantly different between defined regions (Southeast > Ohio River > Midwest > Northeast). Mercury deposition is strongly seasonal in eastern North America. The average mercury concentration is about two times higher in summer than in winter, and the average deposition is approximately more than three times greater in summer than in winter. Forty-eight sites with validated datasets of five years or more were tested for trends using the non-parametric seasonal Kendall trend test. Significant decreasing mercury wet-deposition concentration trends were found at about half of the sites, particularly across Pennsylvania and extending up through the Northeast.     

Controlling the Flue-Fed Incinerator

This paper examines various health effects of photochemical air pollution in Japan, primarily through the review of epidemiological studies. Health effects discussed include subjective respiratory symptoms, respiratory function testing, ocular effects, and hospital diagnostic tests. The downward trend in oxidant cautions and paralleled health effects, as reported by the Japanese Environmental Agency, are discussed. The methods determined by Japanese ordinance for measurement of oxidants, SO₂, NO _x , and CO are described.