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31.
Monitoring of Cr, Cu, Pb, V and Zn in polluted soils by laser induced breakdown spectroscopy (LIBS) 总被引:2,自引:0,他引:2
Dell'Aglio M Gaudiuso R Senesi GS De Giacomo A Zaccone C Miano TM De Pascale O 《Journal of environmental monitoring : JEM》2011,13(5):1422-1426
Laser Induced Breakdown Spectroscopy (LIBS) is a fast and multi-elemental analytical technique particularly suitable for the qualitative and quantitative analysis of heavy metals in solid samples, including environmental ones. Although LIBS is often recognised in the literature as a well-established analytical technique, results about quantitative analysis of elements in chemically complex matrices such as soils are quite contrasting. In this work, soil samples of various origins have been analyzed by LIBS and data compared to those obtained by Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES). The emission intensities of one selected line for each of the five analytes (i.e., Cr, Cu, Pb, V, and Zn) were normalized to the background signal, and plotted as a function of the concentration values previously determined by ICP-OES. Data showed a good linearity for all calibration lines drawn, and the correlation between ICP-OES and LIBS was confirmed by the satisfactory agreement obtained between the corresponding values. Consequently, LIBS method can be used at least for metal monitoring in soils. In this respect, a simple method for the estimation of the soil pollution degree by heavy metals, based on the determination of an anthropogenic index, was proposed and determined for Cr and Zn. 相似文献
32.
Martina Kralj Cinzia De Vittor Cinzia Comici Federica Relitti Rocco Auriemma Giorgio Alabiso Paola Del Negro 《Environmental science and pollution research international》2016,23(13):12675-12690
The Mar Piccolo of Taranto, classified as a ‘Site of National Interest’ (SIN), is a semi-enclosed basin divided into two inlets with lagoon features and sea influences, seriously affected by anthropic activities. In the framework of the RITMARE project, a study has been carried out to evaluate the functionality of this ecosystem. As part of this work, measurements of the water abiotic parameters were performed in order to assess the physical–chemical features of this area after the activation, in the last decade, of treatment plants for various urban and industrial dumping. Seawater intrusions and continental inputs, as well as several submarine freshwater springs, clearly affect physical–chemical characteristics of the water column in the two inlets. This finding suggests that small-scale patterns in water circulation have the potential to influence the chemical properties of the seawater. The comparison with a 20-year dataset reveals a drastic decrease in nutrient concentrations after the year 2000, validating the functionality of the treatment plants. The reduction of nutrient inputs into the basin (up to ?90 % in the first inlet characterized by lower hydraulic residence time) has changed the biogeochemical characteristics of the Mar Piccolo from being relatively eutrophic to moderately oligotrophic. 相似文献
33.
Luca Alessandria Tiziana Schilirò Raffaella Degan Deborah Traversi Giorgio Gilli 《Environmental science and pollution research international》2014,21(8):5554-5564
Recently, much attention has been devoted to urban air pollution because epidemiological studies have reported health impacts related to particulate matter (PM). PM10 and PM2.5 were collected during different seasons in Torino, a northern Italian city, and were characterised by inorganic chemical species (secondary particulates and bio-available iron). The biological effects of aqueous and organic solvent PM extracts on human epithelial lung A549 were evaluated, and the effects on cell proliferation and lactate dehydrogenase (LDH) release were assayed. The average PM10 concentration during the sampling period was 47.9?±?18.0 μg/m3; the secondary particles accounted for 49 %?±?9 % of the PM10 total mass, and the bio-available iron concentration was 0.067?±?0.045 μg/m3. The PM2.5/PM10 ratio in Torino ranged from 0.47 to 0.90 and was higher in cold months than in warm months. The PM10 and PM2.5 extracts inhibited cell proliferation and induced LDH release in a dose-dependent manner with a seasonal trend. The PM10 extract had a stronger effect on LDH release, whereas the PM2.5 extract more strongly inhibited cell proliferation. No significant differences were observed in the effects induced by the two extracts, and no significant correlations were found between the biological effects and the PM components evaluated in this study, thus emphasising the importance of the entire mixture in inducing a cytotoxic response. 相似文献
34.
Amoroso Maria Grazia Di Concilio Denise Langellotti Antonio Luca Martello Anna Cioffi Barbara Suffredini Elisabetta Cozzi Loredana Russo Valeria Mauriello Gianluigi Di Pasquale Simona Galiero Giorgio Fusco Giovanna 《Food and environmental virology》2021,13(3):329-336
Food and Environmental Virology - Kinetics of hepatitis A virus (HAV) accumulation and depuration from mussels (Mytilus galloprovincialis) was studied in an experimental depuration system.... 相似文献
35.
Maria Grazia Amoroso Antonio Luca Langellotti Valeria Russo Anna Martello Marina Monini Ilaria Di Bartolo Giovanni Ianiro Denise Di Concilio Giorgio Galiero Giovanna Fusco 《Food and environmental virology》2020,12(1):48-57
Bivalve mollusks as filter-feeders concentrate in their digestive tissue microorganisms likely present in the harvesting water, thus becoming risky food especially if consumed raw or poorly cooked. To eliminate bacteria and viruses eventually accumulated, they must undergo a depuration process which efficacy on viruses is on debate. To better clarify the worth of the depuration process on virus elimination from mussels, in this study we investigated rotavirus kinetics of accumulation and depuration in Mytilus galloprovincialis experimentally contaminated. Depuration process was monitored for 9 days and virus residual presence and infectivity were evaluated by real time quantitative polymerase chain reaction, cell culture and electron microscopy at days 1, 2, 3, 5, 7, 9 of depuration. Variables like presence of ozone and of microalgae feeding were also analyzed as possible depuration enhancers. Results showed a two-phase virus removal kinetic with a high decrease in the first 24 h of depuration and 5 days necessary to completely remove rotavirus. 相似文献
36.
Pignata C Fea E Rovere R Degan R Lorenzi E de Ceglia M Schilirò T Gilli G 《Environmental monitoring and assessment》2012,184(4):2091-2103
This study investigates the impact of wastewater treatment plant (WWTP) effluent on the toxicity of the recipient water body
and the effectiveness of the disinfection treatment applied (sodium hypochloride) to assure the compliance of both microbiological
and toxicological emission limits. No toxicity was found in the majority of samples collected from the recipient river, upstream
and downstream of the WWTP, using three different toxicity tests (Vibrio fischeri, Daphnia magna, and Pseudokirchneriella subcapitata). Only three samples presented toxic unit (TU) values with V. fischeri, and one presented TU with P. subcapitata. The influent toxicity ranged from slightly toxic to toxic (TU = 0.68–4.47) with V. fischeri, while only three samples presented TU values with the other tests. No toxicity was found in the absence of chlorination,
while the mean toxicity was 3.42 ± 4.12 TU with chlorination in the effluent. Although no toxicity or very slight toxicity
was found in the receiving water, its residual toxicity was higher than the US EPA Quality Standard in two samples. Escherichia coli concentration had a lower mean value in the chlorinated effluent: 13,993 ± 12,037 CFU/100 mL vs. 62,857 ± 80,526 CFU/100 mL
for the not chlorinated effluent. This difference was shown to be significant (p < 0.05). E. coli in ten chlorinated samples was higher than the limit established by European and Italian Legislation. The mean highest trihalomethanes
(THMs) value was found in the influent samples (2.79 ± 1.40 μg/L), while the mean highest disinfection by-products (DBPs)
was found in the effluent samples (1.85 ± 2.25 μg/L). Significant correlations were found between toxicity, sodium hypochlorite,
THMs, DBPs, E. coli, and residual chlorine. In conclusion, this study highlighted that the disinfection of wastewater effluents with sodium hypochlorite
determines the increase of the toxicity, and sometimes is not enough to control the E. coli contamination. 相似文献
37.
38.
Brunialti G Giordani P Isocrono D Loppi S 《Environmental monitoring and assessment》2002,75(3):271-280
A total of 65 operators involved in lichen mapping studies in central and northwestern Italy underwent quality control tests during five lichen biomonitoring workshops organized between 1999and 2000. The results showed that 75% quantitative accuracy and90% quantitative precision can be regarded as satisfactory levels for lichen biodiversity data; 65% proved to be sufficientfor accuracy of taxonomic identification in the field. Average correct assignment of the interpretative naturality/alteration class was only 48.7%. The results indicated the need for taxonomic training. 相似文献
39.
Francesco Nazzi Renzo Bortolomeazzi Giorgio Della Vedova Fabio Del Piccolo Desiderato Annoscia Norberto Milani 《Die Naturwissenschaften》2009,96(2):309-314
The mite Varroa destructor Anderson & Trueman is a parasite of the honeybee Apis mellifera L. and represents a major threat for apiculture in the Western world. Reproduction takes place only inside bee brood cells
that are invaded just before sealing; drone cells are preferred over worker cells, whereas queen cells are not normally invaded.
Lower incidence of mites in queen cells is at least partly due to the deterrent activity of royal jelly. In this study, the
repellent properties of royal jelly were investigated using a lab bioassay. Chemical analysis showed that octanoic acid is
a major volatile component of royal jelly; by contrast, the concentration is much lower in drone and worker larval food. Bioassays,
carried out under lab conditions, demonstrated that octanoic acid is repellent to the mite. Field studies in bee colonies
confirmed that the compound may interfere with the process of cell invasion by the mite. 相似文献
40.
Naphthalenesulfonates were found in water samples of the Italian river Bormida. Samples were collected at increasing distances from the point of emission of pollutants, and their analyses showed that these compounds can persist in river water and that they can propagate for considerable distances. 相似文献