Simulating the production and dispersion of environmental pollutants in aerosol phase in an urban area of great historical and cultural value

Mathematical models were developed to simulate the production and dispersion of aerosol phase atmospheric pollutants which are the main cause of the deterioration of monuments of great historical and cultural value. This work focuses on Particulate Matter (PM) considered the primary cause of monument darkening. Road traffic is the greatest contributor to PM in urban areas. Specific emission and dispersion models were used to study typical urban configurations. The area selected for this study was the city of Florence, a suitable test bench considering the magnitude of architectural heritage together with the remarkable effect of the PM pollution from road traffic. The COPERT model, to calculate emissions, and the street canyon model coupled with the CALINE model, to simulate pollutant dispersion, were used. The PM concentrations estimated by the models were compared to actual PM concentration measurements, as well as related to the trend of some meteorological variables. The results obtained may be defined as very encouraging even the models correlated poorly: the estimated concentration trends as daily averages moderately reproduce the same trends of the measured values.     

An Eco-balance of a Recycling Plant for Spent Lead–Acid Batteries

This study applies Life Cycle Assessment (LCA) methodology to present an eco-balance of a recycling plant that treats spent lead–acid batteries. The recycling plant uses pyrometallurgical treatment to obtain lead from spent batteries. The application of LCA methodology (ISO 14040 series) enabled us to assess the potential environmental impacts arising from the recycling plants operations. Thus, net emissions of greenhouse gases as well as other major environmental consequences were examined and hot spots inside the recycling plant were identified. A sensitivity analysis was also performed on certain variables to evaluate their effect on the LCA study. The LCA of a recycling plant for spent lead–acid batteries presented shows that this methodology allows all of the major environmental consequences associated with lead recycling using the pyrometallurgical process to be examined. The study highlights areas in which environmental improvements are easily achievable by a business, providing a basis for suggestions to minimize the environmental impact of its production phases, improving process and company performance in environmental terms.