全文获取类型
收费全文 | 1291篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
安全科学 | 43篇 |
废物处理 | 86篇 |
环保管理 | 91篇 |
综合类 | 124篇 |
基础理论 | 276篇 |
环境理论 | 2篇 |
污染及防治 | 457篇 |
评价与监测 | 145篇 |
社会与环境 | 81篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 12篇 |
2022年 | 42篇 |
2021年 | 34篇 |
2020年 | 18篇 |
2019年 | 25篇 |
2018年 | 39篇 |
2017年 | 52篇 |
2016年 | 61篇 |
2015年 | 40篇 |
2014年 | 77篇 |
2013年 | 118篇 |
2012年 | 78篇 |
2011年 | 111篇 |
2010年 | 71篇 |
2009年 | 55篇 |
2008年 | 68篇 |
2007年 | 96篇 |
2006年 | 60篇 |
2005年 | 36篇 |
2004年 | 37篇 |
2003年 | 32篇 |
2002年 | 34篇 |
2001年 | 18篇 |
2000年 | 10篇 |
1999年 | 13篇 |
1998年 | 3篇 |
1997年 | 8篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 3篇 |
1991年 | 4篇 |
1989年 | 3篇 |
1987年 | 3篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1979年 | 1篇 |
1974年 | 1篇 |
1972年 | 2篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1964年 | 2篇 |
1961年 | 3篇 |
1960年 | 1篇 |
1959年 | 1篇 |
1932年 | 1篇 |
排序方式: 共有1307条查询结果,搜索用时 281 毫秒
51.
Pedro Salvador Begoña Artíñano Casimiro Pio Joana Afonso Michel Legrand Hans Puxbaum Samuel Hammer 《Atmospheric environment (Oxford, England : 1994)》2010,44(19):2316-2329
This study has investigated the influence of synoptic weather patterns and long-range transport episodes on the concentrations of several compounds related to different aerosol sources (EC, OC, SO42?, Ca2+, Na+, K+, 210Pb, levoglucosan and dicarboxylic acids) registered in PM10 or PM2.5 aerosol samples collected at three remote background sites in central Europe. Air mass back-trajectories arriving at these sites have been analysed by statistical methods. Firstly, air mass back-trajectories have been grouped into clusters. Each cluster corresponds to specific meteorological scenarios, which were extracted and discussed. Finally, redistributed concentration fields have been computed to identify the main potential source regions of the different key aerosol components. A marked seasonal pattern is observed in the occurrence of the different clusters, with fast westerly and northerly Atlantic flows during winter and weak circulation flows in summer. Spring and fall were characterised by advection of moderate flows from northeastern and eastern Europe. Significant inter-cluster differences were observed for concentrations of receptor aerosol components, with the highest concentrations of EC, OC, SO42?, K+ and 210Pb associated with local and mesoscale aerosol sources located over central Europe related to enhanced photochemical processes. Emissions produced by fossil fuel and biomass burning processes from the Baltic countries, Byelorussia, western regions of Russia and Kazakhstan in spring and fall also contribute to elevated levels of EC, OC, SO42?, K+ and 210Pb. In the summer period long-range transport episodes of mineral dust from North-African deserts were also frequently detected, which caused elevated concentrations of coarse Ca2+ at sites. The baseline aerosol concentrations in central Europe at the high altitude background sites were registered in winter, with the exception of coarse Na+. While the relatively high concentrations of Na+ can be explained by sea salt advected from the Atlantic, the low levels of other aerosol components are caused by efficient aerosol scavenging associated to advections of Atlantic air masses, as well as lower emissions of these species over the Atlantic compared to those over the European continent and very limited vertical air mass exchange over the continent. 相似文献
52.
Anita Jemec Damjana Drobne Tatjana Tišler Kristina Sepčić 《Environmental science and pollution research international》2010,17(3):571-581
Background, aim and scope
For reliable environmental risk assessment of pollutants, knowledge on the effects at different levels of biological organisation is needed. During the early days of biomarker research in environmental studies approximately two decades ago, biochemical biomarkers were considered as the most promising tool for such purposes. Among these, three enzymes have often been studied: catalase (CAT), glutathione S-transferase (GST) and cholinesterase (ChE). However, despite their intensive research, their measurements in invertebrates have not been commonly applied in environmental risk assessment (ERA) or for regulatory purposes. 相似文献53.
Roberto Rosal Ismael Rodea-Palomares Karina Boltes Francisca Fernández-Piñas Francisco Leganés Soledad Gonzalo Alice Petre 《Environmental science and pollution research international》2010,17(1):135-144
Background, aim, and scope
The high consumption of blood lipid regulators is leading to frequent reports of the occurrence of fibrates in natural streams and wastewater effluents. This paper describes a study undertaken to evaluate the acute toxicity of bezafibrate, clofibric acid, gemfibrozil, and fenofibric acid, a metabolite of fenofibrate whose ecotoxicity has not been previously reported. 相似文献54.
María Luz Martín-Peña José María Sánchez-López 《Journal of Environmental Planning and Management》2010,53(3):297-315
Drawing on Ajzen's Theory of Planned Behaviour, this paper analyses whether there is a relation between management's behavioural intentions toward an environmental problem and the company's specific actions in this area, and also considers the impact of the company size on these actions. For the data, a questionnaire was sent to 184 managers employed in industrial companies located in Spain which belonged to the automobile industry. The empirical analysis produces positive and significant regression coefficients and provides support for the hypotheses proposed. Specifically, the results show that the environmental actions carried out in the company respond at least in part to management's behavioural intentions toward these issues and the size of the firm. 相似文献
55.
José Mario Aquino Romeu C. Rocha-Filho Cristina Sáez Pablo Cañizares Manuel A. Rodrigo 《Environmental science and pollution research international》2014,21(14):8442-8450
Oxidation of anthraquinonic dye Acid Blue 62 by electrolysis with conductive-diamond electrodes is studied in this work. COD, TOC, and color have been selected to monitor the degradation of the molecule as a function of several operating inputs (current density, pH, temperature, and NaCl concentration). Results show that the electrochemical oxidation of this model of large molecules follows a first order kinetics in all the conditions assessed, and it does not depend on the pH and temperature. The occurrence of chloride ions in wastewaters increases the rate of color and COD removal as a consequence of the mediated oxidation promoted by the chlorinated oxidizing species. However, chloride occurrence does not have an influence on the mineralization rate. First-order kinetic-constants for color depletion (attack to chromophores groups), oxidation (COD removal), and mineralization (TOC removal) were found to depend on the current density and to increase significantly with its value. A single model was proposed to explain these changes in terms of the mediated oxidation processes. Rate of mineralization remained very close to that expected for a purely mass transfer-controlled process. This was explained assuming that mediated oxidation does not have a significant influence on the mineralization in spite it has some effect on intermediate oxidation stages. The efficiency of the oxidation was found to depend mainly on the concentration of COD being negligible the effect of the other inputs assessed except for the occurrence of chloride ions. Opposite, the efficiency of mineralization depends on concentration of TOC and current density and it did not depend on the chloride occurrence. This observation was found to have an important influence on the power required to remove a given percentage of the initial TOC or COD. To decrease COD efficiently, the occurrence of chloride in the solution is very important, while to remove TOC efficiently, it is more important to work at low current densities and chloride effect is negligible. Energy consumption could be decreased by folds using the proper conditions. 相似文献
56.
Marko Kete Egon Pavlica Fernando Fresno Gvido Bratina Urška Lavrenčič Štangar 《Environmental science and pollution research international》2014,21(19):11238-11249
Photocatalytic properties of titanium (IV) oxide (TiO2) in anatase form can be used for various purposes, including photocatalytic purification of water. For such an application, suspended or fixed photocatalytic reactors are used. Those with fixed phase seem to be preferred due to some advantages, one of which is the avoidance of photocatalyst filtration. To avoid leaching and exfoliation of the fixed phase, an immobilization procedure leading to a good adhesion of a catalyst to a substrate is crucial. Within this work, we present physical and photocatalytic characterization results of five commercially available TiO2 photocatalysts (P25, P90, PC500, KRONOClean 7000, VPC-10) and one pigment (Hombitan LO-CR-S-M), which were successfully immobilized on glass slides by a “sol suspension” procedure. Different mechanical tests and characterization methods were used to evaluate the stability and morphology of the layers. Evaluation of photocatalytic activity was done by tests under UVA and UV–vis irradiation, using a method based on the detection of the fluorescent oxidation product of terephthalic acid (TPA), i.e., hydroxyterephthalic acid (HTPA). Aeroxide® P90 incorporated into the silica-titania binder was the most photocatalytically active layer and, unlike the others, showed significant increase of photocatalytic activity through the entire range of tested UVA irradiation intensities (2.3 mW/cm2–6.1 mW/cm2). The high mechanical stability of some photocatalytic layers allows using them in water photocatalytic purification reactions. 相似文献
57.
58.
59.
60.
Emma Gracia-Lor María Ibáñez Tatiana Zamora Juan V. Sancho Félix Hernández 《Environmental science and pollution research international》2014,21(8):5496-5510
Pharmaceuticals, once ingested, are commonly metabolized in the body into more polar and soluble forms. These compounds might not be completely removed in the wastewater treatment plants and consequently being discharged into the aquatic ecosystem. In this work, a multi-class sensitive method for the analysis of 21 compounds, including 7 widely consumed pharmaceuticals and 14 relevant metabolites, has been developed based on the use of UHPLC-MS/MS in selected reaction monitoring (SRM) mode. The method was validated in six surface waters (SW) and six effluent wastewaters (EWW) at realistic concentration levels that can be found in waters. The optimized method was applied to the analysis of different types of water samples (rivers, lakes and effluent wastewater), detecting nearly all the parent compounds and metabolites investigated in this work. This fact illustrates that not only pharmaceuticals but also their metabolites are commonly present in these types of waters. Analytical research and monitoring programs should be directed not only towards parent pharmaceuticals but also towards relevant metabolites to have a realistic overview of the impact of pharmaceuticals in the aquatic environment. 相似文献