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21.
S. Trivikrama Rao Gopal Sistla 《Journal of the Air & Waste Management Association (1995)》2013,63(6):645-648
Abstract The topic of global warming as a result of increased atmospheric CO2 concentration is arguably the most important environmental issue that the world faces today. It is a global problem that will need to be solved on a global level. The link between anthropogenic emissions of CO2 with increased atmospheric CO2 levels and, in turn, with increased global temperatures has been well established and accepted by the world. International organizations such as the United Nations Framework Convention on Climate Change (UNFCCC) and the Intergovernmental Panel on Climate Change (IPCC) have been formed to address this issue. Three options are being explored to stabilize atmospheric levels of greenhouse gases (GHGs) and global temperatures without severely and negatively impacting standard of living: (1) increasing energy efficiency, (2) switching to less carbon-intensive sources of energy, and (3) carbon sequestration. To be successful, all three options must be used in concert. The third option is the subject of this review. Specifically, this review will cover the capture and geologic sequestration of CO2 generated from large point sources, namely fossil-fuel-fired power gasification plants. Sequestration of CO2 in geological formations is necessary to meet the President’s Global Climate Change Initiative target of an 18% reduction in GHG intensity by 2012. Further, the best strategy to stabilize the atmospheric concentration of CO2 results from a multifaceted approach where sequestration of CO2 into geological formations is combined with increased efficiency in electric power generation and utilization, increased conservation, increased use of lower carbonintensity fuels, and increased use of nuclear energy and renewables. This review covers the separation and capture of CO2 from both flue gas and fuel gas using wet scrubbing technologies, dry regenerable sorbents, membranes, cryogenics, pressure and temperature swing adsorption, and other advanced concepts. Existing commercial CO2 capture facilities at electric power-generating stations based on the use of monoethanolamine are described, as is the Rectisol process used by Dakota Gasification to separate and capture CO2 from a coal gasifier. Two technologies for storage of the captured CO2 are reviewed—sequestration in deep unmineable coalbeds with concomitant recovery of CH4 and sequestration in deep saline aquifers. Key issues for both of these techniques include estimating the potential storage capacity, the storage integrity, and the physical and chemical processes that are initiated by injecting CO2 underground. Recent studies using computer modeling as well as laboratory and field experimentation are presented here. In addition, several projects have been initiated in which CO2 is injected into a deep coal seam or saline aquifer. The current status of several such projects is discussed. Included is a commercial-scale project in which a million tons of CO2 are injected annually into an aquifer under the North Sea in Norway. The review makes the case that this can all be accomplished safely with off-the-shelf technologies. However, substantial research and development must be performed to reduce the cost, decrease the risks, and increase the safety of sequestration technologies. This review also includes discussion of possible problems related to deep injection of CO2 . There are safety concerns that need to be addressed because of the possibilities of leakage to the surface and induced seismic activity. These issues are presented along with a case study of a similar incident in the past. It is clear that monitoring and verification of storage will be a crucial part of all geological sequestration practices so that such problems may be avoided. Available techniques include direct measurement of CO2 and CH4 surface soil fluxes, the use of chemical tracers, and underground 4-D seismic monitoring. Ten new hypotheses were formulated to describe what happens when CO2 is pumped into a coal seam. These hypotheses provide significant insight into the fundamental chemical, physical, and thermodynamic phenomena that occur during coal seam sequestration of CO2 . 相似文献
22.
Kumar Gaurav Richa Srivastava Jai Gopal Sharma Ram Singh Vishrut Singh 《International Journal of Green Energy》2016,13(3):320-327
Biodiesel provides a feasible solution to the twin crisis of energy security and environmental concerns prevalent today, and it can be extracted from conventional oil crops as well as microalgae. However, lipid productivity in case of microalgae is much higher and has several advantages as compared with crop plants, so it is a better feedstock for biodiesel. In case of Chlorella pyrenoidosa, the heterotrophic cultured cells were found to be better in terms of lipid production, and ultimately biodiesel production, but the bottleneck is that in this mode glucose is used to feed the cells, which amounts to almost 80% of the total cost of biodiesel production. The purpose of this study is to evaluate and highlight the feasibility of using the industrially cheap cane molasses as a carbon source in place of glucose for a large-scale, low-cost lipid production of Chlorella pyrenoidosa. When treated molasses was used as a carbon source instead of glucose, the biomass sharply increases from 0.89 to 1.22 g L–1. On the other hand, the total lipid content increases from 0.27 to 0.66 g g–1. The specific growth rate and yield was higher in treated molasses as compared with that in glucose-supplemented. A mathematical model was also developed based on logistic, Luedeking–Piret, and Luedeking-Piret-like equations. Model predictions were in satisfactory agreement with the measured data, and the mode of lipid production was growth-associated. 相似文献
23.
Gopal R. Patil 《Environmental Modeling and Assessment》2016,21(5):629-642
Tailpipe emissions in the road transportation system are a major source of air pollution and greenhouse gases. One of the possible approaches is to influence drivers’ routing decisions such that the emissions and fuel consumption is minimized. In order to evaluate such condition, we develop environmental traffic assignment (E-TA) models based on user equilibrium (UE) and system optimal (SO) behavioral principles. Extending the traditional travel time-based UE and SO principles to E-TA is not straightforward because, unlike travel time, the rate of emissions increases with the increase in vehicle speed beyond a certain point. The results of various TA models show a network-wide traffic control strategy in which vehicles are routed according to SO-based E-TA, can reduce system-wide emissions. However, a system in which drivers make routing decisions to minimize their own emissions (E-UE system) results in a paradoxical situation of increased individual as well as system-wide emissions. 相似文献
24.
Excess lead alters growth, metabolism and translocation of certain nutrients in radish 总被引:4,自引:0,他引:4
To elucidate the deleterious effects of excess lead on radish (Raphanus sativus) cv. Jaunpuri plants were grown in refined sand in complete nutrient solution for 30 days. On the 31st day lead nitrate was superimposed at 0.1 and 0.5mM to radish for 65 days. A set of plants in complete nutrient solution was maintained as control for the same period without lead. Excess Pb at 0.5mM showed growth depression with interveinal chlorosis on young leaves at apex. Excess Pb reduced the fresh and dry weight pronouncedly at d 65. Lead accumulation reduced the concentration of chlorophyll, iron, sulphur (in tops), Hill reaction activity and catalase activity whereas increased the concentration of phosphorus, sulphur (in roots) and activity of peroxidase, acid phosphatase and ribonuclease in leaves of radish. 相似文献
25.
Shashi B. Singh Irani Mukherjee Jaya Maisnam Praveen Kumar Madhuban Gopal Gita Kulshrestha 《Journal of environmental science and health. Part. B》2013,48(4):300-306
Studies were conducted to analyze the residue of commonly used pesticides viz. methyl parathion, chloropyrifos, endosulfan, cypermethrin, fenvalerate, carbendazim, imidacloprid and carbaryl in mango, Dashehari variety, integrated pest management (IPM) and non-IPM samples were collected from the IPM and non-IPM orchards, Lucknow, India. We also present a method for the simultaneous determination of these pesticides in mango samples. Residues of methyl parathion, chloropyriphos, endosulfan, cypermethrin, fenvalerate were extracted from the samples with acetone: cyclohexane: ethyl acetate in the ratio 2:1:1 followed by cleanup using neutral alumina. Analysis was performed by gas chromatography-electron capture detector (GC-ECD) with a megabore column (OV-1). Residues of carbendazim, imidacloprid and carbaryl were extracted with acetone and after cleanup, analysis was performed by high performance liquid chromatography (HPLC) using photo diode array (PDA) detector. Recoveries of all the pesticides ranged between 72.7 – 110.6%, at 0.1 and 1.0 μg g? 1 level of fortification. The residues detected in non-IPM samples of mango were found to be below the prescribed limits of maximum residue limit (MRL) while IPM samples were free from pesticide residues. 相似文献
26.
The activity levels of lactate dehydrogenase andlactic acid were assessed in various tissues of the fishduring exposure to lethal concentration of group-IIPyrethroids (deltamethrin, cypermethrin, fenvalerate andfluvalinate) for a period of 72 hours. The results showedsteady increased levels in all the tissues (blood,muscle, brain and liver) with response patterncharacteristic of their own. The increased LDH activityand lactic acid levels indicate the shifting of aerobicglycolysis to anaerobiosis and its further utilizationfor energy production during adaptation to toxic stress. 相似文献
27.
V. Gopal S. Parvathy P. R. Balasubramanian 《Environmental monitoring and assessment》1997,48(2):117-124
Cyprinus carpio were exposed to two non-essential (Hg and Pb)and two essential (Cu and Ni) heavy metal salts at lethal andsub-lethal concentrations. Blood serum total protein, serum globulinand serum albumin was analysed every 2 hr for 24 hrs andagain at 48 and 72 hrs. Serum protein and globulin level showedan intial sharp increase from 2 to 20 hrs, followed by decline thatextend over a period of 72 hrs. Serum albumin showed an initialimmediate decline from 2 to 4 hrs, followed by an intermittent period of recovery and decline that extend over a period of 72hrs. Both lethal and sub-lethal concentrations of metal salts elicited asimilar pattern of response varying only in magnitude. The use offish blood serum protein, albumin and globulin measurements as general indicators of pollutant stress response isdiscussed. 相似文献
28.
Kumari A Sinha RK Gopal K Lata S 《Journal of environmental biology / Academy of Environmental Biology, India》2002,23(3):279-281
Concentrations of DDT, HCH, aldrin and endosulfan were determined in river dolphins from the River Ganges, Patna. Among the organochlorines studied in the dolphins, DDT concentration was highest followed by HCH. This shows exposure of dolphins to these organochlorine pesticides. Presences of organochlorines to higher degree in tissues suggest that the river dolphins be at greater risk due to pesticidal contamination of the river system. 相似文献
29.
Babu MS Gopal NV Reddy KP 《Journal of environmental biology / Academy of Environmental Biology, India》2007,28(1):21-27
This study reports the effects of low level developmental Pb exposure on specific brain regions like hippocampus, cerebellum and cerebral hemispheres of antioxidant enzyme activities. Wistar dams were exposed to 50 ppm, 100 ppm and 500 ppm of Pb acetate in drinking water during pregnancy and lactation (gestation day 6 through PND 21 (post natal day) and activities of superoxide dismutase (SOD), glutathione peroxidase (GSH-Px) and glutathione reductase (GR) were determined in the hippocampus, cerebellum and cerebral hemispheres of pups during treatment period (PND 7, 14, and 21 days) and also during withdrawl period (PND 35, 45, 60 and 90 days). During treatment period, SOD activity significantly (p < 0.05) decreased in all regions of all the treated groups with maximum decrease in 500 ppm treated group of 21 days, while GSH-Px and GR activities increased with maximum increase in 21 days aged 500 ppm group. During withdrawl period, the activities of all enzymes were significantly (p < 0.05) reversed. Thus the perinatal exposure of dams to variable dosages of low level lead results in characteristic neurochemical alterations in rat brain regions due to impaired antioxidants function. 相似文献
30.
Subhashis Sahu Santi Gopal Maity Subhabrata Moitra Moumita Sett Prasun Haldar 《International journal of occupational safety and ergonomics》2013,19(4):657-665
Van-rickshaw is a popular mode of transport of people and merchandise in developing countries. The purpose of this study was to assess the effect of age on cardiovascular load of van-rickshaw pullers in the summer season (March-June) in real situations. In 142 participants, divided into 2 age groups (25-40 and 41-55 years), cardiovascular load was assessed on the basis of working and partial recovery heart rate (HR), predicted maximal HR, working maximal HR, average working HR, percentage of reserved HR, sum of recovery heart beats, percentage of recovery, relative and net cardiac cost, etc. Except for percentage of recovery, all parameters differed significantly between the groups and were significantly correlated with age. As this activity is very stressful, it places a heavy demand on the cardiovascular system. Therefore, age is an important factor for sustainability of the work, especially in a hot environment. Some ergonomic interventions are necessary to reduce cardiovascular load. 相似文献