Investigation of the concentration and isotopic composition of inputs and outputs of Pb in waters at an upland catchment in NE Scotland

As a consequence of the accumulation of anthropogenic Pb in upland catchments, there has been much recent concern about the potential mobilisation and transport of Pb from the soils to receiving waters and also the possible harmful effects that this might have on aquatic biota. This paper presents the findings of a two-year study of Pb behaviour in an organic-rich upland catchment at Glensaugh in NE Scotland. Pb inputs to the catchment were characterised by direct measurements of Pb concentration and (206)Pb/(207)Pb ratios in rain water and interception. Pb outputs from the catchment were calculated from measurements on stream water samples taken from the two main streams, the Cairn Burn and Birnie Burn. The relative contribution of Pb from groundwater and throughflow, under different flow conditions (base flow and high flow), to stream waters was investigated via analysis of springs sourced from groundwater and of waters flowing through the various soil horizons (S (surface), A, B, C, and D), respectively. The outcome of intensive sampling and analysis over the two-year time period was that, even with marked reduction in Pb inputs over the past two decades, the catchment was still acting as a net sink for the current atmospheric deposition. Although the Pb isotopic signature for stream water is very similar to that for the contemporaneous rain water ((206)Pb/(207)Pb approximately 1.15-1.16), only a small portion of the rain water is transferred directly to stream water. Instead, the Pb input is transferred to the stream waters mainly via groundwater and it was also confirmed that the latter had a similar Pb isotopic signature. From the Pb isotopic measurements on throughflow waters, however, Pb being removed via the streams contained some previously deposited Pb, i.e. mobilisation of a small portion of soil-derived anthropogenic Pb was occurring. These findings are important not only with respect to the source/sink status of the catchment but also for calculation of the extent of retention of the current atmospheric Pb inputs, which must take account of the release of previously deposited Pb from the catchment soils, a process occurring mainly under high flow conditions.     

Performance optimisation of a passive sampler for monitoring hydrophobic organic pollutants in water

The performance of an integrative passive sampler that consists of a C18 Empore disk sorbent receiving phase fitted with low density polyethylene membrane was optimised for the measurement of time-weighted average concentrations of hydrophobic micropollutants in water. A substantial improvement of sampling characteristics including the rate of sampling and the sampling precision was achieved by decreasing the internal sampler resistance to mass transfer of hydrophobic organic chemicals. This was achieved by adding a small volume of n-octanol, a solvent with high permeability (solubility [times] diffusivity) for target analytes, to the interstial space between the receiving sorbent phase and the polyethylene diffusion-limiting membrane.     

Mean Annual Temperature and Total Annual Precipitation Trends at Canadian Biosphere Reserves

This article examines instrumental climate records from a varietyof stations associated with the following Biosphere Reserves across Canada: (i) Waterton Lakes, (ii) Riding Mountain, (iii) Niagara Escarpment, (iv) Long Point, and (v) Kejimkujik (Candidate Biosphere Reserve). Annual series are generated fromdaily temperature and precipitation values. In addition, homogeneous data are used from other stations and regional records to supplement the records from the local biosphere stations. Long term trends are identified over the period of the instrumental record. In general, data from the interval 1900 to 1998 show cooler temperatures in the 1920's, warmingfrom the early 1940's into the early 1950's, cooling into the1970's, and subsequent warming. At many stations, 1998 is the warmest in the instrumental record. Comparisons with the regional data sets show good agreements between the temperatureseries. The 20th century warming is approximately 1.0 °C in the Riding Mountain area and 0.6 °Cin the Long Point, Niagara Escarpment, and Waterton Lakes areas.There has been slight cooling in the Kejimkujik area over the past half century. Precipitation data show increasing trends inthe Kejimkujik, Long Point, Niagara Escarpment, and Waterton Lakes areas with no long term trend in the Riding Mountain area. This work is part of the Canadian Biosphere Reserves Association (CBRA) Climate Change Initiative (CCI), designed to present climate change information to Biosphere Reserve communities to allow local organizations to understand climate change and adapt to potential impacts.     

An objective and practical model for economic evaluation of environmental investment projects

Summary The problems faced by business as a result of the growth of the environmental agenda are described. The consequence this has on investment decisions is outlined and the trend, largely induced by present day investment appraisal techniques, for adopting end-of-pipe rather than Clean technology solutions is explained. A solution to this reactive investment approach is described by way of the Paras model. This adopts a holistic and practical approach and considers the special nature of environmental investments throughout all stages of the analysis. By objectively incorporating a measure for uncertainty within the analysis it adds considerable value and rationality to the decision-making process. The collaborative research project between the University of Surrey and Paras Ltd is described. This is run under the Engineering Doctorate programme and aims to develop a multicriteria decision tool to support the parallel quantification of the environmental and financial performance of investment projects.Graham Earl is a research engineer with the Engineering Doctorate (EngD) programme and is sponsored by the University of Surrey and Paras Ltd. Tuula Moilanen is a senior consultant with Paras Ltd at 120A, High Street, Newport, Isle of Wight, P030 ITP, UK. Paras are a technology and engineering consultancy and the developers of the Paras financial model for the evaluation of environmental investments. The authors are currently actively seeking companies who would be interested in contributing to further research through a test case, be it in the form of past or planned environmental investment decision.     

Valuing uncertain asset cash flows when there are no options: A real options approach

The real option valuation method is often presented as an alternative to the traditional discounted cash flow (DCF) approach because it is able to quantify the additional asset value arising from flexible asset management. However, these two valuation methods differ on a more fundamental level: their approach to determining the effects of cash flow uncertainty on asset value. Real option valuation adjusts for risk within the cash flow components while the DCF method discounts for risk at the aggregate net cash flow. This seemingly small difference allows the real option method to differentiate assets according to their unique risk characteristics, while the conventional DCF approach cannot.This paper presents an overview of the real options and conventional DCF frameworks for valuing uncertain cash flows. To emphasize the approaches' different treatment of risk we assume an absence of managerial flexibility. Using simple algebra, this paper demonstrates that the traditional DCF method fails to adequately discount net cash flow risk, no matter what discount rate is used. Finally, in a stylized mining example we show that DCF rules would lead a developer to forego $24.5 million in value creation, at a profitability index of 1.49, by making a poor investment decision.     

Bioremediation of Stranded Oil on an Arctic Shoreline

The application of slow-release and soluble fertilizers proved to be an effective and environmentally benign way of stimulating oil biodegradation on an Arctic shoreline. Fertilizer application to the surface of the beach delivered nutrients to the oiled sediment beneath the beach surface. There was no significant run-off of this fertilizer to either the nearshore water or to unfertilized plots, and there were no adverse toxicological effects of the fertilizer application. The fertilizer application was followed by an increase in oxygen consumption and carbon dioxide evolution from the beach, increased microbial biomass, and significantly greater biodegradation of oil on the plots that had received fertilizer. The rate of oil biodegradation was approximately doubled over the course of a year by fertilizer applications in the first two months after the spill.Simple test kits proved adequate to monitor the fertilizer-application process in the field in a time frame that would allow the application process to be fine-tuned during treatment on a real spill. Simple test kits and portable instrumentation were useful in demonstrating the initial success of the bioremediation strategy.     

EFFECTS OF CLIMATE VARIABILITY ON RIVERS: CONSEQUENCES FOR LONG TERM WATER QUALITY ANALYSIS1

ABSTRACT: Associations between the El Nino Southern Oscillation (ENSO) climate pattern and temporal variability in flow and 12 water quality variables were assessed at 77 river sites throughout New Zealand over a 13‐year period (1989 through 2001). Trends in water quality were determined for the same period. All 13 variables showed statistically significant linear regression relationships with values of the Southern Oscillation Index (SOI). The strongest relationships were for water temperature (mean R²= 0.20), dissolved reactive phosphorus (0.18), and oxidized nitrogen (0.17). The association with SOI varied by climate region. The observed patterns were generally consistent with known ENSO effects on New Zealand rainfall and air temperature. Trends in water quality variables for the periods 1989 through 1993, 1994 through 1998, and 1989 through 1998 were reasonably consistent with trends in SOI, even when the influence of river flow was removed from the data. This suggests that SOI effects on water quality are not necessarily a direct consequence of changes in flow associated with rainfall variation. In addition, both Baseline (32 upstream) and Impact (45 downstream) sites showed similar trends, indicating that changes in management were not directly responsible. We conclude that interpretation of long term water quality datasets in rivers requires that climate variability be fully acknowledged and dealt with explicitly in trend analyses.     

PLANNITG INDIANA'S WATER INFRASTRUCTURE FROM A COMPETITIVE PERSPECTIVE1

ABSTRACT: Indiana has embarked on a program to assess the condition of its infrastructure and to plan for its future. The perspective of this planning differs from the traditional “master plan” approach — instead, the focus is on competitiveness for economic development. The initial work on the water and sewerage competitiveness of the infrastructure includes: (1) a comparative analysis of the water resources and infrastructure of Indiana and its industrial midwestern neighbors; (2) a technology scan to identify possible technological opportunities that may be important for Indiana; and (3) a set of recommendations for future planning. This work is preliminary in nature but should serve as a starting point for continued strategic planning over the next decade for positioning of Indiana's water and sewerage infrastructure as a key element in the economic growth equation.     

New Proof-of-Concept in Viral Inactivation: Virucidal Efficacy of 405 nm Light Against Feline Calicivirus as a Model for Norovirus Decontamination

The requirement for novel decontamination technologies for use in hospitals is ever present. One such system uses 405 nm visible light to inactivate microorganisms via ROS-generated oxidative damage. Although effective for bacterial and fungal inactivation, little is known about the virucidal effects of 405 nm light. Norovirus (NoV) gastroenteritis outbreaks often occur in the clinical setting, and this study was designed to investigate potential inactivation effects of 405 nm light on the NoV surrogate, feline calicivirus (FCV). FCV was exposed to 405 nm light whilst suspended in minimal and organically-rich media to establish the virucidal efficacy and the effect biologically-relevant material may play in viral susceptibility. Antiviral activity was successfully demonstrated with a 4 Log₁₀ (99.99%) reduction in infectivity when suspended in minimal media evident after a dose of 2.8 kJ cm^?2. FCV exposed in artificial faeces, artificial saliva, blood plasma and other organically rich media exhibited an equivalent level of inactivation using between 50–85% less dose of the light, indicating enhanced inactivation when the virus is present in organically-rich biologically-relevant media. Further research in this area could aid in the development of 405 nm light technology for effective NoV decontamination within the hospital environment.