Climate impact potential of utilizing forest residues for bioenergy in Norway

The utilization of forest residues for bioenergy in Norway is foreseen to increase due to the government call to double bioenergy output by 2020 to thirty Tera-Watt hours. This study focuses on the climate impacts of bioenergy utilization where four forest residue extraction scenarios at clear-cut are considered: i) 75 % above ground residues (branches, (25 %) foliage, tops); ii) 75 % above and below ground residues (branches, tops, (25 %) foliage, stumps, coarse and small roots); iii) extracting 100 % of all available forest residue; and iv) leaving all residues in the forest. The Yasso07 soil-carbon model was utilized to quantify the carbon flux to the atmosphere due to the forest residues that are left in the forest in each scenario. The climate impact potential for each scenario was then calculated for the carbon-flux neutral Norway Spruce (Picea abies) forest system in five regions of Norway. The biogenic carbon dioxide emissions associated to decomposition upon forest floor, procurement losses and bioenergy conversion are included in these calculations. Results suggest that if such bioenergy can directly replace a fossil source of energy, the utilization of this biomass was found to be climatically beneficial in most fossil energy replacement cases and time horizons when compared to leaving the residues in the forest. Integrated global temperature change displacement factors have been developed which have been used to estimate the magnitude of this climate change mitigation over a particular time horizon.     

Inhalation exposure to volatile organic compounds in the printing industry

ABSTRACT

This study reports on the occupational inhalation exposure to VOCs of workers in the Kuwaiti printing industry. Using the evacuated canister methodology, we targeted 72 VOCs in three printeries and compared the concentrations to previous reports and relevant occupational exposure levels (OELs). We found that recent efforts in the printing industry to reduce VOC usage had been successful, as concentrations of key hazardous VOCs were substantially lower than anticipated. On the other hand, nearly all target VOCs were found. Non-production areas were sampled along with the offset printing areas, another strength of this study, and revealed exposures to hazardous VOCs among administers and digital printer and CTP operators. Exposure to ototoxic VOCs amounted to 1–3% of the OEL, consisting mostly of ethylbenzene, which was likely in use in two of the study printeries. Exposure to carcinogenic or probably carcinogenic VOCs was 15–20% of the OEL at four locations across the three printeries, consisting mostly of vinyl chloride and benzyl chloride. Vinyl chloride VOC was partially sourced from outdoors, but was also likely used inside the study printeries. Interestingly, concentrations of vinyl chloride were similar in most sampling locations to that of CFC-114, a CFC banned by the Montreal Protocol and not commonly used as a refrigerant. This unexpected finding suggests further study is warranted to identify the use of these VOCs in printeries. Exposure to hazardous VOCs up to nearly 50% of the OEL, consisting largely of bromoform and vinyl chloride. Bromoform was found in all the study printeries, sourced partially from outdoor air. The higher concentrations found inside the study printeries likely resulted from the use of the desalinated water for washing. This finding raises of emissions from sources other than blanket washes, and inks, etc. adding to the total VOC load in printery indoor air.

Implications: Results from this study indicate that efforts to reduce worker exposure to VOCs particularly dangerous to human health in recent years have been successful, but there is still much to be done to protect workers. Exposures to ototoxic and carcinogenic VOCs were identified, among both production and non-production workers. Unexpected findings included the apparent use in printing activities of the carcinogen vinyl chloride and CFC-114, banned under the Montreal Protocol. Observed lapses in safety procedures included failure to utilize ventilation systems and closing doors between work areas, indicating management and worker education should remain a priority.     

A longitudinal study of the relationship between career management and organizational commitment among graduates in the first ten years at work

This paper reports the findings of a two‐wave longitudinal study investigating relationships between organizational and individual career management activities and organizational commitment in the early years of graduate careers. Several hypotheses are tested and receive mixed support. High organizational commitment predicts the practice of career management activities by graduates to further their career within the organization while low commitment is closely associated with behaviour aimed at furthering the career outside the organization. Graduates who manage their own careers also receive more career management help from their employer. This suggests that there may be the potential for employers to create a ‘virtuous circle’ of career management in which individual and organizational activities complement each other. Copyright © 2002 John Wiley & Sons, Ltd.     

Chemical characterization of synthetic soil from composting coal combustion and pharmaceutical by-products

Land application of coal combustion by-products (CCBs) mixed with solid organic wastes (SOWs), such as municipal sewage sludge, has become increasingly popular as a means of productively using what were once considered waste products. Although bulk chemical and physical properties of several of these CCB-SOW materials have been reported, detailed information about their synthesis and mineralogy of the CCB-SOW materials has not been reported. In this paper, chemical and mineralogical properties of a soil-like material obtained from composting a mixture of CCBs with a pharmaceutical fermentation by-product (FB) were investigated at the laboratory and field scale. All starting materials and products were characterized by X-ray diffraction (XRD), fourier transform infrared (FFIR) spectroscopy, and elemental analyses. The results showed that the FB was strongly bound to the CCBs and could not be removed by washing. Within 2 wk of the start of a composting study, there was a rapid drop in pH from 12 to 8, an increase in temperature to 70 degrees C, and a reduction in the dissolved oxygen content, attributed to the rapid establishment of a highly active microbial population. Composting produced a soil-like material with high levels of plant nutrients, a high nutrient retention capacity, and metal contents similar to median levels of those metals reported for soils. The levels of boron and soluble salts are such that sensitive plants may initially show toxicity symptoms. However, with adequate rainfall, leaching should rapidly remove most of the B and soluble salts. With care, the material produced is safe for use as a synthetic topsoil.