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291.
危险化学品事故应急救援预案编制过程问题讨论 总被引:4,自引:0,他引:4
孙自涛 《安全.健康和环境》2006,6(2):36-38
通过对编制危险化学品事故应急救援预案过程中若干问题的思考,探讨如何按国家安全生产监督管理总局颁布的<危险化学品事故应急救援预案编制导则(单位版)>的要求,结合石化企业的实际情况,编制或修订详细完善的危险化学品事故应急救援预案. 相似文献
292.
随着石油化工企业应用放射源数量的不断增多,放射源的安全管理已经成为石化企业安全管理工作的重要组成部分,尤其是废弃、闲置的放射源,存放不当或保存时间过久很容易丢失.对此,国家和中国石化集团公司高度重视,陆续颁布了一系列新的法规、规定.如国务院新修订的<放射性同位素与射线装置安全和防护条例>从2005年12月1日起实施,中国石化集团公司安全环保局也于2004年新修订了<放射防护管理规定>,并实行射线作业票制度.在中国石化集团公司历年安全大检查中,加大了对放射源的安全检查力度,放射源安全检查成为每次安全检查的必检内容. 相似文献
293.
Fengyu Liu Wei Li Fusheng Li Shiguo Sun 《Environmental monitoring and assessment》2013,185(5):4153-4158
Considering of the basic properties and also the two nitrogen atoms in the structure, hydrazine hydrate was employed to be an amine additive candidate, to build a Ru(bpy) 3 2+ /hydrazine electrochemiluminescence (ECL) system, and ECL of Ru(bpy) 3 2+ has been employed for the determination of hydrazine hydrate in the paper. The result demonstrated that the logarithmic ECL increasing (ΔECL?=?ECLafter addition of hydrazine???ECLbefore addition of hydrazine) versus the logarithmic concentration of hydrazine hydrate is linear over a concentration range of 1.0?×?10?9 to 1.0?×?10?5?mol/L, on both glassy carbon and Pt electrodes in a pH 9 phosphate buffer. The hydrazine hydrate detection limit was down to 1.0?×?10?9?mol/L, comparatively lower than other detection methods. To check its applicability, the proposed method was applied to the determination of hydrazine hydrate added into a tap water sample with good reproducibility and stability. All these provide a possibility to develop a novel ECL detection method for hydrazine in water. 相似文献
294.
Sun HF Takata A Hata N Kasahara I Taguchi S 《Journal of environmental monitoring : JEM》2003,5(6):891-895
The degradation, sorption, transportation and material balance of cationic surfactants discharged from domestic waste into river water was studied. Ion-pair solid-phase extraction behavior showed that the sorption of cationic surfactants as an ion-pair with anionic surfactant onto river sediment was so strong that little cationic surfactant was found in the bulk water. Cationic surfactant was found in river sediment at more than 500 times higher concentration than that in the bulk water. The degradation of the cationic surfactant was very slow in river water and much slower in the sediment. A material balance of cationic surfactant was estimated for a river running through Toyama City by measuring the flow rate and the concentration of cationic surfactant in the water at several points. It was found that more than 30% of cationic surfactant introduced to the river was lost during the river running through ca. 3 km in 3 h. This reduction probably comes from a quick transfer of the cationic surfactant from river water to sediment and water weed by means of adsorption or precipitation with suspending solids. 相似文献
295.
296.
抚顺市大气重金属污染的植物监测与分析研究 总被引:1,自引:0,他引:1
采用生物富集原理,利用松针对抚顺地区大气中重金属元素的分布情况进行了监测与分析,结果表明:抚顺地区三种不同的松树对不同金属元素的富集能力是不同的,总体上看沙松的富集能力略高于油松和落叶松;工业区、交通干道和居民区松针中富集的金属含量高于农村地区;从不同的海拔高度上来看,在500米以下的低空大气中金属元素的分布量比高海拔地区高;不同金属元素间存在一定的相关关系。 相似文献
297.
Effluent dissolved organic nitrogen (DON) is problematic in nutrient sensitive surface waters and needs to be reduced to meet demanding total dissolved nitrogen discharge limits. Bioavailable DON (ABDON) is a portion of DON utilized by algae or algae + bacteria,while biodegradable DON (BDON) is a portion of DON decomposable by bacteria. ABDON and BDON in a two-stage trickling filter (TF) wastewater treatment plant was evaluated using three different microalgal species, Selenastrum capricornutum, Chlamydomonas reinhardtii and Chlorella vulgaris and mixed cultured bacteria. Results showed that up to 80% of DON was bioavailable to algae or algae + bacteria inoculum while up to 60% of DON was biodegradable in all the samples. Results showed that C. reinhardtii and C. vulgaris can be used as a test species the same as S. capricornutum since there were no significant differences among these three algae species based on their ability to remove nitrogen species. 相似文献
298.
Polycyclic aromatic hydrocarbons(PAHs), as persistent toxic substances(PTS), have been widely monitored in coastal environment, including seawater and sediment. However, scientific monitoring methods, like ecological risk assessment and integrated biomarker response, still need massive researches to verify their availabilities. This study was performed in March, May, August and October of 2018 at eight sites, Yellow River estuary(S1), Guangli Port(S2), Xiaying(S3), Laizhou(S4), Inner Bay(S5), Ou... 相似文献
299.
Jixing Liu Fuhong Yu Jian Liu Lifeng Cui Zhen Zhao Yuechang Wei Qianyao Sun 《环境科学学报(英文版)》2016,28(10):45-58
A series of meso-microporous Cu-SAPO-34 catalysts were successfully synthesized by a one-pot hydrothermal crystallization method, and these catalysts exhibited excellent NH_3-SCR performance at low temperature. Their structure and physic chemical properties were characterized by means of X-ray diffraction patterns(XRD), Scanning electron microscopy(SEM), Transmission electron microscopy(TEM), N_2 sorption-desorption, nuclear magnetic resonance(NMR), Inductively Coupled Plasma-Atomic Emission spectrometer(ICP-AES), X-ray absorption spectroscopy(XPS),Temperature-programmed desorption of ammonia(NH_3-TPD), Ultraviolet visible diffuse reflectance spectroscopy(UV-Vis DRS) and Temperature programmed reduction(TPR).The analysis results indicate that the high activities of Cu-SAPO-34 catalysts could be attributed to the enhancement of redox property, the formation of mesopores and the more acid sites. Furthermore, the kinetic results verify that the formation of mesopores remarkably reduces diffusion resistance and then improves the accessibility of reactants to catalytically active sites. The 1.0-Cu-SAPO-34 catalyst exhibited the high NO conversion( 90%) among the wide activity temperature window in the range of 150–425℃. 相似文献
300.
Ground observation data from 8 meteorological stations in Xi'an, air mass concentration data from 13 environmental quality monitoring sites in Xi'an, as well as radiosonde observation and wind profile radar data, were used in this study. Thereby, the process, causes and boundary layer meteorological characteristics of a heavy haze episode occurring from 16 to 25 December 2013 in Xi'an were analyzed. Principal component analysis showed that this haze pollution was mainly caused by the high-intensity emission and formation of gaseous pollutants (NO2, CO and SO2) and atmospheric particles (PM2.5 (fine particles) and PM10 (respirable suspended particle). The second cause was the relative humidity and continuous low temperature. The third cause was the allocation of the surface pressure field. The presence of a near-surface temperature inversion at the boundary layer formed favorable stratification conditions for the formation and maintenance of heavy haze pollution. The persistent thick haze layer weakened the solar radiation. Meanwhile, a warming effect in the urban canopy layer and in the transition zone from the urban friction sublayer to the urban canopy was indicated. All these conditions facilitated the maintenance and reinforcement of temperature inversion. The stable atmospheric stratification finally acted on the wind field in the boundary layer, and further weakened the exchange capacity of vertical turbulence. The superposition of a wind field with the horizontal gentle wind induced the typical air stagnation and finally caused the deterioration of air quality during this haze event. 相似文献