碱熔融—微波晶化法合成粉煤灰沸石及其对Cd2+的吸附

以粉煤灰为主要原料,采用碱熔融—微波晶化法合成粉煤灰沸石。采用XRD,SEM,TEM等技术表征了粉煤灰沸石的微观结构,并对其吸附Cd²⁺的性能进行了研究。表征结果显示,粉煤灰沸石主要由X型沸石、P型沸石和铝组成,粉煤灰沸石中有排列规则、呈蜂窝状的孔穴和孔道存在,其孔穴和孔道大小分布均匀,致密。粉煤灰沸石的比表面积为108.49 m²/g,平均孔径为3.779 nm,孔体积为0.221 mL/g。实验结果表明,在溶液pH为7、吸附时间30 min的最佳吸附条件下,Cd²⁺去除率均大于94%。粉煤灰沸石对Cd²⁺的吸附可很好地用二级动力学方程进行拟合,相关系数为0.999 99。可用Langmuir等温吸附模型描述该吸附过程,该吸附过程是单分子层吸附,主要是化学吸附,粉煤灰沸石对Cd²⁺的饱和吸附量为49.261 mg/g。     

微波消解-氢化物发生原子荧光光谱法测定生活污水中的微量砷

采用硝酸-高氯酸微波消解水样,在盐酸介质中以硫脲-抗坏血酸处理样品,以硼氰化钾的氢氧化钠溶液为还原剂,氢化物发生原子荧光光谱法测定生活污水中的痕量砷.方法检出限＜0.02μg/L,精密度0.14%,加标回收率92%～108%,操作简单,结果准确,重现性好.     

两种电压模式下GIS内部异物动态特性研究

异物是引发GIS设备内部击穿故障最主要的原因之一,运行电压下GIS设备内部异物受电场力作用发生随机运动,现场检测难以确定内部异物的特征。本文针对GIS设备内部异物开展力学特性分析,建立126 kV GIS等效模型,并仿真比对交流电压及脉冲电压作用下GIS内部异物的动态轨迹。研究结果表明交流电压下GIS设备内部异物颗粒的跳动轨迹呈现无规律特征,施加特定脉冲电压条件作用时,GIS内部异物跳动规律可控,其跳动高度及时间间隔基本一致。     

柴油低温临界吸收法回收装车挥发油气

研究了采用柴油低温临界吸收法回收装车挥发油气的效果。实验结果表明：按装车挥发油气中的总烃体积分数为20.88%、装车挥发油气流量为280 m³/h、年运行时间为2 668 h计,装置年回收油气量为291 t,装置年最大运行功率为206.770 MW,装置投资回收期为3 a;处理后净化气中的总烃体积分数为1.24%,排放质量浓度低于25 g/m³,油气回收率达95%。处理后净化气满足GB 20950—2007《储油库大气污染物排放标准》,取得了较好的环保效益和经济效益。     

Authentication of emission monitoring data and optimization of desulfurization in the molybdenum roasting process based on BAT-OOPN and the response surface method

Environmental Science and Pollution Research - This paper presents a quantitative pollutant discharge model for a typical molybdenum roasting plant, which combines the best available technology and...     

Contextual and organizational factors in sustainable supply chain decision making: grey relational analysis and interpretative structural modeling

Environment, Development and Sustainability - Sustainable supply chain emerges as a major business trend essential to long-term competitive advantage. Relevant corporate decisions concern a broad...     

Thermal conversion of rice husks and sawdust to liquid fuel

The paper focuses on studying the conversion of rice husks and sawdust into liquid fuel. Rice husks, sawdust and their mixture are pyrolyzed at temperatures between 420 and 540 degrees C, and the main product of liquid fuel is obtained. The experimental result shows that the yield of liquid fuel depends on various factors such as feedstock and temperature. The maximum yields for rice husks, sawdust and their mixture are 56%, 61% and 60% at 465, 490 and 475 degrees C, respectively. Analyses with GC-MS and other apparatus show that the liquid fuel is a complicated compound with low caloric value and can be directly used as a fuel oil for combustion in a boiler or a furnace without any upgrading. Alternatively, the fuel can be refined to be used by vehicles.     

CO2资源化利用的现状及前景

介绍了CO2分离捕集最新工艺——电化学法、膜法、化学循环燃烧法的研究进展。评述分析了CO2的各种资源化应用前景：CO2气体用作生物碳源、辅助注射成型剂及有机物（如氨基甲酸酯、表面活性剂）合成原料等;液态CO2用于人造金刚石、热泵干燥、超临界CO2萃取及固体干冰冷喷射清洗等。CO2作为一种潜在的丰富碳源,应不断研发其新的应用领域,加快其工业化应用。     

Enhanced arsenate removal from aqueous solution by Mn-doped MgAl-layered double hydroxides

Environmental Science and Pollution Research - In this study, Mn-doped MgAl-layered double hydroxides (LDHs) were successfully synthesized for efficient removal arsenate from aqueous solution. The...     

江西农田鼠害及其防治措施

农田鼠害是江西农业生物灾害中的主要灾种之一,它具有发生面积之、造成损失重、灾情越来越严重的特点,本文在回顾了江西农田鼠发生概况的基础上,简述了农田害鼠的种类、分布、主要特征及其发生发展规律,并从自然因素和人为因素等方面分析了鼠害成灾的主要原因,最后,提出了农田鼠害的防治措施。