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651.
Aluminum formate (AF), a degradable and non-corrosive coagulant, was synthesized from aluminum hydroxide and formic acid. Polyamidine (PA), as a coagulation aid, was combined with AF for dye wastewater treatment. AF was characterized by XPS, FT-IR, viscosity, zeta potential, mass spectrum and XRD, and the flocculation properties of the dual-coagulation system were characterized by FT-IR and SEM. The results showed that COOH, Al2O3-Al and O2-Al bonds were formed in the AF synthesis process, and AF had a higher molecular weight and higher charge neutralization ability than PAC. The hydrolysates of AF were determined to contain Al13 Al11 and Al2, and the components of AF were confirmed to comprise a mixture including aluminum formate (C3H3AlO6) and its hydrate. When the color removal efficiency reached 100% in jar tests, the optimized dosage of AF/PA was 18.91/0.71 mg/L, while the optimized dosage of PAC/PA was 21.19/0.91 mg/L. According to the variance analysis, the interaction between AF/PA and PAC/PA were insignificant in macroscopic view. FT-IR spectrum indicated AF captured pollutant by means of CCO bond, PAC captured pollutant by δ CH, CC and δ CH. Overall, although the coagulation mechanism of AF was different from that of PAC, AF/PA showed better coagulation efficiency than PAC/PA in dye wastewater treatment. 相似文献
652.
甜菜制糖工业废水由于其流量大、有机物浓度高、且季节性生产的特点,使得污水处理工艺难以按照常规方式进行。本研究选择适合北方地区特点、运行费用低、再启动快捷的水解-好氧-化学氧化-混凝沉淀的处理工艺,将生化与物化方法相结合,最后达到理想的效果,也为同类型工业污水的处理提供参考经验。 相似文献
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655.
复合混凝剂用于夏季太湖水混凝脱浊研究 总被引:3,自引:0,他引:3
用特征粘度系列化的聚二甲基二烯丙基氯化铵(PDM)与聚合氯化铝(PAC)复合得到稳定的复合混凝剂,用于夏季高藻太湖水强化混凝脱浊处理.通过混凝烧杯实验.考察了无机/有机复合比例、PDM特征粘度对脱浊效果及絮团沉淀性能的影响.结果表明,对浊度为30-33 NTU,温度为28~30℃,藻含量为2.6×107个儿的太湖水,在与某市水厂混凝强度相近的搅拌强度下.当达到该水厂2NTU沉淀池出水的余浊标准时,PAC需7.00 mg/L的投加量.质量复合比例为5:1、10:1、20:1的PAC(以Al2O3计)/PDM复合混凝剂所需PAC投加量随PDM特征粘度0.52、1.53、2.46 dL/g的增加分别为3.00-2.83 ms/L、3.50-3.49ms/L、5.37-4.67 mg/L,相对于PAC减少投加量57.14%-59.57%、50%-50.14%、23.29%-33.29%;作为深度处理的技术准备.当沉淀出水浊度要求提高至1NTU的情况下,复合药剂依然可发挥好的作用,PAC需10 mg/L的投加量,PAC(以Al2O3计)与PDM质量复合配比为20:1、10:1、5:1的复合混凝剂需8.33-3.91 mg/L的投加量,能比PAC减少投加量16.7%~60.9%.可见,PDM明显提高了PAC的混凝脱浊效果与沉淀性能,且PAC/PDM质量复合配比越低,PDM特征粘度越高,脱浊效果与沉淀性能越好. 相似文献
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658.
地方政府要做好自然灾害应对工作必须统筹兼顾两个方面的工作:一是在自然灾害应对的法规、组织等层面上切实发挥政府的主导作用;二是充分发挥多元主体参与的作用,集聚社会力量共同参与自然灾害应对。努力形成组织规范、运转协调的政府主导下的多元主体参与的自然灾害应对模式,切实提高地方政府自然灾害应急管理的能力和水平。 相似文献
659.
Fangfang Sun Dazhi Wen Yuanwen Kuang Jiong Li Jianli Li Weidong Zuo 《环境科学学报(英文版)》2010,22(7):1006-1013
Emissions from industrial activities pose a serious threat to human health and impose the need for monitoring both inorganic and
organic pollutants in industrial areas.We selected Masson pine (Pinus massoniana L.) as potential biomonitor and collected the current
(C) and previous year (C+1) needles from three industrial sites dominated by petrochemical, ceramics manufacturing, and iron and steel
smelting plants and one remote site to determine heavy metals (Cu, Cd, Pb, Zn, Cr, Ni and Co) and polycyclic aromatic hydrocarbons
(PAHs) in unwashed and water-washed needles. Both unwashed and washed C+1 needles showed generally higher concentrations of
heavy metals and PAHs than C needles, although the washed needles more clearly spotlighted the accumulation e ect of PAHs over
exposure time. Water-washing resulted in a significant decrease in needle PAH concentrations with more significant e ects shown in
C needles. By contrast, needle heavy metal concentrations were much less a ected by washing. Although heavy metals and PAHs
might di er in adsorption and uptake strategies, their higher concentrations in the needles at the industrial sites indicated conspicuous
contamination due to industrial emissions there. The PAH distribution patterns in pine needles accorded with the real types of energy
consumption in the study sites and were e ciently used for pinpointing local pollutant sources. 相似文献
660.
Carbonaceous particles in the atmosphere and precipitation of the
Nam Co region, central Tibet 总被引:4,自引:1,他引:3
A continuous air and precipitation sampling for carbonaceous particles was conducted in a field observatory beside Nam Co, Central Tibetan Plateau during July of 2006 through January of 2007. Organic carbon (OC) was the dominant composition of the carbonaceous particles both in the atmosphere (1660 ng/m3) and precipitation (476 ng/g) in this area, while the average elemental carbon (BC) concentrations in the atmosphere and precipitation were only 82 ng/m3 and 8 ng/g, respectively. Very high OC/BC ratio suggested local secondary organic carbon could be a dominant contribution to OC over the Nam Co region, while BC could be mainly originated from Southern Asia, as indicated by trajectory analysis and aerosol optical depth. Comparison between the BC concentrations measured in Lhasa, those at “Nepal Climate Observatory at Pyramid (NCO-P)” site on the southern slope of the Himalayas, and Nam Co suggested BC in the Nam Co region reflected a background with weak anthropogenic disturbances and the emissions from Lhasa might have little impact on the atmospheric environment here, while the pollutants from the Indo-Gangetic Basin of Southern Asia could be transported to the Nam Co region by both the summer monsoon and the westerly. 相似文献