阳离子絮凝剂P(AM-DMC)的合成及其对活性染料废水的絮凝脱色

以K2S2O8-脲为引发剂,通过自由基聚合法合成了丙烯酰胺-2-甲基丙烯酰氧乙基三甲基氯化铵P（AM—DMC）絮凝剂,并研究了其对4种活性染料模拟废水的脱色效果,考察了P（AM—DMC）加入量、阳离子度、特性粘数、染料溶液pH等因素对脱色效果的影响。实验结果表明：最佳P（AM—DMC）加入量随染料分子中磺酸基数目的增加而增加,随絮凝剂阳离子度的增大而减少;阳离子度大于52％时,最高脱色率基本相同;特性粘数对脱色效果影响很小;在染料溶液为弱酸性及中性条件下,P（AM—DMC）的脱色效果较好。P（AM—DMC）对活性染料废水的脱色机理是,P（AM—DMC）中的-N^＋（CH3）3与染料分子中的-SO3^-结合,生成-N^＋（CH3）3SO3^-,同时也形成了分子间氢键,通过键合作用使染料分子聚集沉降。     

定电位电解二氧化硫传感器特性研究

选用了3SF定电位电解型传感器作为二氧化硫连续在线监测探头。通过对该传感器各项特性指标的研究表明：该传感器在0～2500mg／m^3测量范围内,输出信号线性相关系数为0．9989,零点漂移为0．64％F．S．,相对准确度最大偏差为28mg／m^3,响应时间为30s,以上特性符合国家HJ／T76—2001标准中对二氧化硫传感器的各项指标要求,试验研究表明该传感器可用于二氧化硫连续在线监测。     

矿井通风系统风流控制的改进算法

介绍了矿井通风系统风流控制的基本数学模型和计算方法,指出了常规计算方法的不足,提出了一种能够避免大量矩阵运算、适用于实际通风网络的新算法,程序简单,计算时间省,并结合实例阐述了算法原理。     

安全管理体系的计算机辅助审核技术研究

关于海运公司安全管理体系 (SMS)的现行审核方法 ,难以保证其文件全面符合国际和国内的强制性规定 ,制约了《国际安全管理 (ISM)规则》效能的发挥。为此 ,课题组基于网络环境开发了对 SMS文件的计算机辅助审核技术 ,其主要成果包括 :建立了法规条款与 SMS文件的映射规则 ,使两者迅速匹配 ,以供审核 ;提出了 SMS文件符合法规程度的数学评价方法 ;设计了计算机辅助审核方案。经试审核 ,表明该技术能协助审核员迅速全面地发现 SMS文件对法规的不符合项 ,给出的符合程度定量合理 ,该技术有利于全面提高 SMS文件对法规条款的符合程度 ,从而方便了公司的全面履约。该技术还可用于类似的管理体系。     

掘进工作面贴附射流通风浓差理论研究

掘进工作面压入式通风形成的风流是贴附射流。根据流体力学和射流理论 ,通风射流体结构分为起始段和主体段。风筒出口风流是新鲜的 ,射流周围气体中污染物浓度高于射流体的浓度 ,与射流气体存在浓度差。因此 ,其通风射流为浓差射流。笔者分析了贴附射流主体段、起始段的轴心浓差和质量平均浓差 ,得出了计算模型。同时为研究压入式通风过程中污染物的分布提供了新的理论依据     

电催化氧化中的三种催化材料处理酸性红B染料的比较研究

本文采用三种不同催化机理的材料———半导体材料TiO2 、软锰矿石和混合稀土进行了电催化氧化 (ECO)染料酸性红B的研究 ,结果表明 ,稀土材料在ECO体系中呈负催化效应 ;软锰矿石的色度去除催化效果明显 ;TiO2 的催化效果最显著 ,其色度和COD去除效果可比无催化剂时效果分别提高60 %和 75% ,可以作为电催化氧化的催化剂。并进一步研究了TiO2 用量对电催化氧化 (ECO)的影响。     

Zebrafish (Danio rerio) as an excellent vertebrate model for the development,reproductive, cardiovascular,and neural and ocular development toxicity study of hazardous chemicals

Environmental Science and Pollution Research - In the past decades, the type of chemicals has gradually increased all over the world, and many of these chemicals may have a potentially toxic effect...     

Controlled-release of fluazinam from biodegradable PLGA-based microspheres

Abstract

Pesticides are biological or chemical substances used to manage pests and diseases. Encapsulation of pesticides in biodegradable carriers creates a slow-release system that can improve water dispersibility and prolong residual activity. We prepared two kinds of poly (lactic-co-glycolic acid)(PLGA) nanoparticles (NPs) with polyvinyl alcohol (PVA) and sodium dodecyl sulfate (SDS) surfactants. These were used to encapsulate the fungicide fluazinam (Flu) against Rhizoctonia solani using the Shirasu Porous Glass (SPG) membrane emulsification method. Both nanoparticles had uniform spherical shapes with average diameters of 314.13?nm (SDS) and 612.80?nm (PVA). The slow-release microspheres had excellent sustained-release properties, resistance to UV degradation, storage stability, leaf surface coverage and antifungal efficacy compared to the commercial formulation.     

Enhanced 4-chlorophenol biodegradation by integrating Fe2O3 nanoparticles into an anaerobic reactor: Long-term performance and underlying mechanism

• 4-chlorophenol biodegradation could be enhanced in Fe₂O₃ coupled anaerobic system. • Metabolic activity and electron transport could be improved by Fe₂O₃ nanoparticles. • Functional microbial communities could be enriched in coupled anaerobic system. • Possible synergistic mechanism involved in enhanced dechlorination was proposed. Fe₂O₃ nanoparticles have been reported to enhance the dechlorination performance of anaerobic systems, but the underlying mechanism has not been clarified. This study evaluated the technical feasibility, system stability, microbial biodiversity and the underlying mechanism involved in a Fe₂O₃ nanoparticle-coupled anaerobic system treating 4-chlorophenol (4-CP) wastewater. The results demonstrated that the 4-CP and total organic carbon (TOC) removal efficiencies in the Fe₂O₃-coupled up-flow anaerobic sludge blanket (UASB) were always higher than 97% and 90% during long-term operation, verifying the long-term stability of the Fe₂O₃-coupled UASB. The 4-CP and TOC removal efficiencies in the coupled UASB increased by 42.9±0.4% and 27.5±0.7% compared to the control UASB system. Adding Fe₂O₃ nanoparticles promoted the enrichment of species involved in dechlorination, fermentation, electron transfer and acetoclastic methanogenesis, and significantly enhanced the extracellular electron transfer ability, electron transport activity and conductivity of anaerobic sludge, leading to enhanced 4-CP biodegradation performance. A possible synergistic mechanism involved in enhanced anaerobic 4-CP biodegradation by Fe₂O₃ nanoparticles was proposed.     

The main anammox-based processes,the involved microbes and the novel process concept from the application perspective

• The PNA, denitratation/anammox, and DAMO/anammox process are reviewed together. • Denitratation/anammox-based process is promising in mainstream treatment. • DAMO and denitratation processes realize the higher nitrogen removal efficiency. • The utilization of metabolism diversity of functional microbe is worth exploring. • An effective waste treatment system concept is proposed. Anammox technology has been widely researched over the past 40-year from the laboratory-scale to full-scale. It is well-known that in actual applications, the solo application of anammox is not feasible. Since both ammonium and nitrite are prerequisites based on the reaction mechanism, the pre-treatment of wastewater is necessary. With the combination of anammox process and other pre-treatment processes to treat the actual wastewater, many types of anammox-based processes have been developed with distinct nitrogen removal performance. Thus, in order to heighten the awareness of researchers to the developments and accelerate the application of these processes to the treatment of actual wastewater, the main anammox-based processes are reviewed in this paper. It includes the partial nitritation/anammox process, the denitratation/anammox (PD/A) process, the denitrifying anaerobic methane oxidation/anammox (DAMO/A) process, and more complex deuterogenic processes. These processes have made the breakthroughs in the application of the anammox technology, such as the combination of nitrification and PD/A process can achieve stability and reliability of nitrogen removal in the treatment of mainstream wastewater, the PD/A process and the DAMO/A have brought about further improvements in the total nitrogen removal efficiency of wastewater. The diversity of functional microbe characteristics under the specific condition indicate the wide application potential of anammox-based processes, and further exploration is necessary. A whole waste treatment system concept is proposed through the effective allocation of above mentioned processes, with the maximum recovery of energy and resources, and minimal environmental impact.