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261.
Sharma KK Dubey JK Deka SC Chandrasekaran S Kalpana Gupta P Kumar A Vandana Devi MJ Singh B Baruah AA Kennedy JS Sharma ID Patyal SK Nath A 《Chemosphere》2007,68(4):790-796
Spiromesifen (Oberon) is a new insecticide and miticide of chemical class ketoenol active against white flies (Bemisia spp., Trialeuroides spp.) and spider mites (Tetranychus and Panonychus spp.). Due to its potential significance in insect resistance management, it is important to establish its behaviour on crop and environment. In the present study, the degradation/dissipation of spiromesifen on tea crop under tropical environmental conditions was studied and its DT(50) (t(1/2)), and DT(90) (time to reduce to 90% of the initial value) were estimated. Spiromesifen was sprayed on tea crop after first rain flush at four different locations @ 96 and 192ga.i.ha(-1). Samples of tea leaves were drawn at 0, 1, 3, 5, 7, 10, 15, 21 and 30 days after treatment and that of soil at 10 days after treatment and at harvest from 0 to 15 and 15 to 30cm layers. After crude extraction of tea leaves for spiromesifen residues with acetone:water, the contents were partitioned with cyclohexane:ethyl acetate and cleaned up on Florosil column. Soil residues were also extracted similarly. Quantification of residues was done on GC-MS in Selected Ion Monitoring (SIM) mode in mass range 271-274m/z. The LOQ of this method was found to be 0.05microgg(-1) while LOD being 0.015microgg(-1). The DT(50) of spiromesifen when applied at recommended doses in tea leaves was found to be 5.0-8.5 days. Ninety-nine percent degradation was found to occur within 33-57 days after application. In soil, no residues of spiromesifen were detectable 10 days after treatment. 相似文献
262.
A well known river hydrodynamic model RiverCAD has been used to simulate and visualize flood scenarios for different designated
flood flows under complex riverbed geometry with several man made structures like bridges and barrages. The model applied
successfully for the stretch of 23 km in the Yamuna floodplain of Delhi region from Wazirabad barrage in the upstream to Okhla
barrage. Flood flows for various return periods namely once in 10, 25, 50 and 100 years were estimated based on recorded flow
data for the period of 1963 to 2003 using standard flood frequency analysis techniques. The simulation results were compared
and the model was calibrated with water surface elevation records of the previous floods at various barrage and bridge locations.
Simulation results enabled prediction of maximum water levels, submergence scenarios and land availability under different
designated flood flows for riverbed assessment, development and management. 相似文献
263.
Singh G Gupta SK Kumar R Sunderarajan M 《Environmental monitoring and assessment》2007,130(1-3):173-185
The present study describes the development of empirical models for the prediction of various trace metals i.e., Mn, Cu, Fe,
Zn and Pb found in the leachates generated from the ash ponds of various thermal power plants. The dispersion phenomenon of
these trace metals followed first order reaction rate kinetics. The empirical models for individual trace metals derived from
the lab scale models data correlate well with the real field data with regression coefficients varying from 0.93 to 0.98.
The predicted concentrations of the trace metals varied within ±3% of the observed values in the leachates generated from
the ash ponds of four thermal power plants with standard deviation varying from 0.001 to 0.032. The empirical models derived
from the study can be applied for prediction of trace metals in leachates generated from similar thermal power plants. 相似文献
264.
Sharma KK Rao CS Dubey JK Patyal SK Parihar NS Battu RS Sharma V Gupta P Kumar A Kalpana Jaya M Singh B Sharma ID Nath A Gour TB 《Environmental monitoring and assessment》2007,132(1-3):25-31
In a field study carried out at three different locations, the dissipation of spiromesifen on cotton and chili was studied
and its DT50, and DT99 were estimated at each location. Spiromesifen was sprayed on chili at 96 and 192 g a.i. ha−1 and cotton at 120 and 240 g a.i. ha−1. Samples of chili fruits were drawn at 0, 1, 3, 5, 7, 10, 15, 21, 30 days after treatment and that of cotton seed and lint
at first picking and harvest. Soil samples were drawn 30 days after treatment from 0 to 15 and 15 to 30 cm layer. Quantification
of residues was done on GC–MS in Selected Ion Monitoring (SIM) mode in mass range 271–274 m/z. The LOQ of this method was
found 0.033 μg g−1, LOD being 0.01 μg g−1. The DT50 of spiromesifen when applied at recommended doses in chili fruits was found to be 2.18–2.40 days. Ninety-nine percent degradation
was found to occur within 14.5–16.3 days after application. Residues of spiromesifen were not detected in cotton seed and
lint samples at the first picking. In soil, no residues of spiromesifen were detectable 15 days after treatment. 相似文献
265.
This study assesses the efficiency of various physico-chemical, biological and other tertiary methods for treating leachate.
An evaluation study on the treatability of the leachate from methane phase bed (MPB) reactor indicated that at an optimum
hydraulic retention time of 6 days, the efficiency of the reactor in terms of biological oxygen demand (BOD) and chemical
oxygen demand (COD) removal was 91.29 and 82.69%, respectively. Recycling of the treated leachate through the municipal solid
waste layers in the leachate recycling unit (LRU) resulted in a significant increase in the biodegradation of organics present
in the leachate. Optimum BOD and COD removal efficiencies were achieved at the third recycle; additional recycling of the
leachate did not produce any significant improvement. Physico-chemical treatment of the leachate demonstrated that alum and
lime (Option 2) were more economical than coagulants lime and MgCO3. A cost analysis of the economics of the various treatments revealed that the alternative treatment consisting of a MPB bed
followed by a LRU and aerated lagoon is the most cost-effective treatment. However, the alternative consisting of a MPB followed
by the LRU and a soil column, which is slightly more costly, would be the most appropriate treatment when adequate land is
readily available. 相似文献
266.
There is a paradigm shift from non renewal resources to renewable resources in view of problems of disposal of plastic products
after their life cycle. This paper deals with the approach, preparation and product properties of polymer prepared by using
polysaccharide based biodegradable polymer. Basic material has been prepared by mixing LDPE, LDPE-g-mA (LDPE grafted with
(0.5%) maleic anhydride (1:1)) containing a polar group in the LDPE backbone. Prepared basic material has been compounded
in twin screw extruder with 0, 2.5, 5.0, 7.5, 10.0, 12.5 & 15% of Potato Starch. Thereafter, after conditioning blown film
samples were prepared using extrusion film blowing technique, under temperature profile ranging from 120 to 160 °C. Packaging
films have been prepared with maximum 15% potato starch contents and have been characterized by FTIR, DSC, TGA, and XRD techniques
to ascertain its impact on some structural and thermal properties like thermal stability, flexibility, crystallinity, crystal
size etc. 相似文献
267.
Municipal solid waste generation rate is over-riding the population growth rate in all mega-cities in India. Greenhouse gas emission inventory from landfills of Chennai has been generated by measuring the site specific emission factors in conjunction with relevant activity data as well as using the IPCC methodologies for CH4 inventory preparation. In Chennai, emission flux ranged from 1.0 to 23.5mg CH4m(-2)h(-1), 6 to 460microg N2Om(-2)h(-1) and 39 to 906mg CO2m(2)h(-1) at Kodungaiyur and 0.9 to 433mg CH4m(-2)h(-1), 2.7 to 1200microg N2Om(-2)h(-1) and 12.3 to 964.4mg CO2m(-2)h(-1) at Perungudi. CH4 emission estimates were found to be about 0.12Gg in Chennai from municipal solid waste management for the year 2000 which is lower than the value computed using IPCC, 1996 [IPCC, 1996. Report of the 12th session of the intergovernmental panel of climate change, Mexico City, 1996] methodologies. 相似文献
268.
Sulfamethazine uptake by plants from manure-amended soil 总被引:12,自引:0,他引:12
Animal manure is applied to agricultural land as a means to provide crop nutrients. However, animal manure often contains antibiotics as a result of extensive therapeutic and subtherapeutic use in livestock production. The objective of this study was to evaluate plant uptake of a sulfonamide-class antibiotic, sulfamethazine, in corn (Zea mays L.), lettuce (Lactuca sativa L.), and potato (Solanum tuberosum L.) grown in a manure-amended soil. The treatments were 0, 50, and 100 microg sulfamethazine mL(-1) manure applied at a rate of 56 000 L ha(-1). Results from the 45-d greenhouse experiment showed that sulfamethazine was taken up by all three crops, with concentrations in plant tissue ranging from 0.1 to 1.2 mg kg(-1) dry weight. Sulfamethazine concentrations in plant tissue increased with corresponding increase of sulfamethazine in manure. Highest plant tissue concentrations were found in corn and lettuce, followed by potato. Total accumulation of sulfamethazine in plant tissue after 45 d of growth was less than 0.1% of the amount applied to soil in manure. These results raise potential human health concerns of consuming low levels of antibiotics from produce grown on manure-amended soils. 相似文献
269.
Gupta PK Gupta V Sharma C Das SN Purkait N Adhya TK Pathak H Ramesh R Baruah KK Venkatratnam L Singh G Iyer CS 《Chemosphere》2009,74(4):590-598
A state-wise assessment of methane (CH(4)) budget for Indian paddies, based on a decadal measurement data across India is presented for the calendar year (CY) 1994, the base year for India's Initial National Communication (NATCOM) to the United Nations Framework Convention on Climate Change (UNFCCC), along with national trend from CY 1979 to 2006. The NATCOM CH(4) emission factors (EFs) for Indian paddy cultivation areas, generally having less than 0.7% of soil organic carbon (SOC), have been estimated as 17.48+/-4 g m(-2) for irrigated continuously flooded (IR-CF), 6.95+/-1.86 g m(-2) for rain-fed drought prone (RF-DP), 19+/-6 g m(-2) for rain-fed flood prone (RF-FP) and deep-water (DW), 6.62+/-1.89 g m(-2) for irrigated intermittently flooded single aeration (IR-IF-SA) and 2.01+/-1.49 g m(-2) for IR-IF multiple aeration (MA) paddy water regimes. The state-wise study for 1994 has indicated national CH(4) budget estimate of 4.09+/-1.19 Tg y(-1) and the trend from 1979 to 2006 was in the range of 3.62+/-1 to 4.09+/-1.19 Tg y(-1). Four higher emitting or "hot spot" states (West Bengal, Bihar, Madhya Pradesh and Uttar Pradesh) have accounted for 53.9% of total CH(4) emission with RF-FP paddy water regime as the major contributor. CH(4) emissions were enhanced by factors such as SOC ( approximately 1.5 times due to increase in SOC by approximately 1.8 times), paddy cultivars (approximately 1.5 times), age of seedlings (approximately 1.4 times), and seasons (approximately 1.8 times in Kharif or monsoon than in Rabi or winter season). 相似文献
270.
The effect of local-scale physical heterogeneity and nonlinear,rate-limited sorption/desorption on contaminant transport in porous media 总被引:1,自引:0,他引:1
Nonideal transport of contaminants in porous media has often been observed in laboratory characterization studies. It has long been recognized that multiple processes associated with both physical and chemical factors can contribute to this nonideal transport behavior. To fully understand system behavior, it is important to determine the relative contributions of these multiple factors when conducting contaminant transport and fate studies. In this study, the relative contribution of physical-heterogeneity-related processes versus those of nonlinear, rate-limited sorption/desorption to the observed nonideal transport of trichloroethene in an undisturbed aquifer core was determined through a series of miscible-displacement experiments. The results of experiments conducted using the undisturbed core, collected from a Superfund site in Tucson, AZ, were compared to those obtained from experiments conducted using the same aquifer material packed homogeneously. The results indicate that both physical and chemical factors, specifically preferential flow and associated rate-limited diffusive mass-transfer and rate-limited sorption/desorption, respectively, contributed to the nonideal behavior observed for trichloroethene transport in the undisturbed core. A successful prediction of trichloroethene transport in the undisturbed core was made employing a mathematical model incorporating multiple sources of nonideal transport, using independently determined model parameters to account for the multiple factors contributing to the nonideal transport behavior. The simulation results indicate that local-scale physical heterogeneity controlled the nonideal transport behavior of trichloroethene in the undisturbed core, and that nonlinear, rate-limited sorption/desorption were of secondary importance. 相似文献