Nitrate leaching and nitrogen recovery following application of polyolefin-coated urea to potato

High N fertilizer and irrigation amounts applied to potato (Solanum tuberosum L.) on coarse-textured soils often result in nitrate (NO3) leaching and low recovery of applied fertilizer N. This 3-yr study compared the effects of two rates (140 and 280 kg N ha(-1)) of a single polyolefin-coated urea (PCU) application versus split applications of urea on 'Russet Burbank' potato yield and on NO3 leaching and N recovery efficiency (RE) on a loamy sand. Standard irrigation was applied in all years and excessive irrigation was used in another experiment in the third year. At the recommended rate of 280 kg N ha(-1), NO3 leaching during the growing season was 34 to 49% lower with PCU than three applications of urea. Under standard irrigation in the third year, leaching from five applications of urea (280 kg N ha(-1)) was 38% higher than PCU. Under leaching conditions in the first year (> or = 25 mm drainage water in at least one 24-h period) and excessive irrigation in the third year, PCU at 280 kg N ha(-1) improved total and marketable tuber yields by 12 to 19% compared with three applications of urea. Fertilizer N RE estimated by the difference and 15N isotope methods at the 280 kg N ha(-1) rate was, on average, higher with PCU (mean 50%) than urea (mean 43%). Fertilizer N RE values estimated by the isotope method (mean 51%) were greater than those estimated by the difference method (mean 47%). Results from this study indicate that PCU can reduce leaching and improve N recovery and tuber yield during seasons with high leaching.     

A new method for spectrophotometric determination of benzene in air

A new spectrophotometric method for the determination of benzene in air is described. The method is based upon the nitration of benzene to m-dinitrobenzene and subsequent reduction to m-phenylenediamine. m-Phenylenediamine is determined by diazotization-coupling reaction. α-Naphthol is used as a coupling reagent. Beer's law is obeyed in the range of 10–80 μg of m-dinitribenzene per 25 mL sample. The dye shows a wavelength of maximum absorption at 530 nm. The dye is stable for ～ 30 h. Toluene, the major interferent, can be separated. Beer's law, sensitivity, reproducibility, and other reaction conditions such as time, temperature, and acidity were studied. Formation of stable dye is the main advantage of the method over the butanone method for benzene, in which the colored complex is stable for only 5 min. It is possible to determine traces of benzene (0.05–0.30 μg/mL) by extracting the azo dye in 10 mL iso-amyl alcohol; this also increases the stability of the dye up to 42 h.     

Abiotic Oxidation Studies of Oxo-biodegradable Polyethylene

The best approach to induce oxo-biodegradation in polyethylene is the use of special additives known as pro-oxidants. Pro-oxidants accelerate abiotic oxidation and subsequent polymer chain cleavage rendering the product apparently more susceptible to biodegradation. In this work, the abiotic oxidation is studied to understand how the addition of nanoclay affects the oxidation rate and the degradation mechanism of oxo-biodegradable polyethylene. In order to achieve this, the following materials were used in this study: (1) polyethylene (PE), (2) oxo-biodegradable polyethylene (OPE), (3) polyethylene nanocomposite (PENac), and (4) oxo-biodegradable polyethylene nanocomposite (OPENac). Wide-Angle X-ray scattering (WAXS) and Transmission Electron Microscopy (TEM) studies reveal that grafting in the preparation of composites helps to achieve mixed intercalated/exfoliated morphology in PENac and OPENac. Abiotic oxidation was carried out in an oven for a period of 14 days at 70 °C with air supply. The effect of abiotic oxidation was evaluated by measuring the changes in tensile strength, elongation at break, carbonyl index and molecular weight. Results show that OPE and OPENac are more susceptible to oxidation than PENac. The molecular weight distribution data obtained from GPC reveal that the addition of nanoclay does not alter the oxidation mechanism in OPE significantly.     

Spectrophotometric determination of nitrite with diphenylamine in potable and polluted water

This paper describes a new method for the determination of nitrite in potable and polluted water, based on the reaction of nitrite with p-nitroaniline to form diazonium salt and its subsequent coupling with diphenylamine in acidic medium. The pink coloured dye formed obeys Beer's law in the range 0.16 to 0.56 μg/ml at λ_max = 540 nm. The molar absorptivity and Sandell's sensitivity being 57.5 × 10³ lmole^?3cm^?1 and 0.0008 μg/cm², respectively. The optimum reaction conditions and other analytical parameters have been studied. Extraction of the dye with chloroform enhances the sensitivity considerably and makes 0.04 μg/ml of nitrite determinable.     

Performance of seed germination and growth of Vicia faba L. in fly ash amended soil

The performance of Vicia faba L. in soil amended by different concentrations of fly ash has been studied. The parameters considered are seed germination, growth behaviour and nodulation frequency of the plant. Results revealed that while fly-ash amendment to the soil improved the growth performance at initial stages with application of lower concentrations, it was inhibitory at higher exposure concentrations. Although there was no difference in survival rates, but the seedling growth was reduced in comparison to control plants. Fly ash delayed the nodulation as lesser number of nodules was recorded at higher amendments. Results suggested feasibility of growing V. faba in fly ash contaminated area.     

Water and solute movement in soil as influenced by macropore characteristics: 2. Macropore tortuosity

The paper describes the results of a laboratory study on the effects of macropore tortuosity on breakthrough curves BTCs and solute distribution in a Forman loam (fine loamy-mixed Udic Haploborolls) soil. BTC were obtained using 2-D columns (slab) containing artificial macropores of five different tortuosity levels. The BTCs were run under a constant hydraulic head of 0.08 m over an initially air dry soil. The input solutions contained 1190 mg l⁻¹ of potassium bromide, 10 mg l⁻¹ of Rhodamine WT, and 100 mg l⁻¹ of FD&C Blue #1. A soil column without macropores served as a control. The displacement of a non-adsorbed tracer was not affected by the tortuosity level. An increase in macropore tortuosity progressively increased the breakthrough time, increased the apparent retardation coefficient (R′), decreased the depth to the center of mass of a given adsorbed tracer, and increased the anisotropy in tracer distribution profile. The relative importance of macropore tortuosity increased with an increase in the adsorption coefficient of the tracer. Compared to macropore continuity, the macropore tortuosity had greater impact on solute distribution profile than in its leaching.     

RESERVOIR OPERATION ANI EVALUATION OF DOWNSTREAM FLOW AUGMENTATION1

ABSTRACT: Operation of a storage‐based reservoir modifies the downstream flow usually to a value higher than that of natural flow in dry season. This could be important for irrigation, water supply, or power production as it is like an additional downstream benefit without any additional investment. This study addresses the operation of two proposed reservoirs and the downstream flow augmentation at an irrigation project located at the outlet of the Gandaki River basin in Nepal. The optimal operating policies of the reservoirs were determined using a Stochastic Dynamic Programming (SDP) model considering the maximization of power production. The modified flows downstream of the reservoirs were simulated by a simulation model using the optimal operating policy (for power maximization) and a synthetic long‐term inflow series. Comparing the existing flow (flow in river without reservoir operation) and the modified flow (flow after reservoir operation) at the irrigation project, the additional amount of flow was calculated. The reliability analysis indicated that the supply of irrigation could be increased by 25 to 100 percent of the existing supply over the dry season (January to April) with a reliability of more than 80 percent.     

Bacterial tolerance strategies against lead toxicity and their relevance in bioremediation application

Among heavy metals, lead (Pb) is a non-essential metal having a higher toxicity and without any crucial known biological functions. Being widespread, non-biodegradable and persistent in every sphere of soil, air and water, Pb is responsible for severe health and environmental issues, which need appropriate remediation measures. However, microbes inhabiting Pb-contaminated area are found to have evolved distinctive mechanisms to successfully thrive in the Pb-contaminated environment without exhibiting any negative effects on their growth and metabolism. The defensive strategies used by bacteria to ameliorate the toxic effects of lead comprise biosorption, efflux, production of metal chelators like siderophores and metallothioneins and synthesis of exopolysaccharides, extracellular sequestration and intracellular bioaccumulation. Lead remediation technologies by employing microbes may appear as potential advantageous alternatives to the conventional physical and chemical means due to specificity, suitability for applying in situ condition and feasibility to upgrade by genetic engineering. Developing strategies by designing transgenic bacterial strain having specific metal binding properties and metal chelating proteins or higher metal adsorption ability and using bacterial activity such as incorporating plant growth-promoting rhizobacteria for improved Pb resistance, exopolysaccharide and siderophores and metallothionein-mediated immobilization may prove highly effective for formulating bioremediation vis-a-vis phytoremediation strategies.