This research examined the fate of polydimethylsilicones (PDMS) in agricultural test plots amended with municipal biosolids. This 4 yr field study involved addition of 0, 15, and 100 Mg ha(-1) of municipal biosolids, which contained ambient concentrations of PDMS (1272 mg kg(-1) biosolids), to corn and soybean test plots. Soil samples collected at intermittent time intervals were analyzed for soil water, soil organic C, extractable PDMS and PDMS hydrolysis products. Above normal precipitation during the field study maintained soil water levels in excess of 100 g kg(-1) for most of the testing period of 1994-1998. Under these conditions half-lives for PDMS (based on field dissipation data) ranged from 876 to 1443 d. When biosolids amended soil samples were brought into the laboratory and subjected to more rapid drying, >80% of the PDMS was transformed to lower molecular weight hydrolysis products within 20 d. No difference in relative PDMS transformation rates were evident for soils that received PDMS in the form of a biosolids amendment or directly dosed to the soil (in the absence of biosolids) indicating little if any effect of direct PDMS-biosolids interactions on PDMS transformation rates. These results support that the overriding factor controlling the fate of PDMS in field soils is the soil moisture content. 相似文献
Dilution has long been considered a solution to many problems of toxic/flammable material releases. It implies diluting to a concentration that is below physiologically dangerous levels for a toxic substance (generally below TLV), or to a level below LFL for a flammable material release, ensuring that the process adopted for dilution does not itself enhance the risks.
In this paper, we discuss the dilution of a gaseous release by deliberate and cautious mixing with air to reduce its concentration to a harmless level. The idea bears its origin to the Bhopal Gas Tragedy where some families saved themselves by turning the ceiling fans on when MIC reached their bedrooms at the dead of very cold night on December 2–3, 1984. The air pushed in by the fans diluted the MIC to below the harm level.
Some of the advantages of using air dilution are: no cost of air, no air storage needed, no need to treat the air after use as in case of water curtains; required equipment, its maintenance and staff training in its use are very likely to cost less than in other ways of handling a release.
Air dilution may not be feasible in all cases, such as gaseous release within a congested equipment layout, release that forms a liquid pool, etc. The method needs to be evaluated for each case. 相似文献
Land application of wastewater in the northern-tier United States during winter months has been suggested as a means to reduce cost of building storage lagoons. A study was initiated in 1996 to assess land application of potato-processing wastewater on a 120-ha field at Park Rapids, MN. One objective of this study was to evaluate the effects of soil P levels and temperature on P leaching in soil columns. In this paper, we report the P sorption, desorption, and leaching characteristics of a high-P (>200 mg kg(-1)) and a low-P (<25 mg kg(-1)) surface soil from the wastewater irrigation site. The leaching experiment was done with wastewater at 4 +/- 2 or 10 +/- 2 degrees C. The high-P soil resulted in an equilibrium P concentration of 8.0 mg L(-1) compared with 0.14 mg L(-1) for the low-P soil. When low-P wastewater was applied to the high-P soil, the soil acted as a P source, and the total phosphorus (TP) concentration in the leachate was 3.5 times higher than the input TP concentration (C0). When high-P wastewater was applied to the high-P soil, the soil acted as a P sink retarding the TP concentration in the leachate by 80%. Phosphorus desorption was higher at 10 degrees C compared with 4 degrees C. The results showed that depending on P levels of the soil and the wastewater, reduction or increase in leachate P will occur below the surface soil. However, further mobility of this P under field conditions will depend on the volume and rate of percolating water as well as the sorption-desorption characteristics of the subsoil. 相似文献
Excessive emissions of certain trace gases such as carbon dioxide, methane, nitrous oxide, carbon monoxide and chlorofluorocarbons are likely to result in global warming due to increased concentration of these greenhouse gases (GHGs). Therefore, measures to control GHG emissions are essential and the current international debate is on how to arrive at optimal GHG limitation strategies. To set emission targets or to distribute the burden of costs of various control measures, it is necessary to identify the major emitters. The World Resources Institute has assessed countrywide contributions to global GHG emissions for 1987. This paper disagrees with the basic approach adopted by WRI because it fails to apportion sinks on a logical basis by keeping in mind equity considerations; it does not account for the residence time of different GHGs; and it uses unreliable and outdated data for estimating the emissions. Using recent and reliable data for India and Brazil as well as the IPCC global warming potential for various GHGs, the shares in global emissions have been recalculated. The paper concludes that if only current emissions are considered there is considerable bias against those countries which are latecomers to the process of industrialization. 相似文献
Acrylonitrile–Butadiene–Styrene (ABS), Polycarbonate (PC) and their alloys are widely used in automotive industry, computer
and equipment housings. With increasing disposal of end-of-life electronic equipment, there is also an increased demand for
recycling of these materials so that they do not pose environmental challenge as solid waste. One of the recycling approaches
is mechanical recycling of these thermoplastics where recycled plastic is melt blended with virgin materials to obtain a high
quality product. Besides obtaining desirable mechanical properties, such blends should also conform to fire safety standards.
In this work, a series of blends were prepared using PC and ABS recovered from discarded computers and virgin materials using
a twin-screw extruder. Their flammability properties were evaluated using burner flammability tests and Ohio State University
(OSU) release rate tests. It was found that the extinguishing time, burning extent and weight loss appears to progressively
decrease with the addition of both virgin or recycled PC to virgin or recycled ABS. It was also seen that the addition of
the 70% of PC, virgin or recycled, to ABS virgin or recycled, appears to significantly decrease heat release and smoke evolution.
The results of this study indicate that recycled polycarbonate can be used as an additive for virgin or recycled ABS, as a
means of giving flame resistance to ABS in high-value applications. This result is significant when related to the result
obtained by a separate study indicating that up to 25% of recycled material can be used without degradation of mechanical
properties in the presence of 15% short glass fiber reinforcement. 相似文献
Plants have been used as good bio-indicators and genetic toxicity of environmental pollution in recent years. In this study, aquatic plants Hydrilla verticillata and Ceratophyllum demersum treated with 10 μmol/L Cd, 5 μmol/L Hg, and 20 μmol/L Cu for 96 h, showed changes in chlorophyll, protein content, and in DNA profiles. The changes in DNA profiles included variation in band intensity, presence or absence of certain bands and even appearance of new bands. Genomic template stability test performed for the ... 相似文献