Contamination of Surface Soils, River Water and Sediments by Trace Metals from Copper Processing Industry in the Churnet River Valley, Staffordshire, UK

The impacts of a functional and a demolished copper processing works on the aquatic and terrestrial environment in the vicinity of the works was investigated by determining the levels of selected trace metals in river water, river sediments, channel margin sediments and overbank soils. Samples were taken at five sites within an area of the Churnet Valley in Staffordshire, where the River Churnet flows through the two works. Analysis of river water samples by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) has shown that only copper is present above background levels considered to typify uncontaminated rivers. Analysis of river sediments, channel margin sediments and overbank soils by nitric-perchloric acid digestion and Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES) analysis has indicated contamination by arsenic, cadmium and copper in the vicinity of both works. Arsenic and copper are deposited primarily within the aquatic environment, although some contamination of the terrestrial environment by copper is also observed. Cadmium is deposited primarily within the terrestrial environment. The deposition of arsenic and copper in river and channel margin sediments respectively is also related to current and historical contamination.     

The relationship between epilithic periphyton (biofilm) bound metals and metals bound to sediments in freshwater systems

Surficial sediments and epilithic periphyton (biofilm) were sampled from six sites on the River Churnet and five sites on the River Manifold in Staffordshire and analysed for cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn). The sites demonstrated a wide range of sediment trace metal concentrations determined by inductively coupled plasma optical emission spectrometry (ICP-OES) and atomic absorbtion spectroscopy (AAS). Biofilm was removed from the substrate using physical abrasion and 0.005 M ethylenediaminoethanetetra-acetic acid (EDTA) extractant. The European Standards, Measurements and Testing Programmes (BCR) operationally defined geochemical speciation scheme was used to determine the exchangeable, acid soluble fraction of the sediments. Significant positive correlations were determined between the EDTA extractable biofilm and the exchangeable sediment fraction for Cd, Cu and Zn but not for Pb. Natural epilithic periphyton may be a potential metal biomonitor particularly of Cu, Cd and Zn in aquatic systems and provide supporting information in relation to potential sediment toxicity.     

A 2.5‐million‐year perspective on coarse‐filter strategies for conserving nature's stage

Climate change will require novel conservation strategies. One such tactic is a coarse‐filter approach that focuses on conserving nature's stage (CNS) rather than the actors (individual species). However, there is a temporal mismatch between the long‐term goals of conservation and the short‐term nature of most ecological studies, which leaves many assumptions untested. Paleoecology provides a valuable perspective on coarse‐filter strategies by marshaling the natural experiments of the past to contextualize extinction risk due to the emerging impacts of climate change and anthropogenic threats. We reviewed examples from the paleoecological record that highlight the strengths, opportunities, and caveats of a CNS approach. We focused on the near‐time geological past of the Quaternary, during which species were subjected to widespread changes in climate and concomitant changes in the physical environment in general. Species experienced a range of individualistic responses to these changes, including community turnover and novel associations, extinction and speciation, range shifts, changes in local richness and evenness, and both equilibrium and disequilibrium responses. Due to the dynamic nature of species responses to Quaternary climate change, a coarse‐filter strategy may be appropriate for many taxa because it can accommodate dynamic processes. However, conservationists should also consider that the persistence of landforms varies across space and time, which could have potential long‐term consequences for geodiversity and thus biodiversity.     

The role of academia in regional sustainability initiatives: Wales

This paper demonstrates the relative non-engagement of universities in regional sustainability initiatives through a case study of Cardiff University in Wales. It is argued that the turbulent and often complicated political and administrative context along with divergent goals and performance targets means that synergies are less readily achieved. A case study of automotive industry alternative technology new cluster development is given to illustrate the arguments. In so doing, the paper presents the view that we need to move beyond mere optimism in order to address fundamental underlying issues.     

Pharmacological evaluation of Thuja occidentalis for the attenuation of neuropathy via AGEs and TNF-α inhibition in diabetic neuropathic rats

Environmental Science and Pollution Research - When diabetes neuropathy occurs, the oxidative stress caused by chronic hyperglycemia may result in chronic neuronal damage. To mitigate the effects...     

Predictors of conviction and sentencing of DWI offenders in a New Mexico County

OBJECTIVE: To analyze predictors of conviction and dismissal of individuals charged with DWI, and predictors of the sentences of those who are convicted. METHODS: Data come from the Citation Tracking System of the State of New Mexico's Motor Vehicle Division and includes information on all individuals who were arrested for DWI in San Juan County between August 1994 and December 2000. Independent variables were: age, gender, race/ethnicity, waiver of right to an attorney, court of arraignment, year of arrest, BAC, and number of prior DWI arrests. Dependent variables were: (1) conviction or dismissal, (2) jail or no jail, (3) incarceration/treatment or not, (4) fine or no fine, (5) length of jail sentence, (6) waived right of attorney, and (7) magnitude of fine. Multiple linear and logistic regression was used in the analyses. RESULTS: Use of an attorney is associated with reduced likelihood of conviction and, if convicted, in reduced likelihood of jail sentence and reduced jail time, but greater likelihood and magnitude of a fine. Native Americans were more likely than Hispanics and non-Hispanic whites to waive their right to an attorney. Native Americans were most likely to be sentenced to the detention/treatment program. BAC and number of prior arrests were each positively associated with increased likelihood of conviction and more severe sentences. There is also substantial variability in severity of sentencing among courts. CONCLUSION: Likelihood of conviction and severity of sentences are both determined by extra-legal factors, resulting in inconsistent application of the law. This may in turn contribute to a lack of compliance with laws related to DWI.     

Analysis of the glyphosate herbicide in water,soil and food using derivatising agents

Glyphosate is used widely to control weeds. Glyphosate is a broad spectrum, non-selective, systemic and post-emergent herbicide. Glyphosate excessive use and impact on the environment is promoting the analysis of glyphosate in water, soil and food materials. Methods to analyse glyphosate at low levels are needed because glyphosate has a short half-life due to easy microbial degradation. Glyphosate has a high polarity and solubility in water, has high binding affinity with soil and is non-volatile. The absence of chromophoric groups in the molecular structure makes the detection difficult. Therefore, detection can be achieved by derivatisation, which makes glyphosate more volatile and stable for spectroscopic analysis. Derivatisation is commonly done by alkyl chloroformates, acylating agents, 9-fluoroenylmethylchloroformate, 4-methoxybenzenesulfonylfluoride and o-phthalaldehyde. Immunosensors allow detection at microlevels. Nanocrystals and nanotechnology allow detection at nanolevels. Here, we review methods to derivatise and analyse glyphosate.     

Correction to: Health risk assessment of hexachlorocyclohexane in soil,water and plants in the agricultural area of Potohar region,Punjab, Pakistan

Environmental Geochemistry and Health - A correction to this paper has been published: https://doi.org/10.1007/s10653-021-00910-5     

Soil Moisture Data Assimilation Using Support Vector Machines and Ensemble Kalman Filter1

Abstract: A hybrid data assimilation (DA) methodology that combines two state‐of‐the‐art techniques, support vector machines (SVMs) and ensemble Kalman filter (EnKF), is applied for soil moisture DA in this work. The SVM methodology provides a statistically sound and robust approach to solving the inverse problem, and thus to building statistical models. EnKF is an extension of the Kalman Filter (KF), a well‐known tool in prediction updating. In the present research, ground measurements were used to build a SVM‐type soil moisture predictor. Subsequent observations and their statistics were assimilated to update predictions from the SVM model by coupling it with EnKF. In this way, both model predictions and ground data, as well as their statistics, are fused thus minimizing the prediction error and making the predictions and observations statistically consistent. The results are shown for two approaches; one in which update is done at every time step and the other which assumes that data is only available at alternate time steps (in window of 10 time steps) and hence update is performed at those occasions. The SVM‐EnKF coupling is shown to improve soil moisture forecasts in an example using data from the Soil Climate Analysis Network site at Ames, Iowa.