Exposure Times to the Spring Atrazine Flush Along a Stream-Reservoir System1

Stoeckel, James A., Jade Morris, Elizabeth Ames, David C. Glover, Michael J. Vanni, William Renwick, and María J. González, 2012. Exposure Times to the Spring Atrazine Flush Along a Stream-Reservoir System. Journal of the American Water Resources Association (JAWRA) 48(3): 616-634. DOI: 10.1111/j.1752-1688.2011.00633.x Abstract: We used enzyme-linked immunosorbent assay to examine reservoir-mediated shifts in spring to fall exposure of aquatic organisms to the spring atrazine pulse over four years in a Midwestern stream-reservoir system. Peak atrazine concentrations in the major inflowing stream exceeded 10 μg/l in all four years. The reservoir had a beneficial effect in two of four years by diluting atrazine below the 10 μg/l threshold. However, during the other two years, exposure times above 10 μg/l were approximately doubled in the reservoir compared to the major inflowing stream. Thresholds of 3 and 5 μg/l were exceeded during all four years in the reservoir. The uplake and downlake reservoir sites were four to five times more likely to exceed these thresholds and aquatic organisms were subjected to longer exposure times above these thresholds compared to the inflowing stream. Release of elevated atrazine concentrations from the reservoir extended exposure times in the outflowing stream. This effect was most pronounced just below the dam. Aquatic organisms upstream of the reservoir were most likely to experience acute exposures whereas organisms within and immediately downstream of the reservoir were more likely to experience chronic exposures. The ubiquity of reservoirs and the annual spring herbicide flush highlight the importance of considering the presence and relative location of reservoirs when assessing risk to aquatic communities as well as locations of drinking water intakes.     

Effects of organic amendments on the reduction and phytoavailability of chromate in mineral soil

In this study, seven organic amendments (biosolid compost, farm yard manure, fish manure, horse manure, spent mushroom, pig manure, and poultry manure) were investigated for their effects on the reduction of hexavalent chromium [chromate, Cr(VI)] in a mineral soil (Manawatu sandy soil) low in organic matter content. Addition of organic amendments enhanced the rate of reduction of Cr(VI) to Cr(III) in the soil. At the same level of total organic carbon addition, there was a significant difference in the extent of Cr(VI) reduction among the soils treated with organic amendments. There was, however, a significant positive linear relationship between the extent of Cr(VI) reduction and the amount of dissolved organic carbon in the soil. The effect of biosolid compost on the uptake of Cr(VI) from the soil, treated with various levels of Cr(VI) (0-1200 mg Cr kg(-1) soil), was examined with mustard (Brassica juncea L.) plants. Increasing addition of Cr(VI) increased Cr concentration in plants, resulting in decreased plant growth (i.e., phytotoxicity). Addition of the biosolid compost was effective in reducing the phytotoxicity of Cr(VI). The redistribution of Cr(VI) in various soil components was evaluated by a sequential fractionation scheme. In the unamended soil, the concentration of Cr was higher in the organic-bound, oxide-bound, and residual fractions than in the soluble and exchangeable fractions. Addition of organic amendments also decreased the concentration of the soluble and exchangeable fractions but especially increased the organic-bound fraction in soil.     

1976 Illinois drought: Evidence for improved water quality

During 1976, Illinois experienced a mild drought, of i ntensity equivalent to the once in 5 years frequency. It was anticipated that the drought would result in deteriorated water quality because dilution of point source discharges would be diminished. Furthermore, because productivity in Illinois streams is light limited, reduced runoff should result in clearer streams, higher algae levels, and greater variability in dissolved oxygen levels. In spite of these expectations, both chemical and biologic data showed that water quality in 1976 was appreciably better than that before 1975. The information provided by the Illinois water quality index (Janardan and Schaeffer 1977) coincides with biologic analyses of benthic invertebrates. The index supports and supplements the biologic data and provides a means for quantifying and integrating chemical and biologic data.The results of this study showed that the drought had little, if any, effect on statewide water quality. Although the magnitude of the drought varied across the state, water quality remained unchanged between 1975 and 1976. This may have reflected the ability of unpolluted systems to adjust to natural variations or have been an indication that there were offsetting statewide gains in pollution control in 1976 or that uncharacterized, broad-based phenomena were operating in stream ecology, or that combinations of these were in effect.Based on presentations before the American Water Resources Assocition, Illinois Section, Chicago, Illinois, June 10–11, 1977.     

Effect of Agave attenuata extracts on detoxification enzymes of Biomphlaria alexandrina

The toxicity and rising costs of synthetic molluscicides have led to interest in compounds derived from locally growing plants that can be used as molluscicides. The aim of the present work was to study the effect of extracts of some Egyptian plants having lethal effect on snails of medical importance (Biomphlaria alexandrina) as well as on antioxidant and glutathione detoxification enzymes. Ethanolic extracts of locally growing plants Agave attenuata, Agave sislana, Phytolaca dodecandra and Euphorbia spllendens were applied as a contact poison to B. alexandrina, the intermediate host of Schistosoma mansoni. The LC₅₀ of A. attenuata, A. sislana, P. dodecandra and E. spllendens are 82, 101, 98 and 98 mg/L, respectively. Glutathione and the enzymes involved in protection of the snail from reactive oxygen species namely, glutathione peroxidase, glutathione reductase, glutathione S-transferase, catalase, gamma glutamyl transferase increased in the survival snails exposed to high concentrations of A. attenuata. Glucose-6-phosphate dehydrogenase indirectly affecting glutathione reductase and the oxidation, reduction of glutathione significantly decreased in snails exposed to A. attenuata extracts. Superoxide dismutase level tend to decrease in snails exposed to A. attenuata of action. In conclusion A. attenuata is preferable when compared with synthetic molluscicides. The enzymes involved directly or indirectly in protection mechanism of the snail against A. attenuata are mainly responsible for snails survival.     

Lay concepts on CCS deployment in Switzerland based on qualitative interviews

Laypeople's acceptance and perception of Carbon Dioxide Capture and Storage (CCS) can have an influence on its political feasibility. It is important, therefore, to study how laypeople perceive CCS and which cognitions they hold with respect to this technique. We conducted in-depth interviews with laypeople (N = 16) to explore their mental concepts of CCS. Little knowledge about CCS was detected among laypeople. We also found that laypeople fear that a deployment of CCS could create incentives that would hinder a sustainable development of the energy economy. A misunderstanding of the concepts of hydro- and geostatic pressure, as well as a lack of knowledge about the physical–chemical properties of carbon dioxide seemed to trigger fundamental rejection of CCS among some laypeople. This qualitative study identifies concepts that underlie CCS perception, and these should be objects of future studies. We provide some suggestions for risk management and communication about CCS.     

Biogeochemistry of fluoride in a plant-solution system

Fluoride (F-) pollutants can harm plants and the animals feeding on them. However, it is largely unknown how complexing and chelating agents affect F bioavailability. Two studies were conducted that measured F- bioavailability and uptake by rice (Oryza sativa L.). In the first study, rice was grown in solution culture (pH 5.0) with 0, 2, or 4 mM F- as KF to compare the interaction of F- with humic acid (HA) and with a conventional chelating agent, N-hydroxyethylenthylenediaminetriacetic acid (HEDTA). In the second study, F was supplied at 0, 0.5, 1.0, and 2.0 mM KF with an additional 2 mM F- treatment containing solution Ca at 2x (2 mM Ca) the level used in the first study, to test the effect added Ca had on F- availability and uptake. Total biomass was greatest with HEDTA and F- < 1 mM. Leaf and stem F concentrations increased exponentially as solution F- increased linearly, with nearly no F partitioning into the seed. Results suggest that F was taken up as HF0 while F- uptake was likely restricted. Additionally, F- competed with HA for Ca, thus preventing the formation of Ca-HA flocculents. The addition of soluble Ca resulted in the precipitation of CaF2 solids on the root surface, as determined by tissue analysis and energy dispersive X-ray spectroscopy.     

Flow-through rates and evaluation of solids separation of compost filter socks versus silt fence in sediment control applications

Soil loss rates from construction sites can be 1000 times the average of natural soil erosion rates and 20 times that from agricultural lands. Silt fence (SF) is the current industry standard used to control sediment originating from construction activities. Silt fences are designed to act as miniature detention ponds. Research has indicated that SF sediment filtering efficiency is related to its ability to detain and pond water, not necessarily the filtration ability of the fabric. Design capacity and spacing is based on flow-through rate and design height. In addition, increased detention of runoff and pressure from ponding may increase the likelihood of overtopping or failure of SF in field application. Testing was conducted on compost silt socks (SS) and SF to determine sediment filtering efficiency, flow-through rate, ponding depth, overtopping point, design height, and design capacity. Results indicate flow-through rate changes with time, as does ponding depth, due to the accumulation of solids on/in the sediment filters. Changes in depth with time were a linear function of flow rate after 10 min of flow, up to the time the sediment filter is overtopped. Predicting the capacity of SF and SS to handle runoff without the filter being overtopped requires consideration of both runoff rate and length of runoff time. Data show SS half the heights of SF were less likely to overtop than SF when sediment-laden runoff water flow rates are less than 1.03 L(-1) s(-1) m(-1) (5 gpm/ft, gal per minute per lineal foot). Ponded depth behind a 61.0-cm (24 in) SF increased more rapidly than behind a 30.5-cm diam. (12 in) SS, and at the end of the thirty minutes, the depth behind the SF was 75% greater than that behind the SS. Removal of solids by the SF and the SS were not shown to be statistically different. Results were used to create a Microsoft Excel-based interactive design tool to assist engineers and erosion and sediment control planners on how to specify compost SS relative to SF in perimeter sediment control applications.