全文获取类型
收费全文 | 3892篇 |
免费 | 183篇 |
国内免费 | 1493篇 |
专业分类
安全科学 | 249篇 |
废物处理 | 276篇 |
环保管理 | 277篇 |
综合类 | 2240篇 |
基础理论 | 628篇 |
环境理论 | 1篇 |
污染及防治 | 1461篇 |
评价与监测 | 138篇 |
社会与环境 | 120篇 |
灾害及防治 | 178篇 |
出版年
2024年 | 1篇 |
2023年 | 67篇 |
2022年 | 169篇 |
2021年 | 153篇 |
2020年 | 117篇 |
2019年 | 96篇 |
2018年 | 125篇 |
2017年 | 174篇 |
2016年 | 165篇 |
2015年 | 216篇 |
2014年 | 264篇 |
2013年 | 407篇 |
2012年 | 329篇 |
2011年 | 341篇 |
2010年 | 263篇 |
2009年 | 272篇 |
2008年 | 290篇 |
2007年 | 247篇 |
2006年 | 220篇 |
2005年 | 173篇 |
2004年 | 113篇 |
2003年 | 139篇 |
2002年 | 154篇 |
2001年 | 96篇 |
2000年 | 117篇 |
1999年 | 140篇 |
1998年 | 115篇 |
1997年 | 106篇 |
1996年 | 101篇 |
1995年 | 110篇 |
1994年 | 77篇 |
1993年 | 65篇 |
1992年 | 48篇 |
1991年 | 32篇 |
1990年 | 15篇 |
1989年 | 6篇 |
1988年 | 15篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 9篇 |
1981年 | 3篇 |
排序方式: 共有5568条查询结果,搜索用时 31 毫秒
1.
Zhu Rong Wang Shixin Srinivasakannan C. Li Shiwei Yin Shaohua Zhang Libo Jiang Xiaobin Zhou Guoli Zhang Ning 《Environmental Chemistry Letters》2023,21(3):1611-1626
Environmental Chemistry Letters - The demand for lithium is growing rapidly with the increase in electric vehicles, batteries and electronic equipments. Lithium can be extracted from brines, yet... 相似文献
2.
分析简单地拉伸、压缩和扭转的情况时,应力状态能容易地被确定.但是,实际上在金属加工过程中材料是承受复杂的应力状态,在模具——工件接触面上增加有摩擦力.而且,这些应力和摩擦力一般地沿着接触面变化.准确的计算或预测载荷、力、应力和温度,不但对设计适宜的设备是重要的,而且对研究工艺期间材料的变化过程也是重要的.本文将讨论材料变形过程中所运用的主要分析方法及其优缺点. 相似文献
3.
Xiaoai Lu Junqian He Jing Xie Ying Zhou Shuo Liu Qiulian Zhu Hanfeng Lu 《环境科学学报(英文版)》2020,32(1):39-48
Carbon–silica materials with hierarchical pores consisting of micropores and mesopores were prepared by introducing nanocarbon microspheres derived from biomass sugar into silica gel channels in a hydrothermal environment.The physicochemical properties of the materials were characterized by nitrogen physical adsorption(BET),scanning electron microscopy(SEM),and thermogravimetric(TG),and the adsorption properties of various organic waste gases were investigated.The results showed that microporous carbon materials were introduced successfully into the silica gel channels,thus showing the high adsorption capacity of activated carbon in high humidity organic waste gas,and the high stability and mechanical strength of the silica gel.The dynamic adsorption behavior confirmed that the carbon–silica material had excellent adsorption capacity for different volatile organic compounds(VOCs).Furthermore,the carbon–silica material exhibited excellent desorption characteristics:adsorbed toluene was completely desorbed at 150℃,thereby showing superior regeneration characteristics.Both features were attributed to the formation of hierarchical pores. 相似文献
4.
Granular acid-activated neutralized red mud (AaN-RM) has been successfully prepared with good chemical stability and physical strength. However, its potential for industrial application remains unknown. Therefore, the performance of granular AaN-RM for phosphate recovery in a fixed-bed column was investigated. The results demonstrated that the phosphate adsorption performance of granular AaN-RM in a fixed-bed column was affected by various operational parameters, such as the bed depth, flow rate, initial solution pH and initial phosphate concentration. With the optimal empty-bed contact time (EBCT) of 24.27 min, the number of processed bed volumes and the phosphate adsorption capacity reached 496.95 and 84.80 mg/g, respectively. Then, the saturated fixed-bed column could be effectively regenerated with a 0.5 mol/L HCl solution. The desorption efficiency remained as high as 83.45% with a low weight loss of 3.57% in the fifth regeneration cycle. In addition, breakthrough curve modelling showed that a 5-9-1 feed-forward artificial neural network (ANN) could be effectively applied for the optimization of the fixed-bed adsorption system; the coefficient of determination (R2) and the root mean square error (RMSE) evaluated on the validation-testing data were 0.9987 and 0.0183, respectively. Therefore, granular AaN-RM fixed-bed adsorption exhibits promising potential for phosphate removal and recovery from polluted water. 相似文献
5.
Feng Liu Lei Sun Jinbao Wan Liang Shen Yanhong Yu Lingling Hu Ying Zhou 《环境科学学报(英文版)》2020,32(3):252-263
Plants constitute a major element of constructed wetlands(CWs).In this study,a coupled system comprising an integrated vertical flow CW(IVCW) and a microbial fuel cell(MFC) for swine wastewater tre atment was developed to research the effects of macrophytes commonly employed in CWs,Canna indica,Acorus calamus,and Ipomoea aquatica,on decontamination and electricity production in the system.Because of the different root types and amounts of oxygen released by the roots,the rates of chemical oxygen demand(COD) and ammonium nitrogen(NH_4~+-N) removal from the swine wastewater differed as well.In the unplanted,Canna indica,Acorus calamus,and Ipomoea aquatica systems,the COD removal rates were 80.20%,88.07%,84.70%,and 82.20%,respectively,and the NH_4~+-N removal rates were 49.96%,75.02%,70.25%,and 68.47%,respectively.The decontamination capability of the Canna indica system was better than those of the other systems.The average output voltages were 520±42,715±20,660±27,and 752±26 mV for the unplanted,Canna indica,Acorus calamus,and Ipomoea aquatica systems,respectively,and the maximum power densities were 0.2230,0.4136,0.3614,and0.4964 W/m~3,respectively.Ipomoea aquatica had the largest effect on bioelectricity generation promotion.In addition,electrochemically active bacteria,Geobacter and Desulfuromonas,were detected in the anodic biofilm by high-throughput sequencing analysis,and Comamonas(Proteobacteria),which is widely found in MFCs,was also detected in the anodic biofilm.These results confirmed the important role of plants in IVCW-MFCs. 相似文献
6.
Ling Liu Qiuhua Zhou Xuezhi Yang Gang Li Jingzhu Zhang Xuehua Zhou Wei Jiang 《环境科学学报(英文版)》2020,32(5):105-116
Inhaled atmospheric fine particulate matter(PM_(2.5)) includes soluble and insoluble fractions,and each fraction can interact with cells and cause adverse effects.PM_(2.5) samples were collected in Jinan,China,and the soluble and insoluble fractions were separated.According to physiochemical characterization,the soluble fraction mainly contains watersoluble ions and organic acids,and the insoluble fraction mainly contains kaolinite,calcium carbonate and some organic carbon.The interaction between PM_(2.5) and model cell membranes was examined with a quartz crystal microbalance with dissipation(QCM-D) to quantify PM_(2.5) attachment on membranes and membrane disruption.The cytotoxicity of the total PM_(2.5) and the soluble and insoluble fractions,was investigated.Negatively charged PM_(2.5) can adhere to the positively charged membranes and disrupt them.PM_(2.5)also adheres to negatively charged membranes but does not cause membrane rupture.Therefore,electrostatic repulsion does not prevent PM_(2.5) attachment,but electrostatic attraction induces remarkable membrane rupture.The human lung epithelial cell line A549 was used for cytotoxicity assessment.The detected membrane leakage,cellular swelling and blebbing indicated a cell necrosis process.Moreover,the insoluble PM_(2.5) fraction caused a higher cell mortality and more serious cell membrane damage than the soluble fraction.The levels of reactive oxygen species(ROS) enhanced by the two fractions were not significantly different.The findings provide more information to better understand the mechanism of PM_(2.5) cytotoxicity and the effect of PM_(2.5) solubility on cytotoxicity. 相似文献
7.
Mengwei Zhang Wanyue Liu Qian Qu Mingjing Ke Zhenyan Zhang Zhigao Zhou Tao Lu Haifeng Qian 《环境科学学报(英文版)》2020,32(11):102-109
An effective broad-spectrum fungicide, azoxystrobin (AZ), has been widely detected in aquatic ecosystems, potentially affecting the growth of aquatic microorganisms. In the present study, the eukaryotic alga Monoraphidium sp. and the cyanobacterium Pseudanabaena sp. were exposed to AZ for 7 days. Our results showed that 0.2–0.5 mg/L concentrations of AZ slightly inhibited the growth of Monoraphidium sp. but stimulated Pseudanabaena sp. growth. Meanwhile, AZ treatment effectively increased the secretion of total organic carbon (TOC) in the culture media of the two species, and this phenomenon was also found in a freshwater microcosm experiment (containing the natural microbial community). We attempted to assess the effect of AZ on the function of aquatic microbial communities through metabolomic analysis and further explore the potential risks of this compound. The metabonomic profiles of the microcosm indicated that the most varied metabolites after AZ treatment were related to the citrate cycle (TCA), fatty acid biosynthesis and purine metabolism. We thereby inferred that the microbial community increased extracellular secretions by adjusting metabolic pathways, which might be a stress response to reduce AZ toxicity. Our results provide an important theoretical basis for further study of fungicide stress responses in aquatic microcosm microbial communities, as well as a good start for further explorations of AZ detoxification mechanisms, which will be valuable for the evaluation of AZ environmental risk. 相似文献
8.
地形因子和植被覆盖是区域灾害评价的关键指标,也是山区型村镇建设生态安全评估的重要内容.为探析山区型村镇建设的生态约束条件,以赤水河流域为研究对象,基于1998—2018年SPOT_VGT NDVI数据,利用地形位置指数(Topographic Position Index,TPI)和坡度位置指数方法,研究了赤水河流域植被生长季NDVI时空变化及地形分异特征.结果表明:①赤水河流域内,1998—2018年植被生长季平均NDVI呈缓慢上升趋势,斜率为0.004 7;NDVI>0.60的集中连片区域主要分布在古蔺县北部、赤水市大部和习水县西北部,占赤水河流域总面积的8.42%;Sen's slope在0.009~0.015区间时,赤水河流域植被生长增强趋势最明显,主要集中分布在赤水河中上游、二道河以及下游的大同河干流地区.②TPI在-39.4~34.3区间的面积最多,为6 221.63 km2,占赤水河流域总面积的34.05%;将赤水河流域坡度类型划分为山脊、上坡、中坡、平坡、下坡、山谷6个坡度位置类型,其中,中坡面积(7 792.02 km2)最大,占流域总面积的42.64%,表明TPI数值较小且坡度大于5°的区域是赤水河流域地形主体.③赤水河流域植被在山脊的平均NDVI最高,为0.747,且山脊平均Sen's slope最高,为0.007 2;山谷平均NDVI最低,为0.709.研究显示,赤水河流域植被分布在118.5~486.9的TPI区间或分布在山脊处时整体生长较好,且生长增强趋势最明显. 相似文献
9.
Liu Cenjie Zhou Zhongbao Liu Qing Xie Rui Zeng Ximei 《Mitigation and Adaptation Strategies for Global Change》2020,25(7):1199-1219
Mitigation and Adaptation Strategies for Global Change - Low-carbon pilot (LCP) policy aims to not only achieve economic development but also address climate change problems in China. With a... 相似文献
10.