Bioavailability and toxicological potential of sunflower-bound residues of (14)C-chlorpyrifos insecticide in rats

Sunflower plants were treated with (14)C-chlorpyrifos under conditions simulating local agricultural practice. Residues present in the oil, methanol extract and cake of the treated sunflower seeds were 7.2, 2.8, and 12 ppm, respectively. When rats fed on sunflower cake containing bound residues for three days, the animals eliminated 46 % of the radioactivity in urine, 25 % in feces and 10 % in the expired air. A further bioavailable amount of 8 % was found in selected organs indicating that the bound residues were highly bioavailable. Chromatographic analysis of urine extract revealed the presence of the parent compound, its oxon, desethyl chlorpyrifos and desethyl chlorpyrifos oxon as free metabolites in addition to a conjugated metabolite. It was liberated by acid hydrolysis and identified as 3,5,6-trichloro-2-hydroxypyridine. Bound residues were found to have biological effects such as inhibition of rat plasma ChE, elevations of liver parameters (ALT, AST, and ALP), decrease in total protein and albumin content suggesting a hepatotoxic potential. A significant increase in the values of creatinine, urea, cholesterol, triglycerides and significant decrease in Catalase and Glutathion-S-Transfrase were observed in treated rats.     

Radio Frequency Identification (RFID) and communication technologies for solid waste bin and truck monitoring system

This paper deals with a system of integration of Radio Frequency Identification (RFID) and communication technologies for solid waste bin and truck monitoring system. RFID, GPS, GPRS and GIS along with camera technologies have been integrated and developed the bin and truck intelligent monitoring system. A new kind of integrated theoretical framework, hardware architecture and interface algorithm has been introduced between the technologies for the successful implementation of the proposed system. In this system, bin and truck database have been developed such a way that the information of bin and truck ID, date and time of waste collection, bin status, amount of waste and bin and truck GPS coordinates etc. are complied and stored for monitoring and management activities. The results showed that the real-time image processing, histogram analysis, waste estimation and other bin information have been displayed in the GUI of the monitoring system. The real-time test and experimental results showed that the performance of the developed system was stable and satisfied the monitoring system with high practicability and validity.     

A new strategy for determination of hydroxylamine and phenol in water and waste water samples using modified nanosensor

A carbon paste electrode modified with p-chloranil and carbon nanotubes was used for the sensitive and selective voltammetric determination of hydroxylamine (HX) and phenol (PL). The oxidation of HX at the modified electrode was investigated by cyclic voltammetry (CV), chronoamperommetry, and electrochemical impedance spectroscopy. The values of the catalytic rate constant (k), and diffusion coefficient (D) for HX were calculated. Square wave voltammetric peaks current of HX and PL increased linearly with their concentrations at the ranges of 0.1–172.0 and 5.0–512.0 μmol L^?1, respectively. The detection limits for HX and PL were 0.08 and 2.0 μmol L^?1, respectively. The separation of the anodic peak potentials of HX and PL reached to 0.65 V, using square wave voltammetry. The proposed sensor was successfully applied for the determination of HX and PL in water and wastewater samples.     

Heavy metals in a typical city-river-reservoir system of East China: Multi-phase distribution, microbial response and ecological risk

The rapid construction of artificial reservoirs in metropolises has promoted the emergence of city-river-reservoir systems worldwide. This study investigated the environmental behaviors and risks of heavy metals in the aquatic environment of a typical system composed of main watersheds in Suzhou and Jinze Reservoir in Shanghai. Results shown that Mn, Zn and Cu were the dominant metals detected in multiple phases. Cd, Mn and Zn were mainly presented in exchangeable fraction and exhibited high bio...     

Life cycle inventory of the commercial production of compost from oil palm biomass: a case study

This paper compared the life cycle inventory (LCI) obtained from three commercial oil palm biomass composting projects in Malaysia which use the open windrow composting system. The LCI was obtained and calculated based on the functional unit of 1 t of compost produced. The input of the inventory are the feed materials such as empty fruit bunches (EFB) and palm oil mill effluent (POME); and utilities which include electricity generated at palm oil mill and diesel used. Composting 2.0–2.5 t of EFB and 5.0–7.5 t of POME required diesel from 218.7 to 270.2 MJ and electricity from 0 to 6.8 MJ. It is estimated that the composting emitted from 0.01 to 0.02 t CO_2eq/t_compost mainly from diesel used to operate machineries. Composting saved 65 % of time required for a complete degradation of POME when compared to ponding system, and 89 % of time required for a complete degradation of EFB compared to mulching. In terms of land required, it required 36 % less land as compared to ponding for POME and 99 % less land as compared to mulching for EFB. Based on the case study, diesel was found to be the main contributor to the environmental impact. There is a potential of upgrading the process to be more economical and environmental friendly. Using electricity as the source of energy has a lower footprint for the composting process. Instead of using raw POME, studies had reported that using treated POME either from anaerobic ponding or digested tank can accelerate the composting process.     

Supplementation with selenium nanoparticles alleviates diabetic nephropathy during pregnancy in the diabetic female rats

Environmental Science and Pollution Research - The bioactivity of nanoparticles has engendered a promise in scientific communities for developing novel therapeutic strategies. This study...     

Primary and secondary organic winter aerosols in Mediterranean cities under different mixing layer conditions (Barcelona and Granada)

Environmental Science and Pollution Research - PM10 was collected during an EMEP winter campaign of 2017–2018 in two urban background sites in Barcelona (BCN) and Granada (GRA), two...     

Recent Advancement of Biopolymers and Their Potential Biomedical Applications

Journal of Polymers and the Environment - Recently, the advantages of biopolymers over conventional plastic polymers are unprecedented, provided that they are used in situations in which they raise...     

Polyaniline films for efficient removal of aromatic acids from water

Adsorbents in the form of powders are commonly used to filtrate organic compounds in waters. However, this technique requires the separation of the solid phase from the solution after adsorption experiments. Here we propose the use of films as adsorbents. We synthesized polyaniline films by chemical oxidative polymerization of aniline on red ceramic brick. This film was tested to remove trimellitic, hemimellitic and pyromellitic acids as model molecules of the biodegradation of aquatic humic substances. We evaluated the effect of pH, contact time and initial concentration. Our results show that optimal adsorption conditions required 45 min of solid/liquid contact at pH 7 and an initial concentration of 20 mg/l. The maximum adsorption capacities for hemimellitic, trimellitic and pyromellitic acids are 154.83 for hemimellitic acid, 161.88 for trimellitic acid and 175.26 mg/g for pyromellitic acid. The adsorption efficiency of the polyaniline film decreased only by 13 % after four cycles. Overall, we conclude that polyaniline films are promising separable adsorbents compared to conventional adsorbents for removal of aromatic polycarboxylic acids from water.     

Toxicity assessment of crude oils: A methodological view

As a continuity of efforts in the field of laboratory ecotoxicological studies of oil on marine organisms, the present work contains data showing to what extent the observed toxicity of two chemically dispersed crude oils (arabian light and heavy) on well succeeded fish culture species (Lebistes reticulatus) is tightly dependent on the instantaneous measured oil concentration in the bioassay media rather than the initial applied concentrations.