Hexavalent chromium reduction kinetics in rodent stomach contents

Reduction of hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) in the stomach prior to absorption is a well-recognized detoxification process thought to limit the toxicity of ingested Cr(VI). However, administration of high concentrations of Cr(VI) in drinking water cause mouse small intestinal tumors, and quantitative measures of Cr(VI) reduction rate and capacity for rodent stomach contents are needed for interspecies extrapolation using physiologically-based toxicokinetic (PBTK) models. Ex vivo studies using stomach contents of rats and mice were conducted to quantify Cr(VI) reduction rate and capacity for loading rates (1-400 mg Cr(VI) L⁻¹ stomach contents) in the range of recent bioassays. Cr(VI) reduction was measured with speciated isotope dilution mass spectrometry to quantify dynamic Cr(VI) and Cr(III) concentrations in stomach contents at select time points over 1 h. Cr(VI) reduction followed mixed second-order kinetics, dependent upon concentrations of both Cr(VI) and the native reducing agents. Approximately 16 mg Cr(VI)-equivalents of reducing capacity per L of fed stomach contents (containing gastric secretions, saliva, water and food) was found for both species. The second-order rate constants were 0.2 and 0.3 L mg⁻¹ h⁻¹ for mice and rats, respectively. These findings support that, at the doses that caused cancer in the mouse small intestine (?20 mg Cr(VI) L⁻¹ in drinking water), the reducing capacity of stomach contents was likely exceeded. Thus, for extrapolation of target tissue dose in risk assessment, PBTK models are necessary to account for competing kinetic rates including second order capacity-limited reduction of Cr(VI) to Cr(III).     

Landslide susceptibility mapping in an area of underground mining using the multicriteria decision analysis method

Landslides are geomorphological phenomena that affect anthropogenic and natural features on the Earth’s surface. Many previous studies have identified several factors that have contributed to landslides. Among these factors are physical characteristics, such as slope, aspect, and land cover, of Earth’s surface. Moreover, landslides can be triggered by human activities such as underground mining. This study aims to identify landslide susceptibility areas by analyzing landslide-related factors, including land subsidence triggered by underground mining. The area of interest was Kozlu, Turkey, where underground mining has been in progress for the past 100 years. Thus, to identify landslide risk zones, the multicriteria decision analysis method, together with the analytical hierarchy method, was used. The datasets included were topography, land cover, geological settings, and mining-induced land subsidence. The spatial extent of land subsidence was estimated using a previously published model. A landslide susceptibility map (LSM) was developed using a purposely developed GIS-based software. The results were compared with a terrain deformation map, which was developed in a separate study using the differential synthetic aperture radar interferometry (DInSAR) technique. The results showed a substantial correlation between the LSM and DInSAR map. Furthermore, it was found that ~?88% of the very high and high landslide risk areas coincided with location of the past landslide events. These facts suggest that the algorithm and data sources used were sufficient to produce a sufficiently accurate LSM, which may be used for various purposes such as urban planning.     

Evaluation of relationship between meteorological parameters and air pollutant concentrations during winter season in Elazığ, Turkey

In recent years, due to the rapid increase in population density, building density and energy consumption, the outdoor air quality has deteriorated in the crowded urban areas of Turkey. Elaz?? city, which is located in the east Anatolia region of Turkey, is also influenced by air pollutants. In the present study, relationship between monitored air pollutant concentrations such as SO₂ and the total suspended particles (TSP) data and meteorological factors such as wind speed, temperature, relative humidity, solar radiation and atmospheric pressure was investigated in months of October, November, December, January, February, and March during the period of 3 years (2003, 2004 and 2005) for Elaz?? city. According to the results of linear and non-linear regression analysis, it was found that there is a moderate and weak level of relation between the air pollutant concentrations and the meteorological factors in Elaz?? city. The correlation between the previous day’s SO₂, TSP concentrations and actual concentrations of these pollutants on that day was investigated and the coefficient of determination R² was found to be 0.64 and 0.54, respectively. The statistical models of SO₂ and TSP including all of meteorological parameters gave R² of 0.20 and 0.12, respectively. Further, in order to develop this model, previous day’s SO₂ and TSP concentrations were added to the equations. The new model for SO₂ and TSP was improved considerably with R²?=?0.74 and 0.61, respectively.     

Effects of urban sprawl on agricultural land: a case study of Kahramanmaraş, Turkey

The main objective of this study is to quantify areal loss of olive groves due to urban sprawl of the city of Kahramanmara?, Turkey. Spatial changes were analysed by interpreting the digitized data derived from a black–white monoscopic aerial photograph taken in 1985, panchromatic IKONOS image of 2000 and two pan-sharpened Quickbird images of 2004 and 2006. Data obtained revealed that the area of olive groves decreased by 25% from 460.55 ha in 1985 to 344.46 in 2006, while the number of parcels increased from 170 to 445. Of the total areal loss, 60% was due to building constructions, with the rest being due to clear-cut for new residential gardens composed of exotic plants, new buildings, or new roads. Rapid population growth, increased land prices due to urban expansion, and abandonment of agricultural practices to construction of multi-storey buildings were the main causes of the process that transformed the olive groves into urbanized areas. Results pointed to an urgent need to (1) revise the national and municipal land management practices, (2) balance the gap between the short- and long-term economic benefits that urban and community development plans ignore, and (3) monitor land-use changes periodically by using high resolution satellite images.     

Post-classification comparison of land cover using multitemporal Landsat and ASTER imagery: the case of Kahramanmaraş, Turkey

This study assessed land cover (LC) changes in Kahramanmara? (K.Mara?) and its environs by using multitemporal Landsat and ASTER imagery, respectively belong to 1989, 2000 and 2004. A priori defined nine land cover classes in the classification scheme were urban and built-up, forest, sparsely vegetated areas, grassland, vegetated stream beds, unvegetated stream beds, bare areas, crop fields, and water bodies. Individual classifications were employed using the combination of both unsupervised and supervised classification methods. Iterative Self Organizing Data Analysis (ISODATA) was used to reduce spectral variation in the scenes arising from complex pattern of crop fields. Maximum Likelihood classifier was used in the LC classification of the individual images. Image pairs of consecutive dates were compared by overlaying the thematic LC maps and cross-tabulating the LC statistics. Urbanization and expansion of agriculture were the major reasons for the dramatic LC conversions. The amount of conversion from crop fields to water occurred as large as 927.67 ha, accounting for 73% of the total land-to-water conversion. Conversions to agriculture have mainly been occurred from grasslands and sparsely vegetated areas as large as 1,314.95 and 1,325.84 ha, respectively. Urban coverage doubled in this period as a result of 1,443.45 ha of increase. Urban area increased in the second period from 2,920 to 3,526 ha. Conversions to agriculture occurred at high amounts. A total of 1,075.79 ha area changed from sparsely vegetated areas to crop fields. A landscape-level environmental monitoring scheme based on satellite remote sensing was proposed for effective environmental resource management.     

Spatial variability of depth and salinity of groundwater under irrigated ustifluvents in the Middle Black Sea Region of Turkey

Information on the potential risk for soil salinity buildup can be very helpful for soil salinity management in irrigated areas. We evaluated the spatial and temporal variability of groundwater salinity (GWS) and groundwater depth (GWD), which are two of the most important indicators of soil salinity, by indicator kriging technique in a large irrigated area in northern Turkey. GWS and GWD were measured on a monthly basis from irrigation season (August 2003) to rainy season (April 2004) at 60 observation wells in the 8,187-ha irrigated area. Five indicator thresholds were used for GWS and GWD. The semivariogram for each of the thresholds for both variables was analyzed then used together with experimental data to interpolate and map the corresponding conditional cumulative distribution functions (CCDF). Risk for soil salinity buildup was greater in the irrigation season compared to that in the rainy season. The greatest risk for soil salinity buildup occurred in the eastern part of the study area, suffering from poor drainage problem due to malfunctioning drainage infrastructure, as indicated by the CCDF of GWS and GWD obtained in both seasons. It was concluded that a combination of mechanical and cultural measures should be taken in high-risk locations to avoid further salinity problems.     

Pesticide residues in dried table grapes from the Aegean region of Turkey

Dried grapes make the ideal low-calorie snack. The formation of gray mold during the drying of the grapes can severely decrease production. Pesticides and fungicides are applied to prevent losses due to pests and mold. Dried grapes from 99 farms in the Aegean region were sampled for pesticide residues. Of the 26 pesticides analyzed for, chlorpyrifos methyl, chlorpyrifos ethyl, deltamethrin, lambda-cyolathrin, dichlofluanid, iprodione, and procymidone were detected in the dried grapes. Only seven samples contained residues above the maximum residue limit. It is important to note that pesticide residues were only present in samples originating from vineyards using conventional farming practices.     

An empirical analysis of surface acting in intra‐organizational relationships

Prior research analyzing surface acting—employees' regulation of emotional expressions—has mostly focused on the interactions between front‐line employees and their customers in service industries and paid very little attention to intra‐organizational relationships. With an aim to shed light on this important yet relatively unexplored area, I developed a theoretical model analyzing the antecedents and outcomes of surface acting within organizations, by drawing on the sociometer theory and self‐presentation theory frameworks. To test the model, I conducted a cross‐level field study in a sample of 65 work groups and 478 employees in two organizations, located in a large city in Northern California. I have collected the data from two sources, including employees and their supervisors who rated their performance. Results indicated that employees were more likely to engage in surface acting when their affective traits and personal goals were less congruent with work environment. Surface acting was also positively related to perceived organizational politics and self‐monitoring. As for outcomes, surface acting was positively related to emotional exhaustion and negatively to performance. I discuss limitations, implications, and future research direction. Copyright © 2012 John Wiley & Sons, Ltd.     

Determination of pesticide residues in Turkey��s table grapes: the effect of integrated pest management, organic farming, and conventional farming

Turkey is one of the world??s largest producers and exporters of table grapes. Growing social concerns over excessive pesticide use have led to farming to move from conventional to organic practices. Table grapes were collected from 99 different farms in three Aegean regions. Pesticide residues were only detected in farms using conventional agriculture practices while no pesticides were detected in grapes from farms using organic or integrated pest management. A risk assessment model indicated that lambda-cyhalothrin posed the most significant risk at conventional farms.     

Some engineering aspects of homoionized mixed clay minerals

Many studies have been conducted to investigate thephysicochemical behavior of pure clay minerals and predicttheir engineering performance in the field. In this study, thephysicochemical properties of an artificial mixture of differentclay minerals namely, 40-50% montmorillonite, 20-30% illite and 10-15% kaolin were investigated. The mixture was homoionized with sodium, Na⁺; calcium, Ca²⁺; andaluminum, Al³⁺. The engineering properties studied wereconsistency limits, sediment volume, compressibility behavior,and hydraulic conductivity. The results revealed that theliquid, plastic and shrinkage limits of soil increased withincreasing cation valence. The hydraulic conductivity of thesoil also increased with an increase in the valence of thecation at any given void ratio. Aluminum and sodium treatedclays had the highest and the lowest modified compressionindex values, respectively. Furthermore, trivalent cationsaturated clayey soil consolidates three times faster thanthat of monovalent and two times faster than that of divalent.These properties of the soils determined were, in general,similar to those of kaolinite rather than those ofmontmorillonite. The comparison of the results obtained withthe published data in the literature revealed that thephysicochemical behavior of the tested clay soil was, ingeneral, similar to that of kaolinite.