Chloride effects on nitrogen dynamics in forested and suburban stream debris dams

Organic debris dams (accumulations of organic material) can function as "hotspots" of nitrogen (N) processing in streams. Suburban streams are often characterized by high flows that prevent the accumulation of organic debris and by elevated concentrations of solutes, especially nitrate (NO(3)(-)) and chloride (Cl(-)). In this study we (1) studied the effects of urbanization on the extent and characteristics of debris dams in large and small streams and (2) evaluated the effects of NO(3)(-) and Cl(-) on rates of N cycle processes in these debris dams. In some suburban streams debris dams were small and rare, but in others factors that reduce the effects of high stream flows fostered the maintenance of debris dams. Ambient denitrification enzyme activity (DEA) in these suburban and forested streams was positively correlated with stream NO(3)(-) concentrations. In laboratory microcosms, DEA in debris dam material from a forested reference stream was increased by NO(3)(-) additions. Chloride additions constrained the response of DEA to NO(3)(-) additions in material from the forested stream, but had no effect on DEA in material from streams with a history of high Cl(-) levels. Chloride additions changed the sign of net N mineralization from negative (consumption of inorganic N) to positive in debris dam material from the forested reference stream, but had no effect on net mineralization in material from streams with a history of exposure to Cl(-). Understanding the factors regulating the maintenance and N cycling activity of organic debris, and incorporating them into urban stream management plans could have important effects on N dynamics in suburban watersheds.     

Polybrominated diphenyl ether flame retardants in the North American environment

North America consumes over half of the world's production of polybrominated diphenyl ether (PBDE) flame retardants. About 98% of global demand for the Penta-BDE mixture, the constituents of which are the most bioaccumulative and environmentally widespread, resides here. However, research on the environmental distribution of PBDEs in North America has lagged behind that in Northern Europe. Examination of available governmentally maintained release data suggests that Deca-BDE use in the US substantially exceeds that in Canada. Penta-BDE use probably follows a similar pattern. PBDE demand in Mexico is uncertain, but is assumed to be comparatively modest. Recent research examining air, water, sediment, sewage sludge and aquatic biota suggests that Penta-BDE constituents are present in geographically disparate locations in the US and Canada. The less brominated congeners have been observed in areas distant from their known use or production, e.g. the Arctic. PBDEs have been detected in low concentrations in North American air, water and sediment, but much higher levels in aquatic biota. Increased burdens as a function of position in the food web have been noted. PBDE concentrations in US and Canadian sewage sludges appear to be at least 10-fold greater than European levels and may be a useful barometer of release. In general, PBDE concentrations in environmental media reported in North America are comparable or exceed those observed elsewhere in the world. In contrast to Europe, environmental burdens are increasing over time here, consistent with the greater consumption of the commercial mixtures. However, data remain relatively scarce. Deca-BDE in the North American environment appears largely restricted to points of release, e.g. urban areas and those where PBDE-containing sewage sludges have been applied. This lack of redistribution is likely due to its extremely low volatility and water solubility. Penta-BDE and Deca-BDE products are used in different applications and this may also be a factor controlling their environmental release.     

Occupational health and safety professionals and management: identity, marriage, servitude or supervision?

The role and training of occupational health and safety professionals is a continuing subject of debate in the light of recent European legislation. This paper discusses the possible roles of professionals in the context of the complexities of Occupational Health and Safety (OHS) management. It presents the roles using the metaphor of parent-adult-child relationships (Harris, 1970) and discusses the ways in which different relationships can lead to different problems of functioning. It concludes with presenting the possible role of training in tackling these problems.     

Designing Environmental Databases for Statistical Analyses

The Environmental Monitoring and Assessment Program (EMAP) collects data that are used to statistically assess the environmental condition of large geographic regions. These data are then posted on the EMAP web site so that anyone can use them. Databases used for the statistical analyses, "analytical" databases, differ in design from the "general-use" databases used by a secondary audience. Their scope is usually restricted in time, in geographic extent, and in type and content of data, often being limited to a single scientific discipline. Their structure may be more horizontal than vertical, so that statistical programs can import the data easily. Their design is strongly influenced by the nature of the scientific analysis because the goal is to create a good computing environment for that analysis. We illustrate these aspects of design with an analytical database for estuaries in the U.S. mid-Atlantic region.     

Developing the understanding of underlying causes of construction fatal accidents

A study of a small sample of construction fatal accidents was used to pilot a potential method of analysis for the UK Health and Safety Executive (HSE) Construction Division. The work was conducted in the context of a Governmental Inquiry into construction fatalities in 2009, but has been developed further since. The sample of 26 accidents (28 fatalities) was drawn from the 211 fatal accidents in the years ending 2006–2008, to be broadly illustrative of the range of accident characteristics. The accidents were analysed on the basis of available inspectorate reports and structured interviews with the investigating inspectors. A standard method of classification on four levels was developed, based on the Human Factors Analysis and Classification System (HFACS) classification of errors and task level factors, with additional categories covering the organisational and regulatory/market levels of the system. The results showed a concentration of underlying factors associated with inadequacies in planning and risk assessment, competence assurance, hardware design, purchase and installation, and contracting strategy. These findings were partially validated by comparing them with another sample of 50 accidents analysed earlier by the HSE. This paper describes the development and testing of the investigation and classification method and how it is being further developed since the initial study. It also provides a summary of the findings relating to underlying causes.     

The influence of physicochemical parameters on bioaccessibility-adjusted hazard quotients for copper,lead and zinc in different grain size fractions of urban street dusts and soils

When the hazard quotient for ingestion (HQI) of a trace element in soil and dust particles is adjusted for the element’s bioaccessibility, the HQI is typically reduced as compared to its calculation using pseudo-total element concentration. However, those studies have mostly used bulk particles (<2 mm or <250 µm), and the reduction in HQI when expressed as bioaccessible metal may not be similar among particle size fractions, the possibility probed by the present study of street dusts and soils collected in Tehran. The highest Cu, Pb and Zn near-total concentrations occurred in the finest particles of dusts and soils. Bioaccessible concentrations of Cu, Pb and Zn in the particles (mg kg^?1) were obtained using simple bioaccessibility extraction test (SBET). The bioaccessibility (%) did not vary much among near-total concentrations. In the bulk (<250 µm) sample, the bioaccessible concentration of Cu and Pb increased as the pH of sample increased, while Zn bioaccessibility (%) in the bulk particles was influenced by organic matter and cation exchange capacity. X-ray diffraction identified sulfide and sulfate minerals in all of the size-fractionated particles, which are insoluble to slightly soluble in acidic conditions and included most of the Cu and Pb in the samples. The only Zn-bearing mineral identified was hemimorphite, which would be highly soluble in the SBET conditions. The calculated HQI suggested potential non-carcinogenic health risk to children and adults from ingestions of soils and dusts regardless of particle size consideration, in the order of Zn > Pb ≥ Cu. The HQI calculated from near-total metal was not much different for particle size classes relative to bulk particles; however, the bioaccessibility percent-adjusted HQI for Pb was higher for the smaller particles than the bulk. This work is novel in its approach to compare HQI for a bulk sample of particles with its composite particle size fractions.