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651.
Generic approaches to transfer 总被引:1,自引:0,他引:1
A review of methods which have been used to describe and predict transfer of radionuclides in biota was undertaken. The intent was to identify approaches that might prove useful in extending predictive estimates to other organisms and environments. Empirical approaches, such as found in the use of transfer factors, were examined. Kinetic methodologies were also presented. Allometric functions, with their ability to make broad generalizations, were also discussed. Data from several earlier radioecological assessments were tested for their potential utility in developing allometric relationships, with the result implying that such an approach might prove useful. 相似文献
652.
Alvarez-Muñoz D Lara-Martín PA Blasco J Gómez-Parra A González-Mazo E 《Environment international》2007,33(4):565-570
The presence of linear alkylbenzene sulfonates (LAS) and their degradation intermediates, sulfophenylcarboxylic acids (SPCs), with concentrations up to 100 ppb has been found in surface waters taken from the estuary of the river Guadalete (Cádiz, SW of Spain). Higher concentrations were found at the sampling site located adjacent to the discharge outlet of a wastewater treatment plant (WWTP). The concentrations decreased downstream to a few ppb as a result of dilution, sorption, and degradation processes, which were taking place along the estuary. Once the presence of both xenobiotics was confirmed in the environment, an in vivo assay was conducted to study their biotransformation and effects in the benthic fish Solea senegalensis. A flow-through system was employed, consisting of an exposure phase (120 h) with environmental levels of the surfactant (200, 500 and 800 microg/L of 2?C(10)LAS), followed by a depuration stage (72 h). The generation of SPCs has been quantified during these phases in both water and fish, with LAS biotransformation shown in all cases. The antioxidant enzymes catalase (CAT), glutathione peroxidase (GPX), glutathione reductase (GR), the phase II enzyme glutathione S-transferase (GST), and the phase III acid and alkaline phosphatases (AcP, ALP) were also estimated and utilized as biomarkers. 相似文献
653.
The aim of this work was to measure survival of the amphipod Corophium insidiosum and luminescence inhibition in the marine bacterium Vibrio fisheri on surface sediment samples collected from a shallow coastal lagoon (Pialassa Baiona, northern Adriatic Italian coast) before execution of dredging operations to deepen the main inner channel of the lagoon and restore the water circulation. Trace metal (Cd, Cu, Cr, Hg, Ni, Pb) concentrations, grain size and organic carbon matter content as loss of ignition were also measured. Toxicity testing with V. fisheri was carried out according to the Microtox Basic Solid-Phase Test (BSPT) protocol. The preliminary outcomes of this work show that: (a) the investigated area can be categorised as moderately degraded; (b) there is no evident spatial pattern in sediment toxicity and trace metal concentrations; (c) Microtox responses are not biased by sediment characteristics such as silt, clay and organic matter content. 相似文献
654.
Seepage from Hg mine wastes and calcines contains high concentrations of mercury (Hg). Hg pollution is a major environmental
problem in areas with abandoned mercury mines and retorting units. This study evaluates factors, especially the hydrological and
sedimentary variables, governing temporal and spatial variation in levels and state of mercury in streams impacted by Hg contaminated
runo . Samples were taken during di erent flow regimes in theWanshan Hg mining area in Guizhou Province, China. In its headwaters
the sampled streams/rivers pass by several mine wastes and calcines with high concentration of Hg. Seepage causes serious Hg
contamination to the downstream area. Concentrations of Hg in water samples showed significant seasonal variations. Periods of
higher flow showed high concentrations of total Hg (THg) in water due to more particles being re-suspended and transported. The
concentrations of major anions (e.g., Cl??, F??, NO3?? and SO4
2??) were lower during higher flow due to dilution. Due to both sedimentation
of particles and dilution from tributaries the concentration of THg decreased from 2100 ng/L to background levels (< 50 ng/L) within
10 km distance downstream. Sedimentation is the main reason for the fast decrease of the concentration, it accounts for 69% and 60%
for higher flow and lower flow regimes respectively in the upper part of the stream. Speciation calculation of the dissolved Hg fraction
(DHg) (using Visual MINTEQ) showed that Hg(OH)2 associated with dissolved organic matter is the main form of Hg in dissolved
phase in surface waters in Wanshan (over 95%). 相似文献
655.
Aged refuse from waste landfills closed for eight years was examined and found to contain rich methanotrophs capable of biooxidation
for methane. Specially, community structure and methane oxidation capability of methanotrophs in the aged refuse were
studied. The amount of methanotrophs ranged 61.97 103–632.91 103 cells/g (in dry basis) in aged refuse from Shanghai Laogang
Landfill. Type I and II methanotrophs were found in the aged refuse in the presence of sterilized sewage sludge and only Type I
methanotrophs were detected in the presence of nitrate minimal salt medium (NMS). The clone sequences of the pmoA gene obtained
from the aged refuse were similar to the pmoA gene of Methylobacter, Methylocaldum, and Methylocystis, and two clones were distinct
with known genera of Type I methanotrophs according to phylogenetic analysis. Aged refuse enriched with NMS was used for methane
biological oxidation and over 93% conversions were obtained. 相似文献
656.
Xinxin Wang Zhen Han Zhihui Bai Jingchun Tang Anzhou M Jizheng He Guoqiang Zhuang 《环境科学学报(英文版)》2011,23(11):1858-1864
The impact of petroleum on archaeal community in salinealkali soils was investigated, which will expand the knowledge of the archaeal population involved in the natural attenuation of hydrocarbons in extreme environments. 相似文献
657.
658.
659.
The photocatalytic degradation of methylene blue(MB) over Fe-doped CaTiO3 under UV-visible light was investigated. The as-prepared samples were characterized using X-ray diffraction(XRD), scanning electron microscope(SEM) equipped with an energy dispersive spectrometer(EDS) system, Fourier transform infrared spectra(FT-IR), and UV-visible diffuse reflectance spectroscopy(DRS). The results show that the doping with Fe significantly promoted the light absorption ability of CaTiO3 in the visible light region. The Fe-doped CaTiO3 exhibited higher photocatalytic activity than CaTiO3 for the degradation of MB.However, the photocatalytic activity of the Fe-doped CaTiO3 was greatly influenced by the calcination temperature during the preparation process. The Fe-doped CaTiO3 prepared at500°C exhibited the best photocatalytic activity, with degradation of almost 100% MB(10 ppm)under UV-visible light for 180 min. 相似文献
660.
Higher concentrations of Hg can be emitted from coal pyrolysis or gasification than from coal combustion, especially elemental Hg. Highly efficient Hg removal technology from coal-derived fuel gas is thus of great importance. Based on the very excellent Hg removal ability of Pd and the high adsorption abilities of activated carbon(AC) for H2 S and Hg, a series of Pd/AC sorbents was prepared by using pore volume impregnation, and their performance in capturing Hg and H2 S from coal-derived fuel gas was investigated using a laboratory-scale fixed-bed reactor. The effects of loading amount, reaction temperature and reaction atmosphere on Hg removal from coal-derived fuel gas were studied. The sorbents were characterized by N2 adsorption, X-ray diffraction(XRD) and X-ray photoelectron spectroscopy(XPS). The results indicated that the efficiency of Hg removal increased with the increasing of Pd loading amount, but the effective utilization rate of the active component Pd decreased significantly at the same time. High temperature had a negative influence on the Hg removal. The efficiency of Hg removal in the N2-H2S-H2-CO-Hg atmosphere(simulated coal gas) was higher than that in N2-H2S-Hg and N2-Hg atmospheres, which showed that H2 and CO, with their reducing capacity, could benefit promote the removal of Hg. The XPS results suggested that there were two different ways of capturing Hg over sorbents in N2-H2S-Hg and N2-Hg atmospheres. 相似文献