Alkaline Degradation of Cellulose: Mechanisms and Kinetics

Cellulose powder and softwood sawdust were subjected to alkaline degradation under conditions representative of a cementitious environment for periods of 7 and 3 years, respectively. During the first 3 years, sampling was frequent, and data on the degradation of cellulose and production of isosaccharinic acid was used for establishing long-term prediction models. Samples after an additional period of 4 years were compared to the predicted values. The total rate of degradation was measured as the increase in total organic carbon (TOC) in corresponding solutions. A previously published theoretical model of degradation kinetics gave a good approximation of the present experimental data. Peeling-off, stopping, and alkaline hydrolysis reaction rate constants were obtained as model parameters, and the results suggested that the transformation of the glucose end group is the rate-limiting step in the cellulose peeling-off reaction and also determines the pH dependence of that reaction. After 3 years, isosaccharinic (ISA) acid represented 70–85% of all degradation products as quantified by capillary zone electrophoresis. The long-term prediction model indicated that all of the cellulose would be degraded after only 150–550 years. The control sampling after 7 years points toward a lower degradation of cellulose and production of ISA than predicted by the model, reflecting either a degradation of ISA that was faster than the production or a termination of the ISA production.     

Effects of experimental acidification on mobilisation of metals from sediments of limed and non-limed lakes

In order to study the influence of pH on the mobilisation of metals from lake sediments, intact sediment cores with overlying water were sampled from one lime treated lake and one acidified lake. The overlying water of two cores from each lake was successively acidified to pH 4.2 over a period of 3 months. In the acid treated samples from the limed lake, the initial concentrations of Al, Cd, Mn, Pb and Zn in the overlying water were generally lower and the final concentrations were higher than in the acid treated samples from the acidified lake. The labile inorganic fraction of Al (Al(i)) was increasingly dominating as pH decreased. Redox potential and pH in the sediment indicated that the upper two centimetres were involved in the exchange reactions. The experiment showed that mobilisation of metals from sediments can occur and the results indicated that mobilisation could contribute to increased concentrations of metals in lake water during reacidification of formerly lime treated lakes.     

Overview of regulatory/policy/economic issues related to carbon dioxide

This is an overview of Session 2c dealing with the regulatory, policy and economic issues related to carbon dioxide and its impact on global climate change. The information is taken from the two papers presented in this session (the U.S. Perspective by Dennis Leaf and the European Perspective by Hans J.H. Verolme) and from the panel discussion that took place at the end of the session. The overview focuses primarily on the policy responses of both the United States (US) and the United Kingdom (UK) to changes in global atmospheric pollution. To a lesser extent, the progress of policy responses to these changes is discussed. The United Nations Framework Convention on Climate Change (UNFCCC) has been signed and ratified by over 180 countries. The UNFCCC contained no binding targets or timetables for emissions reductions. The Kyoto Protocol [United Nations. Kyoto Protocol to the United Nations Framework Convention on Climate Change. UNEP.IUC/99/10. Chatlelaine, Switzerland: United Nations Environment Programme's Information Unit for Conventions, for the Climate Change Secretariat, 1997] to the UNFCCC did contain targets and timetables for reductions of greenhouse gases on the part of developed countries. The US has signed but not ratified the Kyoto Protocol. The US has experienced some movement to reduce greenhouse gas emissions on the part of various levels of government, as well as the private sector. The UK's commitment to reducing green house gases is laid down in the UK Climate Change Programme 2000. The UK is a member of the European Union (EU). In this context, an example of EU-wide progress, the voluntary agreement with car manufacturers to reduce CO(2) emissions in new vehicles, will be discussed. In addition, there will be some discussion on the UK CO(2) trading scheme that created the first market in the world in April 2001. Overall, the policy process is constantly informed by scientific research. In the case of climate change, much of this work is carried out under the auspices of international scientific panels.     

Interacting effects of ambient light and plumage color patterns in displaying Wire-tailed Manakins (Aves,Pipridae)

Sending color signals to conspecifics may attract predators, leading to opposing selection pressures on the evolution of signal expression and display behavior in animals. The costs of signaling can be reduced, however, because conspicuousness is the combined result of the reflectance spectra of the displayer's color pattern and the spectra of ambient light illuminating the animal. Changes in ambient light can alter conspicuousness, even when chemical and structural color-generating mechanisms remain constant, potentially allowing animals to display their colors most fully in light environments where the benefits are greatest relative to the costs. Using spectroradiometric methods, we determined how light habitat use affects conspicuousness in adult males of the Wire-tailed Manakin Pipra filicauda, a lekking bird species with vivid plumage colors. We studied three aspects of visibility, including properties of the entire color pattern, visual contrast within an individual's plumage and a bird's contrast relative to its visual background. Wire-tailed Manakins usually displayed in forest shade environments, which reduced their conspicuousness at larger viewing distances, while maximizing visual contrast within the plumage color pattern at close viewing distances. Compared to sunspots, ambient light in forest shade reduces the contrast of individual bird colors with the background at close viewing distance. However, background contrast of individual bird colors in the shade was still relatively higher during sunny than during cloudy weather which may explain why males were more active when the sun was not blocked by clouds. Assuming that the visual perceptions of predators and other manakins do not differ from the reflectance patterns we measured, Wire-tailed manakins tend to display in light environments that reduce the conflicts between avoiding long distance detection by predators and displaying conspicuous color signals to visiting females.     

Mercury and Methylmercury in Runoff from a Forested Catchment – Concentrations, Fluxes, and Their Response to Manipulations

Measurements of TotHg (total mercury) and MeHg (methylmercury) in runoff from the covered catchment G1 and the reference catchment F1 at Lake Gårdsjön, Sweden, have been performed and evaluated. The roof over the covered catchment limits atmospheric deposition input of TotHg and MeHg and a response in runoff concentrations and transport was expected. Based on data from 10 yr of monitoring, no statistically significant change in runoff flux of TotHg or MeHg can be observed. A slight decrease in MeHg output in the covered catchment was observed after 2 yr of the experiment. This can be explained as a temporary effect caused by the roof construction. The main conclusion is that release of TotHg and MeHg from the forest soil is controlled by factors other that wet deposition input, for example the mineralisation of organic matter. Furthermore, there is no indication of a depletion of the Hg pool in the soil. In spring 1999, the reference catchment F1 was affected by forestry machinery significantly disturbing the forest soil layer in a limited area. This caused MeHg concentrations to increase dramatically in runoff and led to an increase of the annual transport by at least a factor of 3. This indicates that forestry and other activities that disturb forest soils may be important for controlling MeHg fluxes to aquatic ecosystems.