Ionic liquids for the inhibition of gas hydrates. A review

The formation of gas hydrates is a major issue during the operation of oil and gas pipelines, because gas hydrates cause plugging, thereby disrupting the normal oil and gas flows. A solution is to inject gas hydrate inhibitors such as ionic liquids. Contrary to classical inhibitors, ionic liquids act both as thermodynamic inhibitors and hydrate inhibitors, and as anti-agglomerates. Imidazolium-based ionic liquids have been found efficient for the inhibition of CO₂ and CH₄ hydrates. For CO₂ gas hydrates, N-ethyl-N-methylmorpholinium bromide showed an average depression temperature of 1.72 K at 10 wt% concentration. The induction time of 1-ethyl-3-methyl imidazolium bromide is 36.3 h for CO₂ hydrates at 1 wt% concentration. For CH₄ hydrates, 1-ethyl-3-methyl-imidazolium chloride showed average depression temperature of 4.80 K at 40 wt%. For mixed gas hydrates of CO₂ and CH₄, only quaternary ammonium salts have been studied. Tetramethyl ammonium hydroxide shifted the hydrate liquid vapour equilibrium to 1.56 K at 10 wt%, while tetrabutylammonium hydroxide showed an induction time of 0.74 h at 1 wt% concentration.

     

Multifarious revolutionary aspects of microbial keratinases: an efficient green technology for future generation with prospective applications

Environmental Science and Pollution Research - Since the dawn of century, tons of keratin bio-waste is generated by the poultry industry annually, and they end up causing environmental havoc....     

Bioavailability and toxicity to rats of bound residues of 14C-pirimiphos-methyl in stored wheat.

Wheat grains were treated with 14C-pirimiphos-methyl to generate bound residues for testing their bioavailability to rats. Bound residues accounted for 25% of the applied dose (50 ppm) at the end of one year. When the grain bound residues were fed to rats for 48 hours the animals eliminated 30 and 40% of the administered dose in urine and feces respectively, after 5 days. Radioactivity in some selected organs and blood accounted for 37% of the administered dose after 2 days, which gradually declined to 1% after 5 days. These data indicate that wheat-bound pirimiphos-methyl residues are moderately bioavailable to rats. In a 90-day feeding study, inhibition of plasma cholinesterase and brain acetylcholinesterase strongly suggest that the bound residues possess a toxicological potential.     

An analysis between financial development,institutions, and the environment: a global view

Financial development is important for the growth of a country which indirectly affects the environment adversely through industrialization. However, in the presence of strong institutions, this adverse effect can be reduced. The main concern of the present study is to estimate the relation between CO₂ and financial development (FD) in the presence of economic institutions as an interactive term. A sample of 101 countries has been selected for econometric analysis for the period from 1995 to 2017. The cross-section dependence test statistics for dependency, CIPS and CADF for panel unit root test, Westerlund test to ascertain the long-run affiliations, and FMOLS to extract the long-run coefficients have been applied. Dumitrescu and Hurlin test is also employed to know about the causal nature of the panel series. The findings show that financial development has a positive relationship with CO₂. However, after inclusion of economic intuitions, the adverse impact of financial development on the environment is reduced. The study also confirms the presence of environmental Kuznets curve in the context of income and financial development. The findings imply that financial development can help to improve environment quality if it is accompanied with strong institutional framework such as assurance of property rights, government integrity, and liberalization in financial sector.

     

Removal of xylenol orange from its aqueous solution using SDS self-microemulsifying systems: optimization by Box–Behnken statistical design

The aim of present study was to develop and evaluate sodium dodecyl sulfate (SDS) self-microemulsifying systems (SMES) for the removal of an anionic dye xylenol orange (XO) from its bulk aqueous media via liquid–liquid adsorption. The composition of SDS SMES was optimized by Box–Behnken statistical design for the maximum removal of XO from its aqueous solution. Various SDS formulations were prepared by spontaneous emulsification method and characterized for thermodynamic stability, self-microemulsification efficiency, droplet size, and viscosity. Adsorption studies were conducted at 8, 16, and 24 h by mixing small amounts of SDS formulations with relatively large amounts of bulk aqueous solution of XO. Droplet size and viscosity of SDS formulations were significantly influenced by oil phase concentration (triacetin), while surfactant concentration had little impact on droplet size and viscosity. However, the percentage of removal of XO was influenced by triacetin concentration, surfactant concentration, and adsorption time. Based on lowest droplet size (35.97 nm), lowest viscosity (29.62 cp), and highest percentage of removal efficiency (89.77 %), formulation F₁₄, containing 2 % w/w of triacetin and 40 % w/w of surfactant mixture (20 % w/w of SDS and 20 % w/w of polyethylene glycol 400), was selected as an optimized formulation for the removal of XO from its bulk aqueous media after 16 h. These results indicated that SDS SMES could be suitable alternates of solid–liquid adsorption for the removal of toxic dyes such as XO from its aqueous solution through liquid–liquid adsorption.     

Building community resilience: can everyone enjoy a good life?

Initiatives to reduce community carbon emissions and foster sustainable lifestyles have had varying degrees of success. There is now a need for a re-energised, concerted and joined-up approach that places environmental issues in a wider context – one that improves quality of life while building community resilience. This involves enhancing the capacity of neighbourhoods to recover, respond and adapt to environmental and socio-economic changes. This paper examines the experience gained in a participatory action research (PAR) study to build community resilience, where facilitators supported residents to take ownership of their own agendas. The New Earswick Good Life Initiative (GLI) was an 18-month project undertaken in a low-income suburb of York (UK). A range of approaches were used to identify activities which had the most potential to nurture resilience and foster a shift towards greater environmental sustainability. The GLI highlighted how the introduction of new ideas not only need to be locally relevant but also requires care and time in order for them to embed within community. Altering the way a community manages its environment involves transforming social relationships, strengthening institutions and influencing local power balances. Furthermore, it is necessary to build social capital, knowledge, leadership skills and support social networks to allow communities to effectively engage with relevant local and national policies. Only by providing opportunities to develop these resilient attributes can increased local responsibility be successful. The paper concludes by providing guidance on strengthening community resilience and delivering pro-environmental behaviour change.     

Exploring the existence of aviation Kuznets curve in the context of environmental pollution for OECD nations

Environment, Development and Sustainability - Environmental degradation has put significant consequences at both the national and global levels. Economic development and ecological sustainability...     

Population and Environment： Necessary Transition Initiatives for Developing Countries

Now environment is an important topic in academic field. Many researches focus on the negative outcomes of nature which are being continually created by human and much attention has been paid to how the environment is protected through integrated research, movement and policy. But few studies are concentrated on population and environment and are to find out the interconnectivity and underlying mechanism that have an effect on people＇s preferring additional children and perception to environment. Many researchers claim that population growth is a great problem for environment but they do not provide the indepth integrated knowledge and mechanism that influence fertility trend and environmental problems. It is very crucial to develop practical and concrete initiatives to confirm a transition to reduce population growth and redirect the perception on population and environment.     

Air pollution and hospitalization in megacities: empirical evidence from Pakistan

Environmental Science and Pollution Research - Air pollution has become a threat to human health in urban settlements, ultimately leading to negative impacts on overall economic system as well....     

Breeding of Euterpina acutifrons,a harpacticid copepod,with special reference to dimorphic males

The breeding of Euterpina acutifrons, a marine harpacticid copepod, was studied both in the laboratory and in the natural population round Anglesey, England, with special reference to dimorphic males. As a result of successful rearing of the species under laboratory conditions, rates of development at different temperatures, and survival and maturation of all types of adults were studied. The dimorphic males developed faster than the females, and the small males had a shorter development time than the larger individuals. Laboratory observations clearly indicated that the males differ markedly in sexual behaviour, the small male being more potent, readily copulating with females, and always very active in breeding. In natural populations, temperature was found to have a limiting influence on the breeding period. Breeding began when the temperature reached 15° to 16°C, and ceased when it fell to 8°C. The most significant feature was the production of small males in nature; they increased in number with the onset of breeding, and always formed a high proportion of the actively breeding population. Both laboratory and field investigations have shown that the small male is a breeding form, and is apparently an adaptation of the species for carrying out successful breeding in the colder areas of its distribution.