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231.
Hot base digestion of fish meal and shrimps in combination with sodium borohydride reduction produces only trimethylarsine (TMA). This treatment produces TMA in different amounts relative to the total arsenic content which is mainly of organic structure. These materials of marine origin yielded 94% and 69% resp. of the calculated amount of TMA. Arsenobetaine and arsenocholine were degraded under identical conditions and were found to produce only TMA (95% and 8% resp.). Furthermore, studies using thin-layer chromatography, electrophoresis and ion-exchange chromatography have confirmed the existence of one organoarsenic compound in fish meal and two organoarsenicals in shrimps. The major organoarsenic compound in fish meal was identified as arsenobetaine by masspectroscopy. In shrimps about of the organoarsenic compounds was shown to be arsenobetaine and there is a strong indication for the presence of arsenocholine. 相似文献
232.
Critical load calculations in the Czech part of 'the Black Triangle' show exceedance of critical load in 75% of the forest area. A comparison with forest damage data shows an insignificant tendency toward more forest damage in areas with high exceedance. We conclude that high exceedance of critical load is a probable contributing factor to forest damage in the area. 相似文献
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Erwin M. Schau Harald Ellingsen Anders Endal Svein Aa. Aanondsen 《Journal of Cleaner Production》2009,17(3):325-334
Energy use is of great concern within fisheries, due to both associated environmental effects and the cost of fuel to fishermen. This article explores the scale of energy consumed by most segments of the Norwegian fishing fleet for gadoid fish and for parts of the pelagic fleet for the period 1980–2005. Fuel use is assigned to the different species caught and different fishing gears using economic and mass-based allocation, where data permit. Correlations between variations in energy use and changing catch rates, quotas and oil prices are found. Inverse correlations are found between fuel consumption per kilogram of fish and catch rates on a yearly basis and between fuel consumption and oil prices on a longer term basis. A long term trend towards increased fuel consumption and reduced real prices is observed from the mid 1980s until 2000. This may indicate that low fuel prices do not motivate the development of energy efficient technology in the long run. Increased fuel use may further be used as an indication of over fishing as the correlation between low catch rates and increased fuel consumption is rather strong. Possible means of reducing energy use and emissions are discussed including changing operational strategies, hull forms and the use of alternative energy carriers. A comparison with measures taken in connection with the previous oil crisis around 1980 is done. 相似文献
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Cecilia Akselsson Olle Westling Harald Sverdrup Johan Holmqvist Gunnar Thelin Eva Uggla Gunnar Malm 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):201-210
The effects of harvesting on the long-term mass balances of calcium (Ca), magnesium (Mg) and potassium (K) were evaluated
on a regional level in Sweden. A new high-resolution weathering database was used together with estimates of total deposition,
losses through harvest and leaching. Estimates were made for pine and spruce separately and for two harvesting intensity scenarios:
stem harvesting and whole-tree harvesting. The mass balance calculations showed net losses of Ca and Mg in almost the whole
country for both scenarios. The losses were smaller for pine than for spruce. The K balances were mainly positive for pine
but negative for spruce. Leaching was a main factor in the mass balances, especially for Ca and Mg. Whole-tree harvesting
in spruce forests led to substantially higher net losses of K and Ca than stem harvesting, according to the calculations.
In the whole-tree harvesting scenario in spruce forests the estimated yearly net losses of Ca, Mg and K corresponded to at
least 5%, 8% and 3% of the pools of exchangeable base cations, respectively, at 25% of the analysed sites. If losses of this
magnitude continue the depletion of the pools of Ca, Mg and K may lead to very low base saturation of the soils, possibly
accompanied by negative effects on soil fertility, runoff water quality, tree vitality and tree growth within a forest rotation
in parts of Sweden. Avoiding whole-tree harvesting can improve the situation substantially for K, but the losses of Ca and
Mg will still be significant. 相似文献
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A dynamic extraction system exploiting sequential injection (SI) for sequential extractions incorporating a specially designed extraction column is developed to fractionate radionuclides in environmental solid samples such as soils and sediments. The extraction column can contain up to 5 g of a soil sample, and under optimal operational conditions it does not give rise to creation of back pressure. Attention has been placed on studies of the readsorption problems during sequential extraction using a modified Standards, Measurements and Testing (SM&T) scheme with four-step sequential extractions. The degree of readsorption in dynamic and conventional batch extraction systems is compared and evaluated by using a double-spiking technique. A high degree of readsorption of plutonium and americium (>75%) was observed in both systems, and they also exhibited similar distribution patterns of the two radionuclides. However, the dynamic system is fully automated, eliminates manual separations, significantly reduces the operational time required, and offers detailed kinetic information. 相似文献