The Indian perspective of utilizing fly ash in phytoremediation, phytomanagement and biomass production

Coal-based power generation is a principal source of electricity in India and many other countries. About 15–30% of the total amount of residue generated during coal combustion is fly ash (FA). FA is generally alkaline in nature and contains many toxic metals like Cr, Pb, Hg, As and Cd along with many essential elements like S, B, Ca, Na, Fe, Zn, Mn and P. Dumped FA contaminates the biosphere by mobilization of its fine particles and hazardous metals. Despite the negative environmental impact of FA, coal continues to be a major source of power production in India and therefore FA disposal is a major environmental issue. To overcome this problem, FA dumping sites have been started as a potential resource for biomass production of tree species. Phytoremediation is a strategy that uses plants to degrade, stabilize, and remove contaminants from soils, water and waste FA. Phytomanagement of FA is based on the plants' root systems, high biomass, woody nature, native nature, and resistance to pH, salinity, and toxic metals. Recently Indian researchers mostly from the National Botanical Research Institute have been working on phytoremediation and revegetation of FA dykes, inoculation of bacterial strains for reducing FA stress and biomass production from FA dykes. Many international researchers have worked on reclamation, revegetation and utilization of FA. FA utilization saves resources, mainly land (topsoil), water, coal, limestone and chemical fertilizer. Safe utilization of FA is a major concern around the world and regulatory bodies are enforcing stringent rules for the proper management of FA. This article summarizes various viable avenues in India for FA utilization and environmental management.     

Pollution influences on atmospheric composition and chemistry at high northern latitudes: Boreal and California forest fire emissions

We analyze detailed atmospheric gas/aerosol composition data acquired during the 2008 NASA ARCTAS (Arctic Research of the Composition of the Troposphere from Aircraft and Satellites) airborne campaign performed at high northern latitudes in spring (ARCTAS-A) and summer (ARCTAS-B) and in California in summer (ARCTAS-CARB). Biomass burning influences were widespread throughout the ARCTAS campaign. MODIS data from 2000 to 2009 indicated that 2008 had the second largest fire counts over Siberia and a more normal Canadian boreal forest fire season. Near surface arctic air in spring contained strong anthropogenic signatures indicated by high sulfate. In both spring and summer most of the pollution plumes transported to the Arctic region were from Europe and Asia and were present in the mid to upper troposphere and contained a mix of forest fire and urban influences. The gas/aerosol composition of the high latitude troposphere was strongly perturbed at all altitudes in both spring and summer. The reactive nitrogen budget was balanced with PAN as the dominant component. Mean ozone concentrations in the high latitude troposphere were only minimally perturbed (<5 ppb), although many individual pollution plumes sampled in the mid to upper troposphere, and mixed with urban influences, contained elevated ozone (ΔO₃/ΔCO = 0.11 ± 0.09 v/v). Emission and optical characteristics of boreal and California wild fires were quantified and found to be broadly comparable. Greenhouse gas emission estimates derived from ARCTAS-CARB data for the South Coast Air Basin of California show good agreement with state inventories for CO₂ and N₂O but indicate substantially larger emissions of CH₄. Simulations by multiple models of transport and chemistry were found to be broadly consistent with observations with a tendency towards under prediction at high latitudes.     

Variations in single scattering albedo and Angstrom absorption exponent during different seasons at Delhi,India

Simultaneous measurements of aerosol absorption and scattering coefficients for the PM_2.5 aerosols particles were done at Delhi during April 2008–March 2009 to estimate the aerosol single scattering albedo (SSA) and the Angstrom absorption exponents at the surface. The annual average SSA at 0.55 μm was found to be 0.70 ± 0.07 with only slight variations during the four seasons, summer (0.63 ± 0.06), monsoon (0.69 ± 0.07), winter (0.74 ± 0.03) and spring (0.72 ± 0.04). However, large variations in average absorption and scattering coefficients were seen during these four seasons. The average absorption coefficients during summer, monsoon, winter and spring were found to be 62.47 ± 21.27, 50.95 ± 43.61, 189.65 ± 85.94 and 90.65 ± 33.06 Mm^?1 respectively. The corresponding scattering coefficients were 110.46 ± 36.15, 95.34 ± 49.46, 565.59 ± 274.59 and 236.56 ± 96.25 Mm^?1. The Angstrom absorption exponent (α_σ(abs)) remained close to unity throughout the year averaging at 1.02 ± 0.08, 1.02 ± 0.10, 1.04 ± 0.11, and 1.03 ± 0.05 during summer, monsoon, winter and spring seasons respectively, strongly indicating that the absorption at Delhi aerosol is mainly due to the abundance of black carbon of fossil fuel origin.     

Microwave synthesis,characterization, and bio-efficacy of novel halogenated Schiff bases

A new series of halogenated Schiff bases was synthesized by the condensation of 5-fluoro-2-hydroxy acetophenone and 3,5-dichloro-2-hydroxy acetophenone with different alkyl amines, namely propyl, pentyl, hexyl, heptyl, octyl, nonyl, dodecyl, tetradecyl, hexadecyl, and octadecyl amines, under microwave irradiation. Newly formed molecules were characterized by Infrared and nuclear magnetic resonance (¹H NMR and ¹³C NMR) spectroscopic techniques. Further, the Schiff bases were screened for antifungal bioassay, and the results showed potential fungicidal activity against two very important plant infecting fungi, viz. Rhizoctonia solani and Sclerotium rolfsii. Among the screened compounds, 2,4-dichloro-2-[1-(propylimino)ethyl]phenol was found to be the most active compound against both R. solani (ED₅₀ 8.02 mg L^?1) and S. rolfsii (ED₅₀ 21.51 mg L^?1) followed by 2,4-dichloro-2-[1-(pentylimino) ethyl]phenol (ED₅₀ 13.02 and 29.57 mg L^?1, respectively). The synthesized compounds were also screened for antioxidant activity by 2,2-diphenyl-1-picrylhydrazyl (DPPH)-free radical scavenging technique. All the compounds showed very low to moderate activity as compared with Gallic acid.     

Ecological Restoration of Coal Mine‐Degraded Lands in Dry Tropical Climate: What Has Been Done and What Needs to Be Done?

In developed countries, ecological restoration is a widely accepted practice to restore the productivity of degraded coal mine spoils and prevent mine‐degraded sites from acting as sources of pollution. During the past decade, ecologists realized the global need for ecological restoration, and the benefit of restoration is now assessed on the basis of ecosystem services that the restored lands can provide. In this article, the knowledge gap between crude reclamation and ecological restoration is examined, the steps crucial to ecological restoration in tropical conditions are identified, and simple guidelines are given for easy understanding. Restoration issues, such as modification of the forestry restoration approach, reestablishment of biodiversity, removal and reuse of topsoil during progressive and final stages of ecological restoration, drainage, promotion of a plant‐succession‐based approach, use of a grass–legume mixture as an initial colonizer, stabilization of steep slopes, and soil blanketing, are discussed. Those attributes of a degraded ecosystem that are responsible for the success of any restoration project are critically examined, and the opportunities provided by ecological restoration are explored.     

A review on optimization techniques for sizing of solar-wind hybrid energy systems

Solar and wind are inexhaustible, abundant, environmentally friendly and freely available renewable energy sources. Integration of these two sources has always been a complex optimization problem which requires efficient planning, designing and control strategies. Many researchers have designed cost effective and efficient hybrid solar-wind energy systems by using various available software tools and optimization algorithms. With the advancement in artificial intelligence methods, various new optimization techniques have been developed in the last few decades. This paper presents state of the art optimization methods applied to hybrid renewable based energy systems. A brief introduction of each technique is presented along with papers published in different reputed journals. This article also reviews different power management, control strategies and multi-objective optimization methods used for hybrid wind-solar systems. A case study is presented to demonstrate the efficacy of some of the algorithms.     

Conservation perceptions and attitudes of semi-nomadic pastoralist towards relocation and biodiversity management: a case study of <Emphasis Type="Italic">Van Gujjars</Emphasis> residing in and around Corbett Tiger Reserve,India

This article examines the perceptions and attitude of the semi-nomadic pastoral community “Van Gujjars” on the use and conservation of natural resources in Corbett Tiger Reserve, India. In this research article, in-depth interview and questionnaire data (n = 340) about demography and perceptions were examined from both qualitative and quantitative information. Respondents have expressed their perception about their own territories, problems, attachments, positive or negative change that occurred during their stay in and around protected area. Respondents overall positive attitudes towards conservation scenarios despite high losses from wildlife while living around protected area suggest that they may support conservation if their livelihood needs are met. Most of the respondents support the concept of conservation, and some respondents have negative attitude towards management authorities, mainly because of restricted access to the forest resources. The study illustrates and suggests a number of options for the viability of resettlement of pastoralist community. A majority of respondents indicated that there is a need for public participation in planning and implementation of resettlement process. Resettlement of Van Gujjar community may be better if exercised with the consensus of all the stakeholders. Resettlement will provide better livelihood opportunity to the pastoral community and enhance the economic status of these people as the educational level increases in time, while also improving habitat recovery leading to better biodiversity conservation. Thus, resettlements could benefit both the pastoral people and the natural resources.     

Eco-friendly PEG-based controlled release nano-formulations of Mancozeb: Synthesis and bioefficacy evaluation against phytopathogenic fungi Alternaria solani and Sclerotium rolfsii

Controlled release (CR) nano-formulations of Mancozeb (manganese-zinc double salt of N,N-bisdithiocarbamic acid), a protective fungicide, have been prepared using laboratory-synthesized poly(ethylene glycols) (PEGs)-based functionalized amphiphilic copolymers without using any surfactants or external additives. The release kinetics of the developed Mancozeb CR formulations were studied and compared with that of commercially available 42% suspension concentrate and 75% wettable powder. Maximum amount of Mancozeb was released on 42nd day for PEG-600 and octyl chain, PEG-1000 and octyl chain, and PEG-600 and hexadecyl chain, on 35th day for PEG-1000 and hexadecyl chain, on 28th day for PEG-1500 and octyl chain, PEG-2000 and octyl chain, PEG-1500 and hexadecyl chain, and PEG-2000 and hexadecyl chain in comparison to both commercial formulations (15th day). The diffusion exponent (n value) of Mancozeb in water ranged from 0.42 to 0.62 in tested formulations. The half-release (t_1/2) values ranged from 17.35 to 35.14 days, and the period of optimum availability of Mancozeb ranged from 18.54 to 35.42 days. Further, the in vitro bioefficacy evaluation of developed formulations was done against plant pathogenic fungi Alternaria solani and Sclerotium rolfsii by poison food technique. Effective dose for 50% inhibition in mgL^?1 (ED₅₀) values of developed formulations varied from 1.31 to 2.79 mg L^?1 for A. solani, and 1.60 to 3.14 mg L^?1 for S. rolfsii. The present methodology is simple, economical, and eco-friendly for the development of environment-friendly CR formulations of Mancozeb. These formulations can be used to optimize the release of Mancozeb to achieve disease control for the desired period depending upon the matrix of the polymer used. Importantly, the maximum amount of active ingredient remains available for a reasonable period after application. In addition, the developed CR formulations were found to be suitable for fungicidal applications, allowing use of Mancozeb in lower doses.     

Estimation of β-cyfluthrin and imidacloprid in okra fruits and soil by chromatography techniques

Dissipation of β-cyfluthrin and imidacloprid in okra was studied following three applications of a combination formulation of Solomon 300 OD (β-cyfluthrin 9 % + imidacloprid 21 %) @ 60 and 120 g a.i. ha(-1) at 7 days interval. Residues of β-cyfluthrin and imidacloprid in okra were estimated by gas liquid chromatography (GLC) and high performance liquid chromatography (HPLC), respectively. Residues of β-cyfluthrin were confirmed by gas chromatograph-mass spectrometry (GC-MS) and that of imidacloprid by high performance thin layer chromatography (HPTLC). Half-life periods for β-cyfluthrin were found to be 0.91 and 0.68 days whereas for imidacloprid these values were observed to be 0.85 and 0.96 days at single and double the application rates, respectively. Residues of β-cyfluthrin dissipated below its limit of quantification (LOQ) of 0.01 mg kg(-1) after 3 and 5 days at single and double the application dosage, respectively. Similarly, residues of imidacloprid took 5 and 7 days to reach LOQ of 0.01 mg kg(-1), at single and double dosages respectively. Soil samples collected after 15 days of the last application did not show the presence of β-cyfluthrin and imidacloprid at their detection limit of 0.01 mg kg(-1).     

Effect of fly ash on sorption behavior of metribuzin in agricultural soils

This investigation was undertaken to determine the effect of two different fly ashes [Kota and Inderprastha (IP)] amendment on the sorption behavior of metribuzin in three Indian soil types. The IP fly ash was very effective in increasing the metribuzin sorption in the soils. The sorption with IP amendment was increased by 15-92%, whereas with the Kota fly ash an increase in sorption by 13-38% was noted. The adsorption isotherms fitted very well to the Freundlich adsorption equation and, in general, slope (1/n) values less then unity were observed. Although both the fly ashes significantly decreased metribuzin desorption, the IP fly ash was comparatively more effective in retaining metribuzin in the soils. Metribuzin sorption in the IP fly ash-amended soils showed strong correlation with the fly ash content and compared to K(f)/K(d) values, K(FA) values (sorption normalized to fly ash content) showed less variation. Metribuzin sorption-desorption did not correlate to the organic carbon content of the soil-fly ash mixture. The study demonstrates that all coal fly ashes may not be effective in enhancing the sorption of metribuzin in soils to the same extent. However, among the fly ashes used in this study, the IP fly ash was observed to be significantly effective in enhancing the sorption of metribuzin in soils. This may play an important role in reducing the run off and leaching losses of the herbicide by retaining it in the soil.