Dissipation and runoff transport of metazachlor herbicide in rapeseed cultivated and uncultivated plots in field conditions

The environmental fate of metazachlor herbicide was investigated under field conditions in rapeseed cultivated and uncultivated plots, over a period of 225 days. The cultivation was carried out in silty clay soil plots with two surface slopes, 1 and 5 %. The herbicide was detectable in soil up to 170 days after application (DAA), while the dissipation rate was best described by first-order kinetics and its half-life ranged between 10.92 and 12.68 days. The herbicide was detected in the soil layer of 10–20 cm from 5 to 48 DAA, and its vertical movement can be described by the continuous stirred tank reactor (CSTR) in series model. Relatively low amounts of metazachlor (less than 0.31 % of the initial applied active ingredient) were transferred by runoff water. More than 80 % of the total losses were transferred at the first runoff event (12 DAA), with herbicide concentrations in runoff water ranging between 70.14 and 79.67 μg L⁻¹. Minor amounts of the herbicide (less than 0.07 % of the initial applied active ingredient) were transferred by the sediment, with a maximum concentration of 0.57 μg g⁻¹ (12 DAA), in plots with 5 % inclination. Finally, in rapeseed plants, metazachlor was detected only in the first sampling (28 DAA) at concentrations slightly higher than the limit of quantification; when in seeds, no residues of the herbicide were detected.

     

Using Various Guidelines and Approaches for the Assessment of Marine Sediment Quality

The aim of the present study is to explore the implications of using different quality guidelines and approaches for marine sediment characterization. As a case study, the sediments of Souda Port, Crete, Greece, were examined in order to assess heavy metal contamination and to estimate anthropogenic contribution and potential adverse effects to aquatic environment, as well as to indicate feasible future management options. The concentration of six heavy metals (Co, Cr, Cu, Ni, Pb, and Zn) was determined and compared with different sediment quality guidelines (SQGs) and regional/national criteria established for dredged material characterization and management. In addition, the geo-accumulation index (I_geo) was calculated and the sediments toxicity and heavy metals bioavailability were determined. Based on the experimental data, it is deduced that Souda sediments are characterized as moderately polluted only in terms of Co, Ni, and Pb.     

Tire tread wear particles in ambient air—a previously unknown source of human exposure to the biocide 2-mercaptobenzothiazole

Urban particulate matter (PM), asphalt, and tire samples were investigated for their content of benzothiazole and benzothiazole derivates. The purpose of this study was to examine whether wear particles, i.e., tire tread wear or road surface wear, could contribute to atmospheric concentrations of benzothiazole derivatives. Airborne particulate matter (PM₁₀) sampled at a busy street in Stockholm, Sweden, contained on average 17 pg/m³ benzothiazole and 64 pg/m³ 2-mercaptobenzothiazole, and the total suspended particulate-associated benzothiazole and 2-mercaptobenzothiazole concentrations were 199 and 591 pg/m³, respectively. This indicates that tire tread wear may be a major source of these benzothiazoles to urban air PM in Stockholm. Furthermore, 2-mercaptobenzothiazole was determined in urban air particulates for the first time in this study, and its presence in inhalable PM₁₀ implies that the human exposure to this biocide is underestimated. This calls for a revision of the risk assessments of 2-mercaptobenzothiazole exposure to humans which currently is limited to occupational exposure.     

Improving anaerobic sewage sludge digestion by implementation of a hyper-thermophilic prehydrolysis step

The present study focuses on a two-step process for treatment and stabilisation of primary sludge. The process consists of a hyper-thermophilic hydrolysis step operated at 70 degrees C and a hydraulic retention time (HRT) of 2 days followed by a thermophilic (55 degrees C) anaerobic digestion step at a HRT of 13 days. A one-step anaerobic digester operated at 55 degrees C and 15 days HRT was used as a reference process. The two-step process was characterized by a 12% higher organic suspended solids removal efficiency and better pathogen reduction effect than the conventional one-step digestion. The microbial community of the digester fed with pre-treated sludge was characterised by a higher activity compared to that of the digester treating raw sludge. Moreover, the pre-treatment of the primary sludge resulted up to 48% increase of the methane potential (20.09 and 13.56mmolCH(4)g(-)VS(-1) with and without pre-treatment, respectively) and up to 115% increase of the methane production rate. Finally it was shown that the extra energy requirements for the operation of a pre-treatment step would be covered by the energy produced from the extra methane production and in addition there would be a significant energy surplus of 2.17kJd(-1) for the system tested.     

Mapping fire behaviour under changing climate in a Mediterranean landscape in Greece

Understanding how future climate periods influence fire behaviour is important for organizing fire suppression strategy and management. The meteorological factors are the most critical parameters affecting fire behaviour in natural landscapes; hence, predicting climate change effects on fire behaviour could be an option for optimizing firefighting resource management. In this study, we assessed climate change impacts on fire behaviour parameters (rate of fire growth, rate of spread and fireline intensity) for a typical Mediterranean landscape of Greece. We applied the minimum travel time fire simulation algorithm by using the FlamMap software to characterize potential response of fire behaviour for three summer periods. The results consisted of simulated spatially explicit fire behaviour parameters of the present climate (2000) and three future summer periods of 2050, 2070 and 2100, under the A1B emissions scenario. Statistical significant differences in simulation outputs among the four examined periods were obtained by using the Tukey’s significance test. Statistical significant differences were mainly obtained for 2100 compared to the present climate due to the significant projected increase in the wind speed by the end of the century. The analysis and the conclusions of the study can be important inputs for fire suppression strategy and fire management (deployment of fire suppression resources, firefighter safety and exposure, transportation logistics) quantifying the effect that the expected future climate periods can have on fire suppression difficulty in Mediterranean landscapes.     

Arsenate removal from drinking water using by-products from conventional iron oxyhydroxides production as adsorbents coupled with submerged microfiltration unit

Environmental Science and Pollution Research - Arsenic is among the major drinking water contaminants affecting populations in many countries because it causes serious health problems on long-term...     

Biogas upgrading to methane and removal of volatile organic compounds in a system of zero-valent iron and anaerobic granular sludge

Environmental Science and Pollution Research - The current study presented a novel process of biogas upgrading to biomethane (higher than 97%) based on anaerobic sludge and zero-valent iron (ZVI)...