Relative accuracy testing of an X-ray fluorescence-based mercury monitor at coal-fired boilers

The relative accuracy (RA) of a newly developed mercury continuous emissions monitor, based on X-ray fluorescence, was determined by comparing analysis results at coal-fired plants with two certified reference methods (American Society for Testing and Materials [ASTM] Method D6784-02 and U.S. Environment Protection Agency [EPA] Method 29). During the first determination, the monitor had an RA of 25% compared with ASTM Method D6784-02 (Ontario Hydro Method). However, the Ontario Hydro Method performed poorly, because the mercury concentrations were near the detection limit of the reference method. The mercury in this exhaust stream was primarily elemental. The second test was performed at a U.S. Army boiler against EPA Reference Method 29. Mercury and arsenic were spiked because of expected low mercury concentrations. The monitor had an RA of 16% for arsenic and 17% for mercury, meeting RA requirements of EPA Performance Specification 12a. The results suggest that the sampling stream contained significant percentages of both elemental and oxidized mercury. The monitor was successful at measuring total mercury in particulate and vapor forms.     

Migrant land rights reception and 'clearing to claim' in sub-Saharan Africa: A deforestation example from southern Zambia

The relationship between migration and deforestation in the developing world continues to receive significant attention. However beyond direct population increase, the precise mechanisms that operate within the intersection of migrant/host land rights remain largely unexamined. Where migrants are provided with land and rights by the State and/or local communities, how such rights are perceived by the migrants is of primary importance in their interaction with land resources, and in aggregate it impacts the development opportunities and environmental repercussions of migration. The authors analyze the operative aspects of land rights reception (as opposed to provision) by migrant populations, and the relationship between this reception and deforestation. The article examines a case in Zambia to analyze how tenurial constructs, emerging from the way rights are perceived by migrants, lead to the continued clearing of areas much larger than needed for cultivation, even when the arrangement appears counter‐productive in terms of land rights provision and labour allocation. While valuable policy efforts have focused on providing resource rights to migrants, how such rights are received and the relationship of this reception to resource management needs greater policy attention.     

INTEGRATING A GEOGRAPHIC INFORMATION SYSTEM,A SCIENTIFIC VISUALIZATION SYSTEM,AND A PRECIPITATION MODEL1

ABSTRACT: Investigating natural, potential, and human-induced impacts on hydrologic systems commonly requires complex modeling with overlapping data requirements, plus massive amounts of one- to four-dimensional data at multiple scales and formats. Given the complexity of most hydrologic studies, the requisite software infrastructure must incorporate many components including simulation modeling and spatial analysis with a flexible, intuitive display. Integrating geographic information systems (GIS) and scientific visualization systems (SVS) provides such an infrastructure. This paper describes an integrated system consisting of an orographic precipitation model, a GIS, and an SVS. The results of this study provide a basis for improving the understanding of hydro-climatic processes in mountainous regions. An additional benefit of the integrated system, the value of which is often underestimated, is the improved ability to communicate model results, leading to a broader understanding of the model assumptions, sensitivities, and conclusions at a management level.     

Seaweed secondary metabolites as antifoulants: effects of Dictyota spp. diterpenes on survivorship, settlement, and development of marine invertebrate larvae

Summary. A recent investigation showed that the brown seaweed Dictyota menstrualis was unfouled relative to co-occurring seaweeds, and that larvae of fouling invertebrates avoided settling on D. menstrualis due to chemicals on its surface. The secondary metabolites dictyol E and pachydictyol A are among the compounds found on this alga's surface. In the present study, we tested the effects of specific diterpenes from Dictyota on the survivorship, growth, and development of invertebrate larvae and developing juveniles that could foul seaweeds. Exposure to dictyol E, dictyol B acetate, pachydictyol A, and dictyodial from Dictyota menstrualis and D. ciliolata caused significant larval mortality, abnormal development, and reduce growth rates for three species of co-occurring invertebrates when their larvae were forced into contact with these metabolites. Larvae were damaged at metabolite concentrations as low as 5% of maximum possible surface concentrations of these compounds for the populations of Dictyota we studied. The negative effects of these secondary metabolites on potential foulers, in conjunction with data demonstrating larval avoidance of dictyol-covered surfaces, suggest that these compounds could function as chemical defenses against fouling, and could select for larvae that avoid hosts producing these metabolites. Received 25 May 1998; accepted 22 June 1998.     

Amniotic fluid enzymes in pregnancies with trisomy 21

The activities of a range of microvillous enzymes in amniotic fluid from normal pregnancies (n = 213) and those complicated by trisomy 21 (n = 26) were compared in a prospective study. Using a centrifugal analyser, the activities of leucine aminopeptidase (LAP), gamma glutamyl transferase (GGT), aspartate transferase (AST), and isoenzymes of alkaline phosphate (ALP) were measured in amniotic fluid alongside alpha fetoprotein (AFP) levels. Of the markers studied, LAP was found to be the most reliable indicator of trisomy 21. Using levels below the 5th percentile, LAP showed sensitivity 73 per cent, specificity 94 per cent, and predictive value positive 63 percent. Although these tests would not replace karyotyping in all cases, the measurement of LAP could be useful as a rapid initial screening test, particularly when amniocentesis is performed for indications other than chromosomal abnormalities.     

Multispecies and Multiscale Conservation Planning: Setting Quantitative Targets for Red‐Listed Lichens on Ancient Oaks

Abstract: Species occurrence in a habitat patch depends on local habitat and the amount of that habitat in the wider landscape. We used predictions from empirical landscape studies to set quantitative conservation criteria and targets in a multispecies and multiscale conservation planning effort. We used regression analyses to compare species richness and occurrence of five red‐listed lichens on 50 ancient oaks (Quercus robur; 120–140 cm in diameter) with the density of ancient oaks in circles of varying radius from each individual oak. Species richness and the occurrence of three of the five species were best explained by increasing density of oaks within 0.5 km; one species was best explained by the density of oaks within 2 km, and another was best predicted by the density of oaks within 5 km. The minimum numbers of ancient oaks required for “successful conservation” was defined as the number of oaks required to obtain a predicted local occurrence of 50% for all species included or a predicted local occurrence of 80% for all species included. These numbers of oaks were calculated for two relevant landscape scales (1 km² and 13 km²) that corresponded to various species responses, in such a way that calculations also accounted for local number of oaks. Ten and seven of the 50 ancient oaks surveyed were situated in landscapes that already fulfilled criteria for successful conservation when the 50% and 80% criteria, respectively, were used to define the level of successful conservation. For cost‐efficient conservation, oak stands in the landscapes most suitable for successful conservation should be prioritized for conservation and management (e.g., grazing and planting of new oaks) at the expense of oak stands situated elsewhere.     

Vulnerability, Risk and Adaptation Assessment Methods in the Pacific Islands Region: past approaches, and considerations for the future

Over two decades of vulnerability assessments have shown the Pacific Islands region to be one of the regions most at risk to the adverse consequences of climate change. Pacific Island countries have shown strong leadership in characterising the challenges of climate change, both nationally and for the region as a whole, and in identifying the most appropriate responses. This paper reviews the various Vulnerability, Risk and Adaptation (VRiA) Assessment Methods and Tools that have been used across the Pacific Islands region, with an emphasis on the past two decades. The aim is to identify the approaches that are best suited to the region, and to develop a common understanding and principles that may be relevant and useful to harmonising the assessment of vulnerability and risk, and of adaptation options across the region. Even though assessments undertaken in the Pacific Islands region tend to share the common objective of reducing vulnerabilities and risks, practitioners in the Pacific are using numerous approaches, methods and tools to assess vulnerabilities and identify possible adaptation interventions. No one approach will address all needs and accommodate all capacities. Rather, several successful approaches, methods and tools are identified. The paper also identifies and assesses the approaches, methods and tools that have merit for further use, without or with further improvements. Lessons learned as well as success stories and success factors are documented. These findings are reflected in principles designed to assist harmonisation of approaches to VRiA assessment. These principles, in turn, influence the development of a proposed higher-level framework and approach for VRiA assessments. It accommodates the various approaches, methods and tools commonly used with success in the Pacific.