Die Organisation des betrieblichen Umweltschutzes durch ein effizientes Umweltmanagementsystem

Betrieblicher Umweltschutz gilt heute als unverzichtbarer Bestandteil moderner Unternehmensführung. Im Gegensatz zu „end of pipe”-Technologien als kostentreibende Ma?nahmen wird der integrierte Umweltschutz, von der Technologie über das Managementsystem bis hin zum Mitarbeiter zunehmend zu einem betriebswirtschaftlichen Erfolgsfaktor. Notwendige Voraussetzung für diesen Erfolg ist ein gut strukturiertes Umweltmanagementsystem (UM-System). Das beschriebene UM-System orientiert sich an der EG-Verordnung über die „Freiwillige Beteiligung gewerblicher Unternehmen an einem Gemeinschaftssystem für das Umweltmanagement und die Umweltbetriebsprüfung”. Da sowohl auf nationaler als auch auf internationaler Ebene sehr intensiv an einer Normierung von Umweltmanagementsystemen gearbeitet wird, bringt diese Arbeit einen Vergleich zum ISO-Entwurf für UM-Systeme.     

Sorption behavior of a new acidic herbicide in soils

The sorptive behavior of the experimental herbicide quinmerac (7-chloro-3-methyl-quinoline-8-carboxylic acid) was investigated in soils of different organic carbon content. Distribution coefficients are low (K_d = 0.03 - 12 mL g⁻¹) and are mainly determined by the soil organic carbon content. The adsorption mechanism operating in neutral to slightly acid agricultural soils is supposed to be cation bridging with the anionic form of quinmerac. Under acid conditions (pH 5.2) the predominating sorption mechanism is hydrophobic interaction. Therefore soil pH and cationic composition are also major factors determining the sorptive capacity of soils for quinmerac.

Adsorption kinetics, equilibrium adsorption and desorption isotherms were determined in batch experiments. Sorption kinetics were investigated at various times from 15 min to 96 hours. A two-step sorption behavior with time was found for the anionic form indicating two types of sorption mechanisms or sorption sites. Equilibrium for the first type was reached at a time-scale of minutes and for the second type after 24 hours. Adsorption isotherms were determined for two soil/solution ratios 1/5 and 1/3. Alteration of the adsorbent concentration exerted a strong influence on the adsorption isotherms. An increase of sorption was found with increasing adsorbent concentration. Under natural soil conditions sorption is therefore expected to be higher compared to the batch experiments. Desorption isotherms were obtained using the consecutive desorption method. Desorption hysteresis was not observed which indicates weak interactions. Implications of the results for the movement of quinmerac under field conditions and for models describing transport are discussed.     

Educational initiative of Osaka University in sustainability science: mobilizing science and technology towards sustainability

One of the most important and yet difficult challenges that modern societies face is how to mobilize science and technology (S&T) to minimize the impact of human activities on the Earth’s life support systems. As the establishment of inter-disciplinary education programs is necessary to design a unified vision towards understanding the complexity of human nature, the Research Institute for Sustainability Science (RISS) launched a new program on sustainability science in April 2008. The program expects to address the issue of how to use knowledge more effectively to understand the dynamic interactions between nature and human society. This paper first offers an overview of international and Japanese initiatives on sustainability education in which we highlight the uniqueness of the attempt by the Integrated Research System for Sustainability Science (IR3S). The paper then introduces the RISS program for sustainability science, addressing the principles and curriculum design of the program. The paper discusses the main problems and constraints faced when developing the program, such as institutional barriers in building a curriculum and obtaining cooperation from faculty. To challenge these barriers and limitations, the RISS uses the program as a platform to disseminate the idea of sustainability science across the university. This attempt helps us to obtain the continuing cooperation necessary to improve and maintain the program.

Assessment of plasma gasification of high caloric waste streams

Plasma gasification is an innovative technology for transforming high calorific waste streams into a valuable synthesis gas and a vitrified slag by means of a thermal plasma. A test program has been set up to evaluate the feasibility of plasma gasification and the impact of this process on the environment. RDF (refuse derived fuel) from carpet and textile waste was selected as feed material for semi-pilot gasification tests. The aim of the tests was: (1) to evaluate the technical feasibility of making a stable synthesis gas; (2) to characterize the composition of this synthesis gas; (3) to define a suitable after-treatment configuration for purification of the syngas and (4) to characterize the stability of the slag, i.e., its resistance to leaching for use as a secondary building material. The tests illustrate that plasma gasification can result in a suitable syngas quality and a slag, characterized by an acceptable leachability. Based on the test results, a further scale-up of this technology will be prepared and validation tests run.     

Novelty Detection – Recognition and Evaluation of Exceptional Water Reflectance Spectra

The aim of environmental surveillance is to monitor known phenomena as well as to detect exceptional situations. Synoptic monitoring of large areas in coastal waters can be performed by remote sensing using multispectral sensors onboard satellites. Many methods are in use which enable the detection and quantification of ‘standard algae’ or specific algae blooms using their known spectral response. The present study focusses on the detection of spectra outside the known range and which are referred to as exceptional spectra. In a first step observations from a one-year period were used to establish the parameterisation of what is defined as ‘normal.’ In a second step observations from a different period were used to test the novelty detection application, i.e. to look for features not occurring in the first period.      

Monitoring Pollution in River MureŞ, Romania, Part III: biochemical effect markers in fish and integrative reflection

Along a downstream stretch of River Mureş, Romania, adult males of two feral fish species, European chub (Leuciscus cephalus) and sneep (Chondrostoma nasus) were sampled at four sites with different levels of contamination. Fish were analysed for the biochemical markers hsp70 (in liver and gills) and hepatic EROD activity, as well as several biometrical parameters (age, length, wet weight, condition factor). None of the biochemical markers correlated with any biometrical parameter, thus biomarker reactions were related to site-specific criteria. While the hepatic hsp70 level did not differ among the sites, significant elevation of the hsp70 level in the gills revealed proteotoxic damage in chub at the most upstream site, where we recorded the highest heavy metal contamination of the investigated stretch, and in both chub and sneep at the site right downstream of the city of Arad. In both species, significantly elevated hepatic EROD activity downstream of Arad indicated that fish from these sites are also exposed to organic chemicals. The results were indicative of impaired fish health at least at three of the four investigated sites. The approach to relate biomarker responses to analytical data on pollution was shown to fit well the recent EU demands on further enhanced efforts in the monitoring of Romanian water quality.