Where artisanal mines and forest meet: Socio‐economic and environmental impacts in the Congo Basin

While mineral exploitation can provide significant income and employment, it may negatively impact the environment, being ultimately detrimental to livelihoods in the long term. The consequences of mining are of concern in high value forest ecosystems such as the Sangha Tri‐National (TNS) landscape covering Cameroon, the Central African Republic and Republic of the Congo. This paper captures the socio‐economic and environmental impacts of small‐scale mining in the TNS. Using structured questionnaires, consultations and observation, diamonds and gold were found to contribute directly to the livelihoods of at least 5% of the landscape's population. Although up to eight income‐generating strategies are used, mining contributes on average to 65% of total income and is used mainly to meet basic needs. A gold miner's average income is US$ 3.10 a day, and a diamond miner earns US$ 3.08, making them slightly wealthier than an average Cameroonian and three times wealthier than an average non‐miner in the TNS. Environmental impacts were temporary, low impact and of limited scale. However, with mining likely to increase in the near future, an increasing population and miners' low environmental awareness, measures are needed to ensure and reinforce the positive impact of artisanal mining on livelihoods and maintain its low environmental footprint in the TNS landscape.     

A recent overview of the effect of road surface properties on road safety,environment, and how to monitor them

Environmental Science and Pollution Research - Road pavements are exposed to traffic loading and external deterioration agents which both can compromise tire-pavement interactions, posing a threat...     

Extractable soil lipids and microbial activity as affected by Bt and non Bt maize grown on a silty clay loam soil

Pyrolysis-gas (Py-GC) chromatography was used to characterize extractable lipids from Bt and non-Bt maize shoots and soils collected at time of harvesting. Py-GC-MS (mass spectrometry) showed that the concentrations of total alkenes identified in non-Bt shoots and soils were 47.9 and 21.3% higher than in Bt maize shoots and soils, respectively. N-alkanes identified were of similar orders of magnitude in Bt and non-Bt maize shoots, but were 28.6% higher in Bt than in non-Bt soils. Bt maize shoots contained 29.7% more n-fatty acids than non-Bt maize shoots, whereas the concentrations of n-fatty acids in Bt soils were twice as high as those in non-Bt soils. Concentrations of unsaturated fatty acids in Bt maize shoots were 22.1% higher than those in non-Bt maize shoots, while concentrations of unsaturated fatty acids were 22.5% higher in non-Bt than in Bt soils. The cumulative CO2-C evolved from soils under Bt and non-Bt crops was 30.5% lower under Bt as compared to non-Bt crops, whereas when maize shoots were added to Bt and non-Bt soils, the decrease in CO2-C evolved were 16.5 and 23.6%, respectively. Our data showed that the cultivation of Bt maize significantly increased the saturated to unsaturated lipid ratios in soils which appeared to negatively affect microbial activity.     

An experimental set up of a PAH vapour generator and its use to test an annular denuder

The aim of this work is to develop and test a dynamic gas generator for semi-volatile organic compounds (SVOC). A single compound, naphthalene, is used as a surrogate PAH to test the system. The dynamic generation of PAH is based on the permeation technique [Analyst 106 (1981) 817; Am. Ind. Hyg. Assoc. J. 38 (1977) 712]. Monitoring the temperature and measuring the mass of PAH present in the permeation chamber every 48 h gives a direct measurement of the sublimation rate of the PAH. Knowing the flow rate, gives an accurate value of the concentration of PAH from the generator. It was found stable over a period of time under constant operating conditions. This concentration is diluted down to between 0.3 and 30 ppbv by a controlled flow of pure air. The diluting airflow is a mixture of dry and wet air, making it possible to control the relative humidity of the flow from the generator as well as its concentration in PAH. We used this generator to calibrate an annular denuder tube, based on the study by Gundel et al. [Atmos. Environ. 29 (1995) 1719]. Although this technique has been shown to be artefact-free for sampling gaseous PAH [Polycyclic Aromatic Compounds 9 (1996) 67; Atmos. Environ. 28 (1994) 3083], its trapping efficiency still depends on environmental parameters (temperature, relative humidity and sampling duration). Accordingly, we used our generator to calibrate a single annular denuder under controlled conditions (T degrees C, HR%, CPAH, sampling duration). The trapping efficiency of the denuder was calculated by two independent methods. Firstly, by comparing the amount trapped on a denuder with the measured mass sublimated in the generator. Secondly, by putting two denuders in series and comparing the mass collected on the first and the second tube. These two methods gave similar results, within the 10% relative uncertainties of both methods. The first results obtained show that, in environmental conditions, the efficiency ranges between 90 and 100%.     

Free energy flow in the process of collecting material for body build up of aquatic organisms

A general formula defining the free energy expenditures in the processes of algal nutrition and zooplankton feeding has been derived. It appears to be symmetrical in respect of space and time scales. In conditions of optimal control the theoretical relationship between effective free energy expenditures and losses appears to be the ‘golden proportion’. The general trends of the system due to the first and second laws of thermodynamics and Prigogine's theorem form a theoretical basis for phenomenological rules of ecosystem's development.     

Separation and measurement of thorium, plutonium, americium, uranium and strontium in environmental matrices

A technique for the isolation of thorium (Th), plutonium (Pu), americium (Am), uranium (U) and strontium (Sr) isotopes from various environmental matrices has been adapted from a previously published method specific to water samples (Maxwell, 2006). Separation and isolation of the various elemental fractions from a single sub-sample is possible, thereby eliminating the need for multiple analyses.The technique involves sample dissolution, concentration via calcium phosphate co-precipitation, rapid column extraction using TEVA™, TRU™ and Sr-Spec™ resin cartridges, alpha spectrometry for Th, Pu, U and Am and Cerenkov counting for Sr.Various standard reference materials were analysed and chemical yields are in the range of 70-80% for Th, Am, U and Sr and 50-60% for Pu. Sample sizes of up to 10 L for water, 5 g for dry soil and sediment and 10 g for dry vegetation and seaweed can be processed using this technique.     

Heterogeneous light-induced ozone processing on the organic coatings in the atmosphere

Many of the more recent studies concerning heterogeneous reactions of atmospheric interest, carry, in some cases, much more details but still follow the basic philosophy of the first pioneering studies. Therefore, in this study the accent is put on the additional complexities that arise when the aerosols of interest have more complex compositions. Hence, it is attempted to identify the products following the simultaneous ozone processing and light irradiation on particles coated with 4-phenoxyphenol in the presence of 4-carboxybenzophenone as a photosensitizer. In order to reveal a more complete picture on the fate of these aromatic compounds under controlled experimental conditions, different analytical tools such as gas chromatography coupled to mass spectrometry (GC–MS) and proton transfer reaction-mass spectrometry (PTR-MS) have been applied.Several surface bound products were identified via GC–MS and some of them (phenol, hydroquinone, catechol, 4-hydroxybenzoic acid, benzoic acid, fumaric acid, terephthalic acid, maleic acid, 1,2,4-trihydroxybenzene and 4,4′-oxydiphenol) confirmed with standards. The main volatile secondary products as identified by PTR-MS in this study were formic acid, phenol and p-benzoquinone.A reaction mechanism was proposed and density functional theory calculations were performed in order to elucidate the initial steps of the ozonolysis reaction on 4-phenoxyphenol in the presence of 4-carboxybenzophenone.     

Lake Borullus of the Nile Delta: a short history and an uncertain future

Borullus, the most centrally situated of the Nile Delta lakes, probably evolved around the eighth century AD from a preexisting salt marsh by fluviatile deposition of sand dunes north of the lake and subsidence of the preexisting tidal swamp behind this barrier. It was flooded yearly (September-December) by the Sebennytic branch of the Nile, and evacuated water through an exit, Bughaz. At low river levels, this process reversed and Bughaz functioned as a marine inlet. Because of this switch, its fauna and flora contained a mix of marine, freshwater, and brackish-water species. Around the mid-nineteenth century, damming of the Nile began, culminating with the high Aswan Dam (1964) that brought the yearly flood fully under control. As a result, a steady flow of Nile water, used for irrigated delta agriculture, began to drain to the lake and became a constant evacuator to the Mediterranean. It turned almost fresh, and its fishery, formerly marine and mullet-based, became cichlid-catfish based. However, rice and other new delta crops caused huge amounts of nutrients to wash down the drains, and currently the lake is eutrophied and only resists hypertrophication because of the low residence time of its water. Finally, the damming of the Nile terminated the influx to the delta of a yearly sediment layer, but subsidence and coastal erosion continue and are now consuming the sand bar that separates the lake from the sea.     

Habitat use of a multispecific seagrass meadow by green turtles Chelonia mydas at Mayotte Island

We investigated the habitat use in green turtles exploiting a 13-ha multispecific seagrass meadow at Mayotte Island, south-western Indian Ocean. A phyto-ecological survey shows the occurrence of eight seagrass species, dominated by Halodule uninervis and Syringodium isoetifolium, distributed according to four distinct seagrass communities along the depth gradient. Direct underwater censuses show that green turtles occurred all over the meadow. Yet when community relative surface area was taken into account green turtles preferentially frequented the most seaward, biomass-richer S. isoetifolium-dominated community, suggesting that green turtles compensate for their intrinsically nutrient-poor herbivorous diet. Additionally, smaller (<80 cm standard curved carapace length, SCCL) individuals also preferentially occurred in the most shoreward H. univervis-dominated community where no larger (>80 cm SCCL) individuals were sighted, suggesting habitat use is indicative of diet selection and may reflect size-specific food requirements and physiology.     

Brominated flame retardants,a cornelian dilemma

Environmental Chemistry Letters -