Modelling and simulation of inhibition-injection systems applied to polymerization reactors

The most critical aspect of polymerization reactors is the agitator's stop and becomes more serious when this occurs exactly at the removal of the heat load, which is generated by the reaction (exothermic). This phenomenon is typical in power-failure situations of the energy supply or because of other related problems at the plant. The objective of this work is to compare the performance of two configurations for the inhibition-injection system for vinyl chloride monomer (VCM) polymerization reactors. To determine the injection time a rigorous mathematical model was developed. From the results of this work one of the configurations was implemented in an industrial plant.     

Environmental Ethics and Biomimetic Ethics: Nature as Object of Ethics and Nature as Source of Ethics

While the contemporary biomimicry movement is associated primarily with the idea of taking Nature as model for technological innovation, it also contains a normative or ethical principle—Nature as measure—that may be treated in relative isolation from the better known principle of Nature as model. Drawing on discussions of the principle of Nature as measure put forward by Benyus (Biomimicry: innovation inspired by nature, Harper Perennial, New York, 1997) and Jackson (Consulting the genius of place: an ecological approach to a new agriculture, Counterpoint, Berkeley, 2010, Nature as measure: the selected essays of Wes Jackson, Counterpoint, Berkeley, 2011), while at the same time situating these discussions in relation to contemporary debates in the philosophy of biomimicry (Mathews in Organ Environ 24(4): 364–387, 2011; Dicks in Philos Technol, doi: 10.1007/s13347-015-0210-2, 2015; Blok and Gremmen in J Agric Environ Ethics 29(2):203–217, 2016), the aim of this paper is to explore the relation between the principle of Nature as measure and environmental ethics. This leads to the argument that mainstream formulations of environmental ethics share the common trait of seeing our ethical relation to Nature as primarily involving duties to protect, preserve, or conserve various values in Nature, and that, in doing so, they problematically either overlook or dismiss as anthropocentric the possibility that Nature may provide measures, understood in terms of ecological standards, against which our own practices, or at least some of them, may be judged—a way of thinking I call “biomimetic ethics”. The practical consequences of this argument are significant. Whereas mainstream environmental ethics has been applied above all to such issues as wilderness preservation, natural resource management, and animal rights and welfare, biomimetic ethics is applicable rather to the question of how we produce, use, and consume things, and, as such, may potentially provide the basic ethical framework required to underpin the transition to a circular, bio-based, solar economy.     

Welfare environmentality and REDD+ incentives in Indonesia

This paper applies the concept of welfare environmentality to analyse Indonesia’s emerging national and project-based incentive frameworks, a key component to the climate programme reducing emissions from deforestation and forest degradation (REDD+). The paper adapts governmentality theory to explore the rationale and design of various incentive instruments, including government institutions to disburse financial payments and co-benefits to multiple recipients, as well as a local demonstration project in Central Kalimantan Province. These REDD+ incentives are often conflated with the neoliberalisation of the climate agenda, focused on the adoption of market instruments and the commodification of forest carbon. However, REDD+ incentives in Indonesia include diverse policy mechanisms and encompass multiple objectives – such as the delivery of social services and employment schemes aimed at improving community livelihoods. These incentives employ a welfare environmentality, where government agencies and their partners deliver certain rights and socio-economic security for communities in return for adopting practices that improve carbon and forest management. The application of welfare environmentality shows how incentive frameworks operate as a state intervention designed to restructure relations between people and environmental resources.     

Total mercury in marine species from the French coast of the Eastern English Channel

Mercury (Hg) in fish can present a potential risk to wildlife and human consumers. Mercury levels were determined in 12 fish species and 2 invertebrate species from the French coast of the Eastern English Channel collected in June and November 2012. Total mercury concentrations in the muscle tissues ranged between 0.04 and 1.63 µg g^-1 (d.w.). Dab and sandeel displayed a significant positive correlation between Hg concentrations and fish length. Seasonal differences in Hg concentrations were observed for dab and shrimp. The lesser weever showed significantly higher concentrations of Hg (0.97 ± 0.34 µg g^-1 d. w.) than all other species. Gobies and sprat, which had the smallest size, showed significantly lower concentrations than herring, whiting, pout and sardine. Among the considered species, flatfish such as dab, flounder, plaice and sole displayed intermediate levels of Hg. In the present study, the fish age expressed as specimen length seems to be one of the major factors governing Hg contents in muscle tissues. Finally, mercury concentrations in commercial fish from the Eastern English Channel were below the levels fixed by the European Union for total mercury in edible parts of fish products.     

Predicting phosphorus availability from soil-applied composted and non-composted cattle feedlot manure

Prediction of phosphorus (P) availability from soil-applied composts and manure is important for agronomic and environmental reasons. This study utilized chemical properties of eight composted and two non-composted beef cattle (Bos taurus) manures to predict cumulative phosphorus uptake (CPU) during a 363-d controlled environment chamber bioassay. Ten growth cycles of canola (Brassica napus L.) were raised in pots containing 2 kg of a Dark Brown Chernozemic clay loam soil (fine-loamy, mixed, Typic Haploboroll) mixed with 0.04 kg of the amendments. Inorganic P fertilizer (KH2PO4) and an unamended control were included for comparison. All treatments received a nutrient solution containing an adequate supply of all essential nutrients, except P, which was supplied by the amendments. Cumulative P uptake was similar for composted (74 mg kg-1 soil) and non-composted manures (60 mg kg-1 soil) and for the latter and the fertilizer (40 mg kg-1 soil). However, the CPU was significantly higher for organic amendments than the control (24 mg kg-1 soil) and for composted manure than the fertilizer. Apparent phosphorus recovery (APR) from composted manure (24%) was significantly lower than that from non-composted manure (33%), but there was no significant difference in APR between the organic amendments and the fertilizer (27%). Partial least squares (PLS) regression indicated that only two parameters [total water-extractable phosphorus (TPH2O) and total phosphorus (TP) concentration of amendments] were adequate to model amendment-derived cumulative phosphorus uptake (ACPU), explaining 81% of the variation in ACPU. These results suggest that P availability from soil-applied composted and non-composted manures can be adequately predicted from a few simple amendment chemical measurements. Accurate prediction of P availability and plant P recovery may help tailor manure and compost applications to plant needs and minimize the buildup of bioavailable P, which can contribute to eutrophication of sensitive aquatic systems.     

Probabilistic Modelling of Cattle Farm Distribution in Australia

A probabilistic Bayesian method called weights of evidence (WofE) was used to develop a synthetic dataset of cattle farm locations at a national scale across Australia. The synthetic dataset was required for the modelling of livestock movements with a view to assessing biosecurity implications. The WofE method is based on the analysis of spatial relationships between evidential patterns with respect to an event, such as the actual location of a farm. The evidential patterns of cattle farms were derived from maps of land use, land tenure, drainage systems, roads, settlements and long-term averaged rainfall. These evidential patterns were used for delineating and ranking land areas suitable for cattle farming. For each evidential pattern statistics such as a positive weight, a negative weight and a contrast were calculated for estimating the degree of correlation between the evidential patterns and known farm locations. The integrated evidential patterns of known farms were then used for estimating posterior probabilities and splitting land into five different classes according to its suitability for farming.

Indicator organisms for assessing sanitization during composting of plant wastes

The potential for using plant pathogens and seeds as indicator organisms for assessing sanitization of plant wastes during composting was tested in bench-scale flask and large-scale systems. Plasmodiophora brassicae was unsuitable due to high temperature tolerance in dry to moist composts, and detection of viable inoculum post-composting using bioassay plants not corresponding with that using TaqMan® PCR, possibly due to preservation of nucleic acids at elevated temperatures. Several other plant pathogens (Sclerotinia sclerotiorum, Microdochium nivale, Phytophthora cinnamomi and Phytophthora nicotianae) were unsuitable due their low temperature tolerance. Fusarium oxysporum f.sp. cepae and f.sp. radicis-lycopersici chlamydospores and tomato seeds were suitable indicators due to their moderate temperature tolerance and ease of viability testing post-composting. Abutilon seeds were more tolerant than tomato seeds of compost temperatures ?52 °C but more prone to degradation at lower temperatures and therefore less suitable as indicators. Relationships between compost temperature during exposures of 2-10 days and subsequent viability of the above chlamydospores or seeds enabled the sanitizing effect of composting processes to be predicted within 2-6 days. Plant waste type (woody or vegetable) had a small but significant effect on the relationship for tomato seeds but not for F. oxysporum chlamydospores.     

Beyond BAT: Selecting optimal combinations of available techniques,with an example from the limestone industry

Technological choices are multi-dimensional and thus one needs a multi-dimensional methodology to identify best available techniques. Moreover, in the presence of environmental externalities generated by productive activities, ‘best’ available techniques should be best from Society's point of view, not only in terms of private interests. In this paper we present a modeling framework based on methodologies appropriate to serve these two purposes, namely linear programming and internalization of external costs. We develop it as an operational decision tool, of interest for both firms and regulators, and we apply it to a plant in the lime industry. We show why, in this context, there is in general not a single best available technique (BAT), but well a best combination of available techniques to be used (BCAT).     

A diagnostic comparison of measured and model-predicted speciated VOC concentrations

This study compares speciated model-predicted concentrations (i.e., mixing ratios) of volatile organic compounds (VOCs) with measurements from the Photochemical Assessment Monitoring Stations (PAMS) network at sites within the northeastern US during June–August of 2006. Measurements of total non-methane organic compounds (NMOC), ozone (O₃), oxides of nitrogen (NO_x) and reactive nitrogen species (NO_y) are used for supporting analysis. The measured VOC species were grouped into the surrogate classes used by the Carbon Bond IV (CB4) chemical mechanism. It was found that the model typically over-predicted all the CB4 VOC species, except isoprene, which might be linked to overestimated emissions. Even with over-predictions in the CB4 VOC species, model performance for daily maximum O₃ was typically within ±15%. Analysis at an urban site in NY, where both NMOC and NO_x data were available, suggested that the reasonable ozone performance may be possibly due to compensating overestimated NO_x concentrations, thus modulating the NMOC/NO_x ratio to be in similar ranges as that of observations.     

Carbon Monoxide and Sulfur Dioxide Adsorption on— and Desorption from Glass,Plastic, and Metal Tubings

It was planned to install 305 m (1000 ft) of tubing on a television tower to transport ambient air samples from different height levels to pollutant monitoring instruments at ground level. A feasibility study was undertaken to determine the sorption characteristics of sulfur dioxide and carbon monoxide on various conduit materials. Sorption studies were completed on 30.5 m (100 ft) lengths of 1.3 cm (Y2 in) diam tubings of glass, Teflon, tygon, polypropylene, PVC piping, aluminum, and stainless steel. Final tests were completed on 305 m of 1.9 cm (3/4 in) diam stainless steel tubing. The following variables were investigated: tubing diameter, gas concentration, flowrate through the tubing, temperature, humidity, and the effect of sorption with sulfur dioxide and carbon monoxide alone or together. The parameter ranges studied approximated either atmospheric or air sampling conditions. For carbon monoxide, there was no significant difference between the mean inlet and outlet tubing concentrations under the conditions of the study. With sulfur dioxide, there was neither tubing adsorption nor desorption under the experimental parameters studied, except for tygon, PVC, and aluminum. After a conditioning period with sulfur dioxide, tygon, PVC, and aluminum could also be used as air inlet conduits; tygon is not recommended.