Improved TITRILOG Sensitivity Part II. Field Performance and Evaluation

Air pollution forecasting is not a new field but is certainly an area with only modest development since its early beginnings. Because ozone Is not a source emission but instead is formed from precursors, ozone episodes should be more readily forecasted than other pollutants by simply monitoring the precursors. The ozone empirical model developed within the course of this study is very site specific, therefore the major goal of the study was to establish the techniques which can be used to develop an ozone forecasting model for specific monitoring networks. The results of using the ozone forecasting model showed that even though errors as high as 25 % occurred the typical error In forecasting was in the 5-10% range.     

Farmers' assessment of the social and ecological values of land uses in central highland Ethiopia

Often in land use evaluations, especially those in developing countries, only the financial aspect receives serious attention, while the social and ecological values are overlooked. This study compared the social and ecological values of four land use types (small-scale woodlot [SSW], boundary tree and shrub planting [BTP], homestead tree and shrub growing [HTG] and cereal farming [CF]) by a criteria-based scoring approach using a bao game. The impacts of local wealth status and proximity to a forest on the value the community renders to the land use types were also assessed. The value comparison, assessed by relative scoring, was accompanied by farmer’s explanations to reveal the existing local knowledge about land use values. It was found that HTG ≥ SSW > BTP > CF for both social and ecological values. Though this trend applies for the medium and rich households, the poor ones chose SSW as the most valuable. With increasing distance from a forest, the social and ecological values of land uses increased. The accompanying scoring justifications indicated the existence of in-depth ecological knowledge, which conform to contemporary scientific reports. Generally, this study showed that social and ecological values, besides financial values, strongly influence farmer’s decision in implementing various practices related to the land use types. Thus, such values are worth considering for a holistic understanding of the diverse benefits of land uses. Finally, the strong preference for tree and shrub-based land use types is a good opportunity for enhancing tree and shrub growing to minimize the major environmental problems (e.g., soil degradation, wood shortage and deforestation) in the central highlands of Ethiopia.     

Use and validation of novel snow samplers for hydrophobic, semi-volatile organic compounds (SVOCs)

Two novel gas-tight snow samplers (snow-can and snow-tube) are presented and the performance of the snow-can in a field trial was assessed. The methodology for the sampling, extraction and analysis of persistent organic pollutants (POPs) are detailed. These samplers allow the various components of a snow sample to be analysed separately; these included the meltwater (MW), particulate matter (GFF) and vapour in the headspace (HS). Snow samples collected on the Punta Indren glacier in the Italian Alps revealed the occurrence of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OC). Replicate samples of the same snow type were undertaken as a test of sampling precision. Relative standard deviations (RSDs) for SigmaPCBs and SigmaPAHs were approximately 30% and approximately 35% respectively. The lowest precision was found for the particle-laden snow, notably for the heavier PCB homologues. For the chlorinated compounds, the pesticides lindane and endosulfan-I had the highest levels in snow, with mean concentrations of 402 and 103 pgl(-1) (snow meltwater) respectively. The vapour present in the headspace (HS) comprised a minor component of a collected sample for all compounds, but HS concentrations for three lighter PAHs gave good agreement with those calculated based on their dimensionless Henry's law constants. This suggests that volatilisation during melting of aged snow-can be reasonably predicted with knowledge of the temperature-dependent Henry's law constant.