全文获取类型
收费全文 | 248篇 |
免费 | 1篇 |
国内免费 | 10篇 |
专业分类
安全科学 | 11篇 |
废物处理 | 45篇 |
环保管理 | 11篇 |
综合类 | 40篇 |
基础理论 | 34篇 |
污染及防治 | 93篇 |
评价与监测 | 8篇 |
社会与环境 | 16篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 2篇 |
2022年 | 5篇 |
2021年 | 5篇 |
2020年 | 1篇 |
2019年 | 3篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 8篇 |
2015年 | 5篇 |
2014年 | 3篇 |
2013年 | 19篇 |
2012年 | 10篇 |
2011年 | 15篇 |
2010年 | 17篇 |
2009年 | 19篇 |
2008年 | 21篇 |
2007年 | 23篇 |
2006年 | 13篇 |
2005年 | 9篇 |
2004年 | 19篇 |
2003年 | 6篇 |
2002年 | 14篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1997年 | 3篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1992年 | 3篇 |
1989年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1969年 | 1篇 |
1957年 | 1篇 |
1956年 | 1篇 |
排序方式: 共有259条查询结果,搜索用时 15 毫秒
101.
102.
A new method utilizing phase separation phenomena for the extraction of heavy metal ions used as colorants in colored glass is proposed. Colored soda-lime-silica glass containing Co or Cr as a colorant was remelted with B2O3 to yield soda-lime-borosilicate glass. The soda-lime-borosilicate glass thus obtained was leached in 1M nitric acid at 90 degrees C to dissolve the borate phase. All cations (Na, Ca, Cr and Co) concentrated in the borate phase are successfully leached out with the dissolution of the borate phase, when the amount of the B2O3 added to the glass and heat treatment conditions are properly chosen. Porous silicate glass powders with high SiO2 purity are obtained as the result of the leaching. Porous glass can also be formed as bulk material by controlling the composition of additives during the remelting. 相似文献
103.
104.
N-Nitrosodimethylamine (NDMA) is a potent carcinogen that yields a cancer risk of 10−6 at concentrations as low as 0.7 ng L−1. Tentative guideline values are set at 3 ng L−1 in California, USA; 9 ng L−1 in Ontario, Canada; 40 ng L−1 nationwide in Canada; and 100 ng L−1 by the World Health Organization. NDMA is a great concern in treating reclaimed water as well as drinking water. UV degradation can be considered effective degradation method. A 1-log reduction of NDMA is achieved by 1000 mJ cm−2 of a 254-nm low pressure (LP) mercury UV lamp. However, a higher degradation efficiency than that provided by LP lamps is desired in practical treatment. In this study, the effects of wavelength and water quality were investigated to achieve higher degradation efficiency. The effects of wavelength were examined by comparing three UV lamps: a 222-nm Kr Cl Excimer UV lamp, a 254-nm LP mercury UV lamp, and a 230- to 270-nm filtered medium pressure (FMP) mercury UV lamp. The 222-nm lamp and FMP lamp achieved 4 times and 2.8 times higher degradation efficiency, respectively, than the conventional 254-nm LP lamp. Effects on water quality were also simulated by using absorption spectrum data of nitrate solutions and process water from a drinking-water treatment plant. In the simulation, the 222-nm lamp was affected by UV-absorbing compounds in the water, whereas the FMP lamp showed more stable degradation efficiency. Appropriate use of these three types of lamps could enhance the efficiency of degradation of NDMA. 相似文献
105.
Tomohiro Kuwae Jota Kanda Atsushi Kubo Fumiyuki Nakajima Hiroshi Ogawa Akio Sohma Masahiro Suzumura 《Ambio》2016,45(3):290-301
Estuarine
and shallow coastal systems (ESCS) are recognized as not only significant organic carbon reservoirs but also emitters of CO2 to the atmosphere through air–sea CO2 gas exchange, thus posing a dilemma on ESCS’s role in climate change mitigation measures. However, some studies have shown that coastal waters take up atmospheric CO2 (Catm), although the magnitude and determinants remain unclear. We argue that the phenomenon of net uptake of Catm by ESCS is not unusual under a given set of terrestrial inputs and geophysical conditions. We assessed the key properties of systems that show the net Catm uptake and found that they are often characteristic of human-dominated systems: (1) input of high terrestrial nutrients, (2) input of treated wastewater in which labile carbon is highly removed, and (3) presence of hypoxia. We propose that human-dominated ESCS are worthy of investigation as a contributor to climate change mitigation. 相似文献
106.
107.
日本的碳储量 总被引:1,自引:0,他引:1
为估计所谓的非能源用途矿物燃料排放的CO2,建立了NEAT(Nonenergy use Emission Accounting Tables,非能源排放统计表)模型.物质流动的统计是该模型的基础.NEAT模型已在许多国家应用,以便验证该模型并促进其应用.本文讨论日本的研究案例.NEAT分析表明:1996年的CO2排放量比以前政府间气候变化委员会(IPCC)指导原则基础上的估计高出23t,相当于日本温室气体总排放量的1.9%.因此,在未来几年,调整日本的排放计算方法,提供更为详细的排放估计方法是可取的.鉴于其它国家的相似结果,建议改进IPCC的指导原则. 相似文献
108.
Mobilization of arsenic from subsurface sediments by effect of bicarbonate ions in groundwater 总被引:5,自引:0,他引:5
Arsenic leaching by bicarbonate ions has been investigated in this study. Subsurface sediment samples from Bangladesh were treated with different carbonate and bicarbonate ions and the results demonstrate that the arsenic leaching efficiency of the carbonate solutions decreased in the order of Na2CO3>NaHCO3>BaCO3>MnCO3. Sodium carbonate and bicarbonate ions extracted arsenic most efficiently; Na2CO3 leached maximum 118.12 microg/l of arsenic, and NaHCO3, 94.56 microg/l of arsenic from the Ganges delta sediments after six days of incubation. The arsenic concentrations extracted in the batch experiments correlated very well with the bicarbonate concentrations. The kinetics study of arsenic release indicates that arsenic-leaching rate increased with reaction time in bicarbonate solutions. Bicarbonate ions can extract arsenic from sediment samples in both oxic and anoxic conditions. A linear relationship found between arsenic contents in core samples and those in leachates suggests that dissolved arsenic concentration in groundwater is related to the amount of arsenic in aquifer sediments. In batch experiment, bicarbonate solutions effectively extracted arsenic from arsenic adsorbed iron oxyhydroxide, reflecting that bicarbonate solutions may mobilize arsenic from iron and manganese oxyhydroxide in sediments that are ubiquitous in subsurface core samples. Carbonate ion may form complexes on the surface sites of iron hydroxide and substitute arsenic from the surface of minerals and sediments resulting in release of arsenic to groundwater. Like in the batch experiment, arsenic and bicarbonate concentrations in groundwater of Bangladesh correlated very well. Therefore, bicarbonate leaching is presumed to be one important mechanism to mobilize arsenic in bicarbonate dominated reducing aquifer of Bangladesh and other parts of the world as well. 相似文献
109.
Environmental conditions for the formation of insoluble Tc in water ponds located above paddy fields
Optimum conditions for the formation of insoluble Tc (Tc in >0.2 microm size fraction) were studied using a microcosm including water ponds above a paddy field to understand Tc behavior in such fields. In the microcosm, soluble TcO(4)(-) was converted to insoluble forms, but no changes in the form of Tc were observed in filtered microcosm samples which were microorganisms-free. The formation of insoluble Tc was inhibited by the addition of the antibiotic chloramphenicol. In addition, the reduction of soluble Tc(VII)O(4)(-) to low-valence oxide was not observed in the filtered microcosm samples, although reducing conditions were present. These results indicated that bacteria were involved in the formation of insoluble Tc. Since oxidizing conditions influence bacterial metabolism, the formation of insoluble Tc by bacteria was studied under aerobic and anaerobic conditions. The results showed that anaerobic conditions were favorable for the formation of insoluble Tc. In addition, the addition of formate as an electron donor to a microcosm sample facilitated the formation of insoluble Tc. The results suggested that insoluble Tc in the water ponds above paddy fields was caused by bacteria, which were shown to couple the oxidation of formate to the reduction of Tc(VII) during anaerobic respiration. 相似文献
110.