Improved space–time forecasting of next day ozone concentrations in the eastern US

There is an urgent need to provide accurate air quality information and forecasts to the general public and environmental health decision-makers. This paper develops a hierarchical space–time model for daily 8-h maximum ozone concentration (O₃) data covering much of the eastern United States. The model combines observed data and forecast output from a computer simulation model known as the Eta Community Multi-scale Air Quality (CMAQ) forecast model in a very flexible, yet computationally fast way, so that the next day forecasts can be computed in real-time operational mode. The model adjusts for spatio-temporal biases in the Eta CMAQ forecasts and avoids a change of support problem often encountered in data fusion settings where real data have been observed at point level monitoring sites, but the forecasts from the computer model are provided at grid cell levels. The model is validated with a large amount of set-aside data and is shown to provide much improved forecasts of daily O₃ concentrations in the eastern United States.     

Formation of submicron sulfate and organic aerosols in the outflow from the urban region of the Pearl River Delta in China

Size-resolved chemical compositions of non-refractory submicron aerosols were measured using a quadrupole Aerodyne aerosol mass spectrometer at a rural site near Guangzhou in the Pearl River Delta (PRD) of China in the summer of 2006. Two cases characterized as the outflows from the PRD urban region with plumes of high SO₂ concentration were investigated. The evolution of sulfate size distributions was observed on a timescale of several hours. Namely mass concentrations of sulfate in the condensation mode (with vacuum aerodynamic diameters (D_va) < 300 nm) increased at a rate of about 0.17–0.37 ppbv h^?1 during the daytime. This finding was consistent with the sulfuric acid production rates of about 0.17–0.3 ppbv h^?1, as calculated from the observed gas-phase concentrations of OH (～3.3 × 10⁶–1.7 × 10⁷ cm^?3) and SO₂ (～3–21.2 ppbv). This implies that the growth of sulfate in the condensation mode was mainly due to gas-phase oxidation of SO₂. The observed rapid increase was caused mainly by the concurrent high concentrations of OH and SO₂ in the air mass. The evolution of the mass size distributions of m/z 44, a tracer for oxygenated organic aerosol (OOA), was very similar to that of sulfate. The mass loadings of m/z 44 were strongly correlated with those of sulfate (r² = 0.99) in the condensation mode, indicating that OOA might also be formed by the gas-phase oxidation of volatile organic compound (VOC) precursors. It is likely that sulfate and OOA were internally mixed throughout the whole size range in the air mass.     

Soil compaction in topsoil replacement during mining reclamation

Current U.S. mining regulations require revegetation in reclaiming surface mines. Excessive soil compaction can be an impediment to successful revegetation in poor soil conditions common to Eastern U.S. coal mine sites. A field study was performed to determine the bulk densities of soils that had been spread by either bulldozers or scrapers at a strip mine site. Moisture-density relationships for the soils were determined from the field samples. These were compared with samples compacted by the Standard Proctor compaction test. The results of the study indicate that the degree of compaction, could be lessened through proper soil handling procedures.     

Seasonal changes in the structure of an intertidal community

Quantitative (0.25 m²) samples of macrofaunal (>1.0 mm) invertebrates were taken in each season from one habitat of an intertidal sandbar in the North Inlet estuary near Georgetown, South Carolina, USA. During all seasons the community inhabiting the sample site was numerically dominated by two species of haustoriid amphipods (Acanthohaustorius millsi and Pseudohaustorius caroliniensis). Seasonal changes at the community level were clearly controlled by the population dynamics of the numerically dominant species, and qualitative information on life histories was important to the interpretation of analyses' results.This work was supported by the Environmental Technology Center of Martin Marietta Corporation and the Belle W. Baruch Institute for Marine Biology and Coastal Research. It is Contribution No. 138 of the Belle W. Baruch Institute for Marine Biology and Coastal research.     

The double-edged sword of humic substances: contrasting their effect on respiratory stress in eastern rainbow fish exposed to low pH

High amounts of humic substances (HS) are commonly found in natural acidic waterways and have been suggested to offer some protection against low pH. This study investigated the ability of HS to decrease respiratory stress in eastern rainbowfish (Melanotaenia splendida splendida) exposed to decreases in pH (range of 7–3.5) in soft and hard water. Repeated measures ANOVA revealed a significant difference in respiration (time taken for ten operculum movements) between pH and HS treatments, with a significant interaction between pH and HS present in 5/6 trials. Respiratory stress was shown to increase with increasing acidity, but significantly decreased in treatments with HS (10 and 20 mg/L) compared to those without. The fish exposed to pH treatments without HS also displayed increased hyperactivity, larger operculum movements and increased mucous production. Increased morbidity was shown in HS treatments at pH 3.5 (soft water) and at pH 4 (hard water) compared to treatment without HS. This indicates that HS is helpful in ameliorating the effects of decreased pH on respiration at sublethal pH levels; however, as pH decreases further, it seems that HS increases the toxicity (morbidity) of the low pH.     

Environmental Assessment Framework for Policy Applications: Life Cycle Assessment,External Costs and Multi-criteria Analysis

The paper presents a framework for the analysis of external costs of environmental burdens, namely an impact pathway analysis, often coupled with the inventory stage of life cycle assessment (LCA). The ground rule is: quantify as much as possible in terms of burdens (pollutant emissions, etc.), impacts, and their monetary equivalent, then use multi-criteria analysis (MCA) for any remaining impacts that are considered to be too uncertain or defy quantification through to monetization. Although MCA could be used directly on estimates of burdens or impacts, monetary valuation provides a mechanism for consistent weighting of impacts categories based on assessment of public preference. Further advantages of extending LCA through detailed impact assessment combined with monetary valuation are that it greatly simplifies MCA by combining a large number of different environmental impact categories, thereby avoiding an unmanageably large number of criteria, and also facilitates cost benefit analysis (CBA). The risks are noted of inappropriate use of the tools or interpretation/use of the results, and recommendations are made for improved practice. These points are illustrated with examples. The key messages are: (1) that policies should be targeted correctly to give a clear signal which source of a burden should be reduced by how much; (2) that analysts should take into account the needs of policy makers and the link between the analysis and possible policy applications; and (3) that current LCA practice gives limited guidance in both areas, largely through a lack of consideration of the relative and absolute importance of different types of impact. However, this is precisely the strength of external costs analysis, particularly when used with MCA.     

The Estuarine Component of the Us E.P.A.'S Environmental Monitoring and Assessment Program

The US Environmental Protection Agency's Office of Research and Development has initiated the Environmental Monitoring and Assessment Program (EMAP) to monitor status and trends in the condition of the nation's near coastal waters, forests, wetlands, agro-ecosystems, surface waters, deserts and rangelands. the programme is also intended to evaluate the effectiveness of Agency policies at protecting ecological resources occurring in these systems. Monitoring data collected for all ecosystems will be integrated for regional and national status and trends assessments. the near coastal component of EMAP consists of estuaries, coastal waters, and the Great Lakes. Near coastal ecosystems have been regionalized and classified, and an integrated sampling strategy has been developed. EPA and NOAA have agreed to coordinate and, to the extent possible, integrate the near coastal component of EMAP with the NOAA National Status and Trends Program. A demonstration project was conducted in estuaries of the mid-Atlantic region (Chesapeake Bay to Cape Cod) in the summer of 1990. in 1991, monitoring continued in mid-Atlantic estuaries and was initiated in estuaries of a portion of the Gulf of Mexico. Preliminary results indicate: there are no insurmountable logistical problems with sampling on a regional scale; several of the selected indicators are practical and sensitive on the regional scale; and an efficient effort in future years will provide valuable information on condition of estuarine resources at regional scales.     

Authentication of synthetic environmental contaminants and their (bio)transformation products in toxicology: polychlorinated biphenyls as an example

Environmental Science and Pollution Research - Toxicological studies use “specialty chemicals” and, thus, should assess and report both identity and degree of purity (homogeneity) of...