三种安全评价方法在苏丹化工项目的应用比较分析与实践

为解决海外炼化项目存在的资源短缺、员工技能不足和管理文化冲突等问题,提高海外炼化项目安全管理水平,本文通过对比苏丹化工项目所采用的3种不同安全评价方法,分析出不同方法的优缺点和适用性。基于此,苏丹化工项目采用这3种评价方法,很好地弥补了单一评价方法的不足,查找出了主要的安全管理漏洞,识别出重大隐患所在,有效防范了各类安全风险,项目的安全管理水平得到了显著提高。     

基于PHA-LEC法金属矿山盲竖井工程安全分析研究

针对盲竖井工程的危险、有害因素的危害程度及特殊工艺,将盲竖井施工系统分为卷扬机硐室开凿、盲竖井掘进、爆破、吊桶提升、出碴、竖井提升装置安装、施工通风7个主要子系统,在对矿山的盲竖井施工事故数据充分调查和分析的基础上,运用预先危险性分析法(PHA)对盲竖井施工的危险、危害因素进行辨识和定性分析,结合生产作业条件安全评价方法(LEC)对盲竖井系统中各子系统进行危险性评价,定量分析计算PHA的危险等级,提出科学预防措施。PHA-LEC法为盲竖井施工安全分析提供了新的模式,为制定防范措施和管理决策提供科学依据,具有一定的实际指导意义。     

Advanced treatment of biologically pretreated coal gasification wastewater by a novel heterogeneous Fenton oxidation process

Sewage sludge from a biological wastewater treatment plant was converted into sewage sludge based activated carbon(SBAC) with Zn Cl2 as activation agent, which was used as a support for ferric oxides to form a catalyst(Fe Ox/SBAC) by a simple impregnation method.The new material was then used to improve the performance of Fenton oxidation of real biologically pretreated coal gasification wastewater(CGW). The results indicated that the prepared Fe Ox/SBAC significantly enhanced the pollutant removal performance in the Fenton process, so that the treated wastewater was more biodegradable and less toxic. The best performance was obtained over a wide p H range from 2 to 7, temperature 30°C, 15 mg/L of H2O2 and 1 g/L of catalyst, and the treated effluent concentrations of COD, total phenols,BOD5 and TOC all met the discharge limits in China. Meanwhile, on the basis of significant inhibition by a radical scavenger in the heterogeneous Fenton process as well as the evolution of FT-IR spectra of pollutant-saturated Fe Ox/BAC with and without H2O2, it was deduced that the catalytic activity was responsible for generating hydroxyl radicals, and a possible reaction pathway and interface mechanism were proposed. Moreover, Fe Ox/SBAC showed superior stability over five successive oxidation runs. Thus, heterogeneous Fenton oxidation of biologically pretreated CGW by Fe Ox/SBAC, with the advantages of being economical, efficient and sustainable, holds promise for engineering application.     

Nitrogen removal from coal gasification wastewater by activated carbon technologies combined with short-cut nitrogen removal process

A system combining granular activated carbon and powdered activated carbon technologies along with shortcut biological nitrogen removal （GAC-PACT-SBNR） was developed to enhance total nitrogen （TN） removal for anaerobically treated coal gasification wastewater with less need for external carbon resources. The TN removal efficiency in SBNR was significantly improved by introducing the effluent from the GAC process into SBNR during the anoxic stage, with removal percentage increasing from 43.8%49.6% to 68.8%-75.8%. However, the TN removal rate decreased with the progressive deterioration of GAC adsorption. After adding activated sludge to the GAG compartment, the granular carbon had a longer service-life and the demand for external carbon resources became lower. Eventually, the TN removal rate in SBNR was almost constant at approx. 43.3%, as compared to approx. 20.0% before seeding with sludge. In addition, the production of some alkalinity during the denitrification resulted in a net savings in alkalinity requirements for the nitrification reaction and refractory chemical oxygen demand （COD） degradation by autotrophic bacteria in SBNR under oxic conditions. PACT showed excellent resilience to increasing organic loadings. The microbial community analysis revealed that the PACT had a greater variety of bacterial taxons and the dominant species associated with the three compartments were in good agreement with the removal of typical pollutants. The study demonstrated that pre-adsorption by the GAC-sludge process could be a technically and economically feasible method to enhance TN removal in coal gasification wastewater （CGW）.     

Effect of alkalinity on nitrite accumulation in treatment of coal chemical industry wastewater using moving bed biofilm reactor

Nitrogen removal via nitrite （the nitrite pathway） is more suitable for carbon-limited industrial wastewater. Partial nitrification to nitrite is the primary step to achieve nitrogen removal via nitrite. The effect of alkalinity on nitrite accumulation in a continuous process was investigated by progressively increasing the alkalinity dosage ratio （amount of alkalinity to ammonia ratio, mol/mol）. There is a close relationship among alkalinity, pH and the state of matter present in aqueous solution. When alkalinity was insufficient （compared to the theoretical alkalinity amount）, ammonia removal efficiency increased first and then decreased at each alkalinity dosage ratio, with an abrupt removal efficiency peak. Generally, ammonia removal efficiency rose with increasing alkalinity dosage ratio. Ammonia removal efficiency reached to 88% from 23% when alkalinity addition was sufficient. Nitrite accumulation could be achieved by inhibiting nitrite oxidizing bacteria （NOB） by free ammonia （FA） in the early period and free nitrous acid in the later period of nitrification when alkalinity was not adequate. Only FA worked to inhibit the activity of NOB when alkalinity addition was sufficient.     

煤矿瓦斯爆炸事故的防治对策

我国煤矿日趋严重的瓦斯爆炸事故灾害严重地威胁着矿井工作人员的生命安全，制约矿井生产的发展，给煤炭企业带来沉重的负担，从安全科学的角度及其事故原因分类出发，提出了防治我国煤矿瓦斯爆炸事故的对策。     

Enhanced nitrogen removal of coal pyrolysis wastewater with low COD to nitrogen ratio by partial nitrification-denitrification bioprocess assisted with polycaprolactone

The purpose of this study is to investigate the enhancement of polycaprolactone (PCL) on total nitrogen (TN) removal of coal pyrolysis wastewater (CPW) with low COD to nitrogen ratio by partial nitrification-denitrification bioprocess (PNDB) in one single reactor. With the innovative combination of PCL and PNDB, the TN removal efficiency in the experimental reactor (signed as R1) was 10.21% higher than control reactor (R2). Nitrite accumulation percentage (NAP) in R1 was 82.02%, which was 17.49% higher than R2 at the dissolved oxygen (DO) concentration of 0.9–1.5 mg/L, for the reason that the extra DO was consumed by PCL biodegradation at the aerobic period. Gel permeation chromatography (GPC) results demonstrated that organics with the molecular weight of 185 Da, which could serve as additional carbon sources for denitrifiers, were generated during the PCL hydrolysis process at the anoxic period. PCL was hydrolyzed by extracellular enzymes with the break of the ester bond which was confirmed by FT-IR spectrometer. Microbial community analysis revealed that Ferruginibacter was the dominant hydrolysis bacteria in R1. Nitrosomonas were the main ammonium-oxidizing bacteria (AOB) and Hyphomicrobium were the denitrifiers in this study.

     

软岩巷道围岩刚柔耦合支护技术研究与应用∗

煤矿开采进入深部开采阶段后,普遍呈现出围岩变形量大、支护构件失效的技术难题。为研究针对性的控制对策,以矿典型高地应力软弱破碎巷道为研究背景,在现场矿压监测、地质雷达探测以及地应力实测的基础上,研究了此类巷道的变形规律。同时基于现场监测及分析成果,提出了以高预应力锚杆、注浆锚杆(索)和“U”型钢架为核心的分步刚柔耦合支护关键技术,并阐明了其具体支护机制。为进一步检验新支护方案的支护效果,在新掘的胶带大巷进行了现场实验,相比原支护围岩松动破坏范围减小了近 50%,顶板下沉量、两帮移近量以及底鼓量仅 163、135 和 107 mm,52 d 内基本实现了巷道变形稳定,取得了良好的支护效果。     

地震灾害应急物流配送系统模型优化方法研究

为合理选择应急物流配送中心地址,提高应急管理能力,基于地震灾害风险评价数据,通过ArcGIS平台形成Voronoi图,可视化表达地震应急准备分区方案并进行应急物流中心预选址;在考虑需求权重情况下,构建应急物流配送中心优化选址模型,通过LINGO软件编程求解得出基于震灾应急准备分区的应急物流配送中心选址方案,并以A市为例,通过与传统行政区划建设方案进行对比,验证本文选址方案的有效性。研究结果表明：本文选址优化模型综合考虑各方面因素,使服务里程总量减少31.39%,单位服务量提高30.61%,验证选址方案的配送效率与公平性。