Concentrations of Cr, Cd, Cu, Zn and Fe in crab Charybdis longicollis and shrimp Penaeus semisulcatus from the Iskenderun Bay, Turkey

Copper, chromium cadmium, iron and zinc concentrations were determined in marine crab Charybdis longicollis and marine shrimp Penaeus semisulcatus in order to assess the impact of industrial activities and the sinking of M/V Ulla ship. Liver, gill and muscle sample solutions prepared analyzed using the atomic absorption spectrophotometry technique. The order of the metal concentrations found in muscle of crab was: Cu>Cr>Fe>Zn>Cd, while in muscle of shrimp the order was different: Cr>Cu>Zn>Fe>Cd. The highest Cu, Cr, Cd, Fe and Zn concentrations were found in the liver, and this was followed by the gill and muscle in both species. The levels of all metals in a given tissue were always higher in C. longicollis than in P. semisulcatus. Metals in both species show seasonal variations. In both species the highest concentrations were detected for all metals in summer.     

Three-Dimensional Modeling of an Urban Park and Trees by Combined Airborne and Portable On-Ground Scanning LIDAR Remote Sensing

In this study, we confirmed the utility of airborne and portable on-ground scanning light detection and ranging (LIDARs) for three-dimensional visualization of an urban park and quantification of biophysical variables of trees in the park. The digital canopy height model (DCHM) and digital terrain model generated from airborne scanning LIDAR data provided precise images of the ground surface and individual tree canopies. The heights of 166 coniferous and broadleaf trees of 11 species in the park were estimated from the DCHM images with slight underestimation (mean error = −0.14 m, RMSE = 0.30 m). Portable on-ground scanning LIDAR provided images of individual trees with detailed features. Tree height and trunk diameter were estimated to be within 0.31 m and 1 cm, respectively, from the on-ground LIDAR images. We combined airborne and on-ground LIDAR images to overcome blind regions and created a complete three-dimensional model of three standing trees. The model allowed not only visual assessment from all viewpoints but also quantitative estimation of canopy volume, trunk volume, and canopy cross-sectional area.     

Residue determination and dissipation of ioxynil octanoate in maize and soil

A simple and efficient residue analysis method for direct determination of ioxynil octanoate in maize and soil was developed and validated with High Performance Liquid Chromatography-Ultra Violet (HPLC-UV). The samples were extracted with mixtures of acetonitrile and deionized water followed by Solid Phase Extraction (SPE) to remove co-extractives prior to analysis by HPLC-UV. The recoveries of ioxynil octanoate extracted from maize and soil samples ranged from 86 %-104 % and 84 %-96 %, respectively, with relative standard deviation (RSD) less than 7.84% and sensitivity of 0.01 mg kg(-1). The method was applied to determine the residue of ioxynil octanoate in maize and soil samples from experimental field. Data had shown that the dissipation rate in soil was described as pseudo-first-order kinetics and the half-life (t(1/2)) was less than 1.78 days. No ioxynil octanoate residue (<0.01 mg kg(-1)) was detected in maize at harvest time withholding period of 60 days after treatments of the pesticide. Direct confirmation of the analytes in field trial samples was realized by Liquid Chromatography-Mass Spectrometry (LC-MS).     

Catalytic Activity of Biomorphic α-MoO(3) in the Degradation of Methyl Violet Dye

A network of fibers comprising orthorhombic molybdenum trioxide (α-MoO(3)) crystals were synthesized using paper as template via a biomorphic approach. The template was completely removed by annealing the sample at 600°C for 5?min. Monoclinic MoO(3) was formed and consequently converted into orthorhombic α-MoO(3) after prolonged annealing. Three milligrams of the biomorphic α-MoO(3) could degrade up to 90% of a methyl violet aqueous solution with a concentration of 20?mg/L under normal visible light. The size of the α-MoO(3) grains and the porosity of the biomorphic sample affected catalytic performance.     

A&WMA Honors Five Individuate and One Company In 1989 Awards Program

A repository of 39 and 34 gaseous organic compounds in compressed gas cylinders at PPM (5 to 700) and PPB levels (1 to 10,000) respectively has been established by EPA for use in performance audits. In this program, to ensure that the concentration of each gas standard has not changed, each standard is periodically analyzed for stability. The gas mixtures were initially analyzed once or twice by the manufacturer before shipment to Research Triangle Institute (RTI). The gas mixtures were then analyzed at RTI upon receipt from the gas manufacturer and then reanalyzed at 2, 6 and 12 months, and annually thereafter, to determine any change in concentration.

An examination of the stability data shows that concentrations for all the organics tested usually varied by less than 10 percent over a period of several years. Ethylene oxide and propylene oxide and trans 1, 4-dichloro-2-butene below the 10 ppb level have been found to be unstable. Six other compounds at the PPM level (aniline, cyclohexanone, p-dichlorobenzene, ethylamine 1, 2-dibromoethylene, and formaldehyde) have been found to be unstable in compressed gas cylinders.     

Evaluation of Contact Columns for Nitrogen Dioxide Absorption

The absorption efficiencies of 6–, 10–, IS–, and 60-turn spiral contact columns for two formulations of Saltzman reagent are evaluated for use in atmospheric nitrogen dioxide analyzers at several air and liquid flow rates. Response times for the several columns as a function of flow rates and absorbing reagent are also given. The recommended column and reagent are indicated. The technique of adjusting instrument parameters for direct readout of NO₂ concentrations is described.     

Urban CO Concentrations and Vehicle Emissions

The effect of the general growth of CO vehicular emissions in urban areas on the CAMP station measurements in downtown areas, where vehicular traffic is saturated is considered. With the assumption that the street-level CO concentration is derived from the sum of an urban background term and a local street-effect term, the urban background CO concentration is computed with a diffusion model by introducing a simple area source distribution. The local street-effect term is taken to be constant at a saturation emission level corresponding to a saturation traffic density when the emission per vehicle-mile and meteorological conditions are fixed. The present analysis indicates that the local street-effect term, AC, has a major role in determining street-level concentrations for pollutants, such as CO, whose air quality standard is based on maximum concentrations with averaging times of 1 hour and 8 hours. The relevance of this analysis to the abatement requirements of the Clean Air Amendments and to the driving cycle adopted is discussed.